• Title/Summary/Keyword: Enhanced Coagulation

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Removal of NOM in a Coagulation Process Enhanced by Modified Clay (개질 Clay를 첨가한 응집공정에서의 자연유기물 제거)

  • Park, Ji-Hye;Lee, Sang-Yoon;Park, Hung-Suck
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.37-46
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    • 2007
  • A feasibility test was conducted to evaluate the addition of turbidity substance in a coagulation process to remove natural organic matters (NOM), the precursor of disinfection by-products (DBPs). The experimental water sources were synthetic water containing 5 mg/L of humic acid and 50 mg/L of NaHCO3 and drinking water resource of Ulsan city (S Dam water, D Dam water and Nak-Dong raw water). The examined turbidity substances were kaolin, acid clay, and modified clay (0.38 meq $NH_4{^+}-N/g$ clay). In Jar tests at different concentrations of the turbidity substances (5, 10, 15, 20, 30 mg/L) using the synthetic water, the turbidity substances improved the removal of turbidity, UV-254 absorbance and dissolved organic carbon (DOC) by 23.8-38.1%, 17.0-24.5% and 2.5-44.5%, respectively. The modified clay showed higher removal efficiencies than other substances. In Jar tests using the drinking water, 10 and 20 mg/L of modified clay enhanced the removal efficiencies of turbidity, UV-254 absorbance, DOC, trihalomethane formation potential (THMFP), and haloacetic acid formation potential (HAAFP) by 3.0~4.3%, 19.1~29.0%, 12~34.9%, 4.9~36.7%, and 1.6~30.2%, respectively.

Effect of operating condition of electro-coagulation on the membrane filtration resistances of activated sludge (전기응집 조건이 활성슬러지 막 여과 저항에 미치는 영향)

  • Hong, Sung-Jun;Chang, In-Soung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.3
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    • pp.2314-2320
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    • 2015
  • MBR (Membrane Bio-Reactor) process is known to consume enormous energy to control membrane fouling. To solve this problem, electro-coagulation technique has been applied to MBR. A series of electro-coagulation was applied to activated sludge suspension under different current density condition. After the electro-coagulations, membrane filtration of the activated sludge suspensions was conducted to investigate the effect of electro-coagulation on the fouling. As current density increased 10 to 40A/m2, the total fouling resistance (Rc+Rf) decreased from 18 to 79%, showing that the electro-coagulation improved the membrane filtration efficiency. Both the organic concentration in bulk and the particles size distribution were not nearly changed before and after the electro-coagulation. The enhanced filtration efficiency might be due to the aluminum hydroxide generated from chemical precipitation, which can be acted as a dynamic membrane preventing a deposition of foulants on membrane surfaces.

The rate and extent of acid indued coagulation of milk protein and physical characteristics of resultant coagulum (산에 의한 응고화에 영향을 미치는 인자들과 형성된 응고물의 물리학적 특징)

  • Bae, Hyuk-Jin;Kim, Byung-Yong;Kim, Myung-Hwan
    • Applied Biological Chemistry
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    • v.35 no.2
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    • pp.69-75
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    • 1992
  • Viscosity changes of acidified milk at the various pH $ranges(5.2{\sim}4.2)$was measured as a function of temperature. The rate and extent of acid-induced coagulation of milk protein were monitored by turbidity changes as a function of temperature, preheating and salt. Relative viscosities of acidified milk were also measured. The coagulation of casein occurred in a specific pH range and was accompanied by a sharp increase in viscosity at pH of $5.0{\sim}5.2$, depending on the heating temperatures. Onset pH of coagulation and maximum coagulation rate were enhanced by increasing temperatures and preheating process and reduced by addition of salt. Relative viscosity of acidified milk was reversed at the same conditions, reflecting the size of casein coagulum formed was related to the coagulation rate.

