• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.133-136
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• 2009

We present calculations for the 4-aminopyrimidine (4AP) – HCl and –HBr complexes. We predict that the charge separated (zwitterionic) form [4AP$H^+-Cl^-$] is not stable, but that [4AP$H^+-Br^-$] is stable enough for experimental detection in gas phase at low temperatures. The latter observation is attributed to smaller dissociation energy of HBr compared with HCl, and to “solvation” of HBr by the amino group in 4AP.

• Current Photovoltaic Research
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• v.11 no.3
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• pp.96-102
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• 2023

Sn-Pb narrow-bandgap perovskite solar cells, which is a light-harvesting layer thicker than 1.3 micrometers, is needed to enhance the low photocurrent. The fabrication of such a thick film through solution processing is a key challenge. Here, we studied and characterized the film by using a precursor solution of increased concentration, comparing it with the universally used 1-micrometer Sn-Pb perovskite film. The increase in molar concentration clearly induced thickness enhancement, but we observed that it also created numerous voids at the interface with bottom charge transporting layer. We hypothesized that these voids might hinder the increase in photocurrent associated with thickness enhancement. By introducing methylammonium chloride (MACl), we successfully fabricated Sn-Pb perovskite film with a thickness of 1.3 micrometer and no voids. Void-controlled Sn-Pb perovskite solar cells not only demonstrated superior short-circuit current density compared to those with voids but also operated smoothly under light exposure.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.4
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• pp.473-478
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• 2014

Microalgae is known as one alternative energy source of the fossil fuel with the small size of $5{\sim}50{\mu}m$ and negative charge. Currently, the cost of microalgae recovery process take a large part, about 20 - 30% of total operating cost. Thus, the microalgae recovery method with low cost is needed. In this study, the optimum current for Scenedesmus dimorphus recovery process using electrocoagulation techniques was investigated. Under the electrical current, Al metal in anode electrode is oxidized to oxidation state of $Al^{3+}$. In the cathode electrode, the water electrolysis generated $OH^-$ which combine with $Al^{3+}$ to produce $Al(OH)_3$. This hydroxide acts as a coagulant to harvest microalgae. Before applying in 1.5 L capacity electrocoagulation reactor, Scenedesmus dimorphus was cultured in 20 L cylindrical reactor to concentration of 1 OD. The microalgae recovery efficiency of electrocoagulation reactor was evaluated under different current conditions from 0.1 ~ 0.3 A. The results show that, the fastest and highest recovery efficiency were achieved at the current or 0.3 A, which the highest energy efficiency was achieved at 0.15 A.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.6
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• pp.1009-1015
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• 2017

Since most of the urban railway operating agencies are established and operated by local governments, Public Service Obligation(PSO) is given priority. Therefore, free riding is carried out based on individual laws and regulations. In Korea, as the aging population goes, the increase in the number of elderly passengers on the urban railways is leading to a free rider as a big part of the fiscal deficit of the city railway operators. However, there have been no previous researches on free pass riding, and especially, it is necessary to study free ride on private investment projects. Several alternatives including a full charge case, free-ride for 70 years old over case, and separate fare charge (900won) are considered. Separate fare charge (900won) was selected as the optimal alternative since there is no fare income adjustment between operating agencies and no subsidy from government.

• Journal of Hydrogen and New Energy
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• v.28 no.1
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• pp.56-62
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• 2017

Although most electricity production contributes to air pollution, the vehicle organizations and environmental agency categorizes all EVs as zero-emission vehicles because they produce no direct exhaust or emissions. Currently available EVs have a shorter range per charge than most conventional vehicles have per tank of gas. EVs manufacturers typically target a range of 160 km over on a fully charged battery. The energy efficiency and driving range of EVs varies substantially based on driving conditions and driving habits. Extreme outside temperatures tend to reduce range, because more energy must be used to heat or cool the cabin. High driving speeds reduce range because of the energy required to overcome increased drag. Compared with gradual acceleration, rapid acceleration reduces range. Additional devices significant inclines also reduces range. Based on these driving modes and climate conditions, this paper discusses the performance characteristics of EVs on energy efficiency and driving range. Test vehicles were divided by low / high-speed EVs. The difference of test vehicles are on the vehicle speed and size. Low-speed EVs is a denomination for battery EVs that are legally limited to roads with posted speed limits as high as 72 km/h depending on the particular laws, usually are built to have a top speed of 60 km/h, and have a maximum loaded weight of 1,400 kg. Each vehicle test was performed according to the driving modes and test temperature ($-25^{\circ}C{\sim}35^{\circ}C$). It has a great influence on fuel efficiency amd driving distance according to test temperature conditions.

• Environmental and Resource Economics Review
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• v.17 no.3
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• pp.91-134
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• 2008

Korean district heating companies levy comprehensive construction fee on consumers in the beginning of construction period and the consumers' burden is much higher than those in any other network industries in Korea. It has also many problems such as inappropriate fee calculation method, cross subsidization, property right dispute, etc.. I show that the cut of construction fee by 30% and at the same time, the upward adjustment of tariff rates by 4~6% for 20 years on average will maintain current profitability based on the standard model simulation, I also suggest that fixed charge part of double tariff should be increased to 25% of total tariff and the cut of construction fee should be levied on fixed charge, directly to improve efficiency.

