• Korean Chemical Engineering Research
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• 제55권2호
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• pp.253-257
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• 2017

그래핀은 $sp^2$ 결합으로 이루어진 한 겹의 탄소 물질이며, 그래핀 본래의 우수한 물성으로 인해 다양한 분야에서 활용되고 있다. 그래핀의 높은 전기전도도와 전하이동도로 인해서 (광)전자 소자 물질로 주목받고 있다. 화학적 도핑 과정을 통해 n 형과 p 형의 그래핀이 형성 가능하며 이를 이용하여 다양한 구조의 소자 형성이 가능하게 되었다. 본 연구에서 그래핀의 도핑 효과를 선택적으로 증대시키기 위해 유전영동 현상을 도입하였다. 주파수 10 kHz, $5V_{pp}$ (peak-to-peak voltage) 조건에서 유전 영동 현상을 이용하였을 때 금나노입자들이 전극 위치 주변으로 집중됨을 확인하였다. 그래핀의 도핑 효과를 라만 분광법과 전기적 물성 변화를 통하여 조사하였으며, 그래핀에 $AuCl_3$ 용액을 이용한 유전 영동 현상을 통하여, 그래핀 기반 소자의 국소적인 부분에 선택적으로 화학적 도핑이 가능함을 확인하였다. 이러한 연구는 그래핀 기반 소자와 interconnection 등에 활용될 수 있을 것으로 기대된다.

• 한국재료학회지
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• 제20권9호
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• pp.472-477
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• 2010

$Al_2O_3$ has received wide attention with established use as a catalyst and growing application in structural or functional ceramic materials. On the other hand, the boehmite (AlO(OH)) obtained by sol-gel process has exhibited a decrease in surface area during phase transformation due to a decline in surface active site at high temperature. In this work, $Al_2O_3$-CuO/ZnO (ACZ) and $Al_2O_3$-CuO/CeO (ACC) composite materials were synthesized with aluminum isopropoxide, copper (II) nitrate hemi (pentahydrate), and cerium (III) nitrate hexahydrate or zinc (II) nitrate hexahydrate. Moreover, the Span 80 as the template block copolymer was added to the ACZ/ACC composition to make nano size particles and to keep increasing the surface area. The ACZ/ACC synthesized powders were characterized by Thermogravimetry-Differential Thermal analysis (TG/DTA), X-ray Diffractometer (XRD), Field-Emmision Scanning Electron Microscope (FE-SEM), Bruner-Emmett-Teller (BET) surface analysis and thermal electrical conductivity (ZEM-2:M8/L). An enhancement of surface area with the addition to Span 80 surfactant was observed in the ACZ powders from 105 $m^2$/g to 142 $m^2$/g, and the ACC powders from 103 $m^2$/g to 140 $m^2$/g, respectively.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.380-380
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• 2010

Currently, organic light-emitting diodes (OLEDs) have been proven of their readiness for commercialization in terms of lifetime and efficiency. In accordance with emerging new technologies, enhancement of light efficiency and extension of application fields are required. Particularly inverted structures, in which electron injection occurs at bottom and hole injection on top, show crucial advantages due to their easy integration with Si-based driving circuits for active matrix OLED as well as large open area for brighter illumination. In order to get better performance and process reliability, usually a proper buffer layer for carrier injection is needed. In inverted top emission OLED, the buffer layer should protect underlying organic materials against destructive particles during the electrode deposition, in addition to increasing their efficiency by reducing carrier injection barrier. For hole injection layers, there are several requirements for the buffer layer, such as high transparency, high work function, and reasonable electrical conductivity. As a buffer material, a few kinds of transition metal oxides for inverted OLED applications have been successfully utilized aiming at efficient hole injection properties. Among them, we chose 2 nm of $WO_3$ between NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] and Au (or Al) films. The interfacial energy-level alignment and chemical reaction as a function of film coverage have been measured by using in-situ ultraviolet and X-ray photoelectron spectroscopy. It turned out that the $WO_3$ interlayer substantially reduces the hole injection barrier irrespective of the kind of electrode metals. It also avoids direct chemical interaction between NPB and metal atoms. This observation clearly validates the use of $WO_3$ interlayer as hole injection for inverted OLED applications.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.423-423
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• 2011

Zinc oxide is metal oxide semiconductor with the 3.37 eV bandgap energy. Zinc oxide is very attractive materials for many application fields. Zinc Oxide has many advantages such as high conductivity and good transmittance in visible region. Also it is cheaper than other semiconductor materials such as indium tin oxide (ITO). Therefore, ZnO is alternative material for ITO. ZnO is attracting attention for its application to transparent conductive oxide (TCO) films, surface acoustic wave (SAW), films bulk acoustic resonator (FBAR), piezoelectric materials, gas-sensing, solar cells and photocatalyst. In this study, we synthesized ZnO nanoparticles and defined their physical and chemical properties. Also we studied about the application of ZnO nanoparticles as a photocatalyst and try to find a enhancement photocatalytic activity of ZnO nanorticles.. We synthesized ZnO nanoparticles using spray-pyrolysis method and defined the physical and optical properties of ZnO nanoparticles in experiment I. When the ZnO are exposed to UV light, reduction and oxidation (REDOX) reaction will occur on the ZnO surface and generate O2- and OH radicals. These powerful oxidizing agents are proven to be effective in decomposition of the harmful organic materials and convert them into CO2 and H2O. Therefore, we investigated that the photocatalytic activity was increased through the surface modification of synthesized ZnO nanoparticles. In experiment II, we studied on the stability of ZnO nanoparticles in water. It is well known that ZnO is unstable in water in comparison with TiO2. Zn(OH)2 was formed at the ZnO surface and ZnO become inactive as a photocatalyst when ZnO is present in the solution. Therefore, we prepared synthesized ZnO nanoparticles that were immersed in the water and dried in the oven. After that, we measured photocatalytic activities of prepared samples and find the cause of their photocatalytic activity changes.