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Prediction of Coagulation/Flocculation Treatment Efficiency of Dissolved Organic Matter (DOM) Using Multiple DOM Characteristics (다중 유기물 특성 지표를 활용한 용존 유기물질 응집/침전 제거효율 예측)

  • Bo Young Kim;Ka-Young Jung;Jin Hur
    • Journal of Korean Society on Water Environment
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    • v.39 no.6
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    • pp.465-474
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    • 2023
  • The chemical composition and molecular weight characteristics of dissolved organic matter (DOM) exert a profound influence on the efficiency of organic matter removal in water treatment systems, acting as efficiency predictive indicators. This research evaluated the primary chemical and molecular weight properties of DOM derived from diverse sources, including rivers, lakes, and biomasses, and assessed their relationship with the efficiency of coagulation/flocculation treatments. Dissolved organic carbon (DOC) removal efficiency through coagulation/flocculation exhibited significant correlations with DOM's hydrophobic distribution, the ratio of humic-like to protein-like fluorescence, and the molecular weight associated with humic substances (HS). These findings suggest that the DOC removal rate in coagulation/flocculation processes is enhanced by a higher presence of HS in DOM, an increased influence of externally sourced DOM, and more presence of high molecular weight compounds. The results of this study further posit that the efficacy of water treatment processes can be more accurately predicted when considering multiple DOM characteristics rather than relying on a singular trait. Based on major results from this study, a predictive model for DOC removal efficiency by coagulation/flocculation was formulated as: 24.3 - 7.83 × (fluorescence index) + 0.089 × (hydrophilic distribution) + 0.102 × (HS molecular weight). This proposed model, coupled with supplementary monitoring of influent organic matter, has the potential to enhance the design and predictive accuracy for coagulation/flocculation treatments targeting DOC removal in future applications.

Inhibitory Effects on Platelet Aggregation and Blood Coagulation by Concurrent Administration of Trifusal and Ibudilast (Triflusal과 Ibudilast 동시처리에 의한 혈소판응집 및 혈액응고 억제효과)

  • Hwang, In-Young;Sohn, Yoon-Ah;Hwang, Seon-A;Koo, Yean-Kyoung;Kim, Sun-Young;YunChoi, Hye-Sook;Kwon, Soon-Kyoung;Jeong, Choon-Sik
    • YAKHAK HOEJI
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    • v.56 no.4
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    • pp.248-253
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    • 2012
  • This study aims to develop a novel regimen for enhanced efficacy and reduced side effect in inhibiting platelet aggregation and blood coagulation by concurrent administration of triflusal and ibudilast as anticoaggulants. The result shows this combination of triflusal and ibudilast (300~500 ${\mu}M$, respectively) has additive effect in inhibiting platelet aggregation and blood coagulation over the administration of truflusal or ibdilast as a single treatment. This pharmaceutical composition is expected to be useful for the prevention or treatment of various diseases and symptoms, for example, ischemic heart disease, ischemic cerebral infarction, arteriosclerosis, and thrombosis caused by the insertion of a stent.

In Vivo Experimental Study on the Effects of Fluid in Increasing the Efficiency of Radiofrequency Ablation

  • Sun, Yi-Xin;Cheng, Wen;Han, Xue;Liu, Zhao;Wang, Qiu-Cheng;Shao, Hua
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.14
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    • pp.5799-5804
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    • 2014
  • Background: Radiofrequency ablation (RFA) is the most widely used and studied method internationally for the local treatment of liver tumors. However, the extension of coagulation necrosis in one RFA procedure is limited and incomplete coverage of the damaged area can lead to a high local recurrence rate. Objective: In this study, we compared the effects of different solutions in enhancing hepatic radiofrequency by establishing a rabbit VX2 liver cancer model. We also determined the optimal solution to maximise effects on the extent of RFA-induced coagulation necrosis. Methods: Thirty VX2 tumor rabbits were randomly assigned to five groups: group A, RFA alone; group B, RFA with anhydrous ethanol injection; group C, RFA with 5% hypertonic saline injection; group D, RFA with lidocaine injection; and group E, RFA with a mixed solution. Routine ultrasound examinations and contrast-enhanced ultrasound (CEUS) of the ablation areas were performed after RFA. Then, we measured the major axis and transverse diameter and compared the areas of coagulation necrosis induced by RFA. Results: The mean ablation area range increased in groups B, C and especially E, and the scopes were greater compared with group A. Preoperative application of anhydrous ethanol, hypertonic saline, lidocaine and the mixed solution (groups B, C, D and E, respectively) resulted in larger coagulation necrosis areas than in group A (p<0.05). Among the groups, the coagulation necrosis areas in group E was largest, and the difference was statistically significant compared with other groups (p<0.05). Pathological findings were consistent with imaging results. Conclusions: A mixture of dehydrated alcohol, hypertonic saline and lidocaine injected with RFA increases the extent of coagulation necrosis in the liver with a single application, and the mixed solution is more effective than any other injection alone.