• Bulletin of the Korean Chemical Society
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• v.27 no.8
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• pp.1175-1180
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• 2006

Si-C composites were prepared by the carbonization of polyaniline (PAn) coated on silicone powder. The physical and electrochemical properties of the Si-C composites were characterized by particle-size analysis, X-ray diffraction, scanning electron microscopy, and battery electrochemical tests. The average particle size of Si was increased by the coating of Pan but somewhat reduced by the carbonization to give silicone-carbon composites. The co-existence of crystalline silicone and amorphous-like carbon was confirmed by XRD analyses. SEM photos showed that the silicone particles were well covered with carbonaceous materials, depending on the PAn content. Si-C$\mid$Li cells were fabricated using the Si-C composites and tested using galvanostatic charge-discharge. Si-C$\mid$Li cells gave better electrochemical properties than Si|Li cells. Si-C$\mid$Li cells using Si-C from HCl-undoped precursor PAn showed better electrochemical properties than precursor PAn doped in HCl. The addition of an electrolyte containing 4-fluoroethylene carbonate (FEC) increased the initial discharge capacity. Also, another electrochemical test, the galvanostatic charge-discharge test with GISOC (gradual increasing of the state of charge) was carried out. Si-C(Si:PAn = 50:50 wt. ratio)|Li cell showed 414 mAh/g of reversible specific capacity, 75.7% of IIE (initial intercalation efficiency), 35.4 mAh/g of IICs (surface irreversible specific capacity).

• Journal of the Korean Society of Environmental Restoration Technology
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• v.19 no.1
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• pp.111-120
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• 2016

This study is aimed at using the grasped problems of protected areas in Korea as the basic data for management planning and system improvement of protected areas by grasping realistic problems through the interview with the persons in charge on the basis of general problems of domestic protected areas. To this end, this study deducted major problems in urgent need of improvement, and improvement direction through the survey of the persons in charge of protected areas. This study result is as follows: The major problems, which should be preferentially improved, were found to be shortages of management infrastructure, cooperation between interested parties, and threat factors in protected areas, etc. Such problems are interconnected with each other, thus coming up complexly; therefore, it's necessary to make a comprehensive approach to the problems after confirming the causal relationship of the identified problems. In addition, for the purpose of effective management of a protected area, it's necessary to implement priority management of major problems through different management intensity from the planning phase. Also, it's important to enhance the effectiveness of planning by considering a possible potential threat factor in the outside of protected areas, and referring to the contents of the development plan for the relevant area in time of management planning. Lastly, there is the need for systematic improvement of an institution through thorough status review of the actual state of management planning fulfillment in order to increase the effectiveness of planning in a follow-up study hereafter.

• Korean Journal of Soil Science and Fertilizer
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• v.51 no.2
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• pp.128-141
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• 2018

Industrial complex releasing huge amounts of dusts, fumes and wastewater containing heavy metal(loid)s could be a source of heavy metal(loid)s pollution in arable soil. Heavy metal(loid)s pollution in arable soil adversely affect crops safety, subsequently human being. Hence, it is important to accurately assess the heavy metal(loid)s pollution in soil using pollution indices. The objectives of this study are 1) to compare assessment methods of heavy metal(loid)s pollution in arable soils located near industrial complex in Gyeongsang provinces and 2) to determine the relationship between concentration of plant available heavy metal(loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 10 industrial complex in Gyeongsang provinces. The average total concentration of all heavy metal(loid)s of the studied soils was higher than that of Korean arable soils but did not exceed the warning criteria established by the Soil Environmental Conservation Act of Korea. Only six sites of arable soils for the total concentration of As, Cu and Ni exceeded the warning criteria (As: $25mg\;kg^{-1}$, Cu: $150mg\;kg^{-1}$, Ni: $100mg\;kg^{-1}$). The contamination factor (CF) and geoaccumulation index ($I_{geo}$) of the heavy metal(loid)s in arable soils varied among the sampling sites, and the average values of As and Cd were relatively higher than that of other metals. Results of integrated indices of As and Cd in arable soils located near industrial complex indicated that some arable soils were moderately or heavily polluted. The plant available concentration of heavy metal(loid)s was negatively related to the soil pH and negative charge of soil. Available Cd, Pb, and Zn concentrations had relatively high correlation coefficient with pH and negative charge of soil when compared with other heavy metal(loid)s. Based on the above results, it might be a good soil management to control pH with soil amendments such as lime and compost to reduce phytoavailability of heavy metal(loid)s in arable soil located near industrial complex.

• Hwankyungkyoyuk
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• v.24 no.2
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• pp.112-130
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• 2011

The study is aimed to investigate the current status of ESD(Education for Sustainable Development) programs in private sector(businesses) carried out in Korea since UN DESD was launched in 2005, For this purpose we conducted a questionnaire survey and case studies on those companies who have supposedly pursued sustainability management Results of questionnaire surveys showed that those in charge of writing sustainability reports in companies had an extremely high understanding of SO, but were not well aware of ESD. These businesses started to pursue sustainable management due to global trends and decisions of CEOs, and most of them had divisions that took charge of or are responsible for sustainable management Sustainability issues that they mainly dealt with were corporate social responsibility, energy and climate change, but other issues were being covered, too. Internal stakeholders got involved in projects related to sustainability from the planning stage. Learning on sustainable management was primarily made through information delivery, and education programs were usually conducted for staff members and executives. Those who cooperated on their sustainable development projects were mostly local communities, universities, etc. They had few ESD programs that they directly developed and carried out, and few cases of ESD-related cooperation; and in those few cases, their partners were often elementary/middle/high schools and universities. Results of ESD case studies and questionnaire surveys showed that businesses dealt with various issues of sustainable development in addition to corporate social responsibility and diversified education programs were carried out inside these companies, Business themselves, therefore, need to be considered and researched in further detail as important targets of ESD as well as supporters or cooperation partners on ESD programme.