• 한국자원식물학회지
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• 제19권3호
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• pp.411-417
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• 2006

This experiment was conducted to study whether priming with deep sea water results in enhancement of seed germination and to identify the optimum concentration of the priming solution, and duration of priming using sweet pepper (Cv. California wonder), rice (Cv. Ilpum) and ginseng seed. Sweet pepper and rice seeds were primed with 5 various concentrations (5%, 10%, 15%, 20% and 30%) for deep sea water for 48 hours, 24 hours and 12 hours at $25^{\circ}C$ and ginseng seeds in 5%, 10%, 15%, 20%, 25% and 30%, and 2,4,6, and 8 electrical conductivity (EC) which were made by desalinating deep sea water. Priming in deep sea water (DSW) improved the early and final germination percentage, mean germinal on rate, emergence percentage and root and shoot length, compared with plain water, $KNO_3$ and without priming treatments. In sweet pepper, 24 hours priming with 5 percentage DSW significantly improved the early germination percentage and radical length. It has also improved the mean germination and emergence days and early emergence percentage, compared with $KNO_3$ and control. Whereas, in rice, 48 hours priming with 10 percent DSW significantly improved the early germination percentage, plumule emergence percentage, root length and shoot height. Hence the best seed priming treatment on sweet pepper and Rice are 24 hours with 5 percentage DSW and 48 hours with 10 percentage DSW, respectively, whereas in ginseng, priming with EC4, EC8 and 25% DSW had shown better germination.

• 폴리머
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• 제33권4호
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• pp.333-341
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• 2009

폴리프로필렌(PP)/기능화된 다중벽 탄소나노튜브(F-MWNT)나노복합체를 용액 삽입법을 이용해서 제조하였다. 두 종류의 F-MWNT인 dodecanol-MWNT(DDO-MWNT)와 dodecylamine-MWNT(DDA-MWNT)를 포함하는 PP 복합체 필름의 열적, 기계적 성질, 모폴로지, 전기전도도, 필름의 투명도 및 개스투과도 등을 조사하고 그 물성을 구조가 다른 F-MWNT에 따라 서로 비교하였다. 전자 현미경(SEM과 TEM) 사진을 통하여 일부의 MWNT는 잘 분간이 되었으나 그렇지 않은 부분도 확인하였다. 적은 양의 F-MWNT가 첨가되어도 PP 복합체 필름의 열적 기계적 물성이 향상되었으며, 2 wt%에서 최대값을 보여주었다. 일반적으로 PP 복합체 필름의 초기 탄성율과 광학 투명도에서 DDO-MWNT가 DDA-MWNT 보다 더 효과적이었나.

• 한국항공우주학회지
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• 제41권12호
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• pp.975-986
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• 2013

기존 위성 전자장비 하우징에 널리 사용되는 알루미늄 합금 소재를 경량 복합재료로 대체함으로써 위성 경량화를 크게 개선하고자, 경량 복합재료로 구성된 전자장비 하우징을 제작하고 성능 검증에 대하여 다루었다. 이를 위해 복합재료의 낮은 가공성을 극복하기 위하여 후처리를 최소화할 수 있는 복합재료 하우징 제작공정을 설계하고, 격자 구조로 강화된 일체형 하우징 본체를 동시경화 방법에 의해 제작하였다. 또한 제작된 전자장비 하우징의 내구성, 강성, 열전도도, 전기전도도, EMI차폐 및 방사차폐에 대한 성능 평가 결과를 분석하였다. 아울러 본 연구에서 제작한 복합재료 하우징은, 동일한 형상의 알루미늄 하우징 대비 상당한 질량절감을 가능하게 함을 제시하였다.

