• Bulletin of the Korean Chemical Society
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• v.22 no.1
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• pp.53-58
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• 2001

Sulfonated poly(phenylene sulfide) (SPPS) polymers were prepared by sulfonation of poly[methyl[4-(phenylthio) phenyl]sulfonium trifluoromethanesulfonate] (PPST) with fumic sulfonic acid (10% $SO_3-H_2SO_4$) and demethylation with aqueous NaOH solution. The equilibrium constants of ion exchange reactions between alkali metal cations ($Li^+,\;Na^+,\;and\;K^+$) and SPPS ion exchanger in organic solvents such as tetrahydrofuran (THF) and dioxane were measured. The equilibrium constants of ion exchange reactions increased as the polarity of the solvent increased, and the reaction temperature decreased. The equilibrium constants of the ion exchange reaction ($K_{eq}$) also increased in the order of $Li^+,\;Na^+,\;and\;K^+$. To elucidate the spontaneity of the exchange reaction in organic solvents, the enthalpy, entropy, and Gibbs free energy were calculated. The enthalpy of reaction ranged from -0.88 to -1.33 kcal/mol, entropy ranged from 1.42 to 4.41 cal/Kmol, and Gibbs free energy ranged from -1.03 to -2.55 kcal/mol. Therefore, the exchange reactions were spontaneous because the Gibbs free energies were negative. The SPPS ion exchanger and alkali metal ion bounding each other produced good ion exchange capability in organic solvents.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.7 s.238
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• pp.814-819
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• 2005

The phase change heat transfer has been applied to the processes of machines as well as of manufacturing. The cycle in a heat exchanger includes the phase change phenomena of coolant for air conditioning, the solidification in casting process makes use of the characteristics of phase change of metal, and the welding also proceeds with melting and solidification. To predict the phase change processes, the experimental and numerical approaches are available. In the case of numerical analysis, the Enthalpy method is most widely applied to the phase change problem, comparing to the other numerical methods, i.e. the Equivalent Specific Heat method and the Temperature Recovery method. It's because that the Enthalpy method is accurate and straightforward. The Enthalpy method does not include any correction step while the correction of final temperature field is inevitable in the Equivalent Specific Heat method and the Temperature Recovery method. When the temperature field is to be used in the calculation, however, there must be converting process from enthalpy to temperature in the calculation scheme of Enthalpy method. In this study, an improved method for the Equivalent Specific Heat method is introduced whose method dose not include the correction steps and takes temperature as an independent variable so that the converting between enthalpy and temperature does not need any more. The improved method is applied to the solidification process of pure metal to see the differences of conventional and improved methods.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.317-322
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• 2008

The objectives of this paper are to study the effects of thermal and geometric conditions on the performance of indoor heat exchanger with R410A for Gas Engine Driven Heat Pump (GHP) application and to find optimum design conditions of indoor heat exchanger by parametric analysis for the key parameters. In the air side, moisture out of the humid air condenses on the fin surface while the refrigerant (R410A) boils inside the smooth tube. Therefore this study uses Log Mean Enthalpy Difference (LMHD) method to analyze the heat transfer from the humid air to the refrigerant of R410A. The results show that fin pitch and longitudinal pitch have significant effect on the heat exchanger preformance. This study will provide the guideline for optimum design of indoor heat exchanger with R410A for GHP application.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.6
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• pp.372-380
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• 2008

In order to control indoor air quality and save energy, it is needed to install a suitable ventilation system equipped with heat exchanger for heat recovery. Paper heat exchanger can recover $50{\sim}70%$ of the enthalpy difference between supply and exhaust air. The purpose of this research is to obtain the experimental correlations for the friction factor, heat transfer coefficient, mass transfer coefficient and permeance of paper heat exchanger, which can be used to predict the performance of the paper heat exchanger. Pressure drops at various velocities, and sensible and latent heat transfer rates at various dry-bulb temperatures, relative humidities and specific humidities are measured to derive experimental correlations. The results of prediction using correlations show fairly good agreement with the experimental data obtained in the actual operating conditions.