• Nuclear Engineering and Technology
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• 제40권1호
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• pp.21-36
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• 2008

High bum-up fuel technology has been developed through a national R&D program, which covers key technology areas such as claddings, $UO_2$ pellets, spacer grids, performance code, and fuel assembly tests. New cladding alloys were developed through alloy designs, tube fabrication, out-of-pile test and in-reactor test. The new Zr-Nb tubes are found to be much better in their corrosion resistance and creep strength than the Zircaloy-4 tube, owing to an optimized composition and heat treatment of the new Zr-Nb alloys. A new fabrication technology for large grain $UO_2$ pellets was developed using various uranium oxide seeds and a micro-doping of Al. The uranium oxide seeds, which were added to $UO_2$ powder, were prepared by oxidizing and heat-treating scrap $UO_2$ pellets. A $UO_2$ pellet containing tungsten channels was fabricated for a thermal conductivity enhancement. For the fuel performance analysis, new high burnup models were developed and implemented in a code. This code was verified by an international database and our own database. The developed spacer grid has two features of contoured contact spring and hybrid mixing vanes. Mechanical and hydraulic tests showed that the spacer grid is superior in its rodsupporting, wear resistance and CHF performance. Finally, fuel assembly test technology was also developed. Facilities for mechanical and thermal hydraulic tests were constructed and are now in operation. Several achievements are to be utilized soon by the Korea Nuclear Fuel and thereby contribute to the economy and safety of PWR fuel in Korea

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.129.1-129.1
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• 2011

최근 급격한 경제성장과 고도 산업사회로의 전환에 따라 에너지 수요가 크게 증가하고 있다. 이에 따라 석유, 가스 등 화석에너지의 소비량과 온실가스 배출량이 급격히 늘어나고 있는 실정이다. 따라서 화석에너지의 소비와 온실가스 배출을 저감시키기 위해 친환경적인 에너지를 이용하기 위한 많은 연구가 이루어지고 있다. 이와 같은 노력 중 하나가 바로 태양열에너지를 이용하는 방법이다. 태양열에너지는 자원 고갈의 우려가 없고, 에너지의 이용 과정에서 공해 물질을 배출하지 않아 대체 에너지원으로 각광을 받고 있다. 하지만 에너지 밀도가 낮고 에너지의 공급이 기상조건에 따라 큰 영향을 받으므로 태양열에너지를 이용하기 위해서는 효율적인 집열시스템이 필요하다. 따라서 본 연구에서는 우수한 열적특성을 가진 탄소나노유체를 히트파이프 작동유체에 적용하여, 태양열 집열기의 효율을 향상시키기 위해 탄소나노유체의 열전도도 및 점도특성을 비교분석하였다. 나노유체는 에탄올에 산화 다중벽 탄소나노튜브(Oxidized Multi-walled Carbon Nanotubes, OMWCNTs)를 혼합하고, 초음파 분산하여 제조하였다. 에탄올-산화탄소나노유체의 열전도도와 점도는 저온($10^{\circ}C$), 상온($25^{\circ}C$), 고온($70^{\circ}C$)에서 측정하여 비교분석하였으며, 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 점도는 회전형 디지털 점도계를 이용하였다. 실험 결과 0.1 vol%의 에탄올-산화탄소나노유체의 열전도도는 기본 유체 대비 33.72%($10^{\circ}C$), 33.14%($25^{\circ}C$), 32.26%($70^{\circ}C$)가 향상되었으며, 점도 또한 기본유체보다 크게 증가하지 않아 히트파이프 작동유체로서 우수한 효과를 나타낼 수 있음을 확인하였다. 본 연구의 결과는 태양열 집열기 히트파이프의 효율 향상을 위한 기초자료로써 유용한 정보를 제공할 것이라 판단된다.

• 대한치과보철학회지
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• 제38권5호
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• pp.595-605
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• 2000

Dental ceramics have good aesthetics, biocompatibility, low thermal conductivity, abrasion resistance, and color stability. However poor resistance to fracture and shrinkage during firing process have been limiting factors in their use, particularly in multiunit ceramic restorations. A new method for making all-ceramic crowns that have high strength and low processing shrinkage has been developed and is referred to as the Vita In-Ceram method. This study was performed to investigate the effect of $CeO_2$ addition in borosilicate glasses on the strength of alumina-glass composites. Porous alumina compacts were prepared by slip casting and sintered at $1,100^{\circ}C$ for 2 hours. Dense composites were made by infiltration of molten glass into partially sintered alumina at $1,140^{\circ}C$ for 4 hours. Specimens were polished sequentially from #800 to #2000 diamond disk. and the final surface finishing on the tensile side was received an additional polishing sequence through $1{\mu}m$ diamond paste. Biaxial flexure test was conducted by using ball-on-three-ball method at a crosshead speed of 0.5mm/min. To examine the microstructural aspect of crack propagation in the alumina-glass composites, Vickers-produced indentation crack was made on the tensile surface at a load of 98.0 N and dwell time of 15 sec, and the radial crack patterns were examined by an optical microscope and a scanning electron microscope. The results obtained were summarized as follows; 1. The porosity rates of partially sintered alumina decreased with the rising of firing temperature. 2. The maximum biaxial flexure strength of 423.5MPa in alumina-glass composites was obtained with an addition of 3 mol% $CeO_2$ in glass composition and strength values showed the aspect of decrease with the increase of $CeO_2$ content. 3 The biaxial flexure strength values of alumina-glass composites were decreased with rising the firing temperature. 4. Observation of the fracture surfaces of alumina-glass composites indicated that the enhancement of strength in alumina-glass composites was due to the frictional or geometrical inter-locking of rough fracture surfaces and ligamentary bridging by intact islands of materials left behind the fracture front.