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.171-171
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• 2005

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.408-413
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• 2008

This study presents comparison of the air side heat transfer and friction characteristics in a heating condition between Louver fin-tube heat exchangers and aluminum heat exchangers. Experiments are performed for the Louver fin-tube heat exchangers and aluminum heat exchangers using a calorimeter, which is designed based on air-enthalpy method described in ASHRAE standards. The air velocities its are varied from 0.7 to 1.6 m/s with 0.3 m/s interval. A study result shows that the heat transfer performances of aluminum heat exchangers are $40{\sim}80%$ higher than those of Louver fin-tube heat exchangers per unit volume, mass and heat transfer area.

• Journal of the Korean Society of Industry Convergence
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• v.11 no.4
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• pp.157-163
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• 2008

The present study investigated the pressure drop and the total frost mass of the louvered fin type heat exchanger, which is widely used at the air-conditioning system. The pressure drop due to the frosting phenomenon and the total frost mass were investigated by changing the wet bulb temperature condition of the inlet air. Hence the brain of 55wt% was used as a cooling solution instead of a common refrigerant. The temperature difference between the brine and the tube outside wall at the outlet of heat exchanger was $10^{\circ}C$, at maximum, higher than that at the inlet of heat exchanger. As the wet bulb temperatures were increased, the pressure drop was linearly increased due to the increment of frost mass. And the increment of heat exchange rate was smaller than that of inlet air enthalpy due to the increment of frost mass. The pressure drop of air side was rapidly increased due to the progress of frosting phenomena. The run time that the pressure drop occurred rapidly was decreased by the growth of frost.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.519-524
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• 2008

In the present study, the air-side heat transfer and pressure drop characteristics of the fin-tube and PF heat exchangers have been experimentally investigated under the cooling standard condition. Fin type of PF heat exchanger is a triangler and squarer form. The experimental data of the slit fin-tube and two kinds of PF heat exchangers are measured using the air-enthalpy calorimeter and the constant temperature water bath. As the inlet air velocity increases, the heat transfer rate and pressure drop of the heat exchanger increased. The heat transfer rate and pressure drop of PF-2 heat exchanger of the squarer fin is larger than that of PF-1 heat exchanger of the triangler fin. As the inlet air temperature increases, the heat transfer rate decreases and the pressure drop is nearly uniform.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.3
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• pp.470-475
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• 2009

In the present study, the heat transfer characteristics of the fin-tube and PF heat exchangers and the performances of the air-conditioner are experimentally investigated. Also, Cooling Seasonal Performance Factor(CSPF) of the air-conditioner is evaluated. For the heat exchanger experiment, the heat transfer and pressure drop are obtained. For the air-conditioner experiment, the cooling capacity, input power and COP are obtained. The air-enthalpy calorimeter and the constant temperature water bath are used. As the inlet air velocity increases, the heat transfer rate and pressure drop of the heat exchanger increased. PF heat exchanger has smaller refrigerant weight and larger capacity and COP than the fin-tube heat exchanger. The performance of PF-2 heat exchanger with the squarer fin is more excellent than that of PF-1 heat exchanger with the triangler fin. Also, CSPF of the fm -tube and PF heat exchanger is evaluated.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.1002-1007
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• 2009

The research are performed to check the characteristics of the ice slurry transport system for the district cooling. The system are installed at the 1st floored building which is as large as the $1204\;m^2$ ($86\;m{\times}14\;m$). Three kinds of heat exchanger are selected, such as, plate, spiral and shell & tube type, to apply to the ice slurry systems. Experiment was done in the two cases. The first case, circulation water flow fixed at the design conditions for the state to change the flow of the supply of ice slurry. The second case, Ice slurry flow fixed at the design conditions for the state to change the flow of circulation water. Both side of Energy balance was calculated. The performance of plate heat exchanger is higher than others and it's enthalpy effectiveness is higher too.