Enhanced total phosphorus removal using a novel membrane bioreactor by sequentially alternating the inflow and by applying a two-stage coagulation control based on pre-coagulation (유입흐름 변경 및 전응집 기반 이단응집 제어 적용 MBR을 통한 총인처리 개선 연구)

  • Cha, Jaehwan;Shin, Kyung-Suk;Park, Seung-Kook;Shin, Jung-Hun;Kim, Byung-Goon
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.103-114
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    • 2017
  • A membrane bioreactor by sequentially alternating the inflow and by applying a two-stage coagulation control based on pre-coagulation was evaluated in terms of phosphorus removal efficiency and cost-savings. The MBR consisted of two identical alternative reaction tanks, followed by aerobic, anoxic and membrane tanks, where the wastewater and the internal return sludge alternatively flowed into each alternative reaction tank at every 2 hours. In the batch-operated alternative reaction tank, the initial concentration of nitrate rapidly decreased from 2.3 to 0.4 mg/L for only 20 minutes after stopping the inflow, followed by substantial release of phosphorus up to 4 mg/L under anaerobic condition. Jar test showed that the minimum alum doses to reduce the initial $PO_4$-P below 0.2 mg/L were 2 and 9 mol-Al/mol-P in the wastewater and the activated sludge from the membrane tank, respectively. It implies that a pre-coagulation in influent is more cost-efficient for phosphorus removal than the coagulation in the bioreactor. On the result of NUR test, there were little difference in terms of denitrification rate and contents of readily biodegradable COD between raw wastewater and pre-coagulated wastewater. When adding alum into the aerobic tank, alum doses above 26 mg/L as $Al_2O_3$ caused inhibitory effects on ammonia oxidation. Using the two-stage coagulation control based on pre-coagulation, the P concentration in the MBR effluent was kept below 0.2 mg/L with the alum of 2.7 mg/L as $Al_2O_3$, which was much lower than 5.1~7.4 mg/L as $Al_2O_3$ required for typical wastewater treatment plants. During the long-term operation of MBR, there was no change of the TMP increase rate before and after alum addition.

Evaluations of Coagulation Process for Membrane Pre-treatment using Floc Growth Rate Analyzer (응집 플록 성장률 측정기를 이용한 멤브레인 공정의 전처리 응집공정 평가)

  • Son, Hee-Jong;Kim, Sang-Goo;Kim, Do-Hwan;Kang, So-Won;Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.25 no.2
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    • pp.231-238
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    • 2016
  • In this study, we have investigated to find optimal pre-treatment flocculation condition by analyzing the floc growth rate with mixing conditions and the membrane permeation flux for pre-treatment step of the membrane process. The higher mixing intensity showed a constant floc size index (FSI) values, and lower mixing intensity increased the degree of dispersion of the FSI values. Results of comparing the distribution characteristics of the FSI value and the permeation flux were more effective in increasing flux when the FSI values were 0.2 or higher. The degree of dispersion of FSI was relatively large in 40 rpm mixing condition compared to 120 rpm. In 40 rpm mixing condition, it decreased the permeation flux compared to 120 rpm because various sizes of flocs were distributed. Coagulation-UF membrane process enhanced 30%~40% of the flux rate compare to UF alone process, and the coagulation-MF process increased up to 5% of the flux rate compare to MF alone process. Pre-treatment, that is, coagulation process, has been found to be less effects on relatively larger pore size for MF membrane. For UF membrane, the flux was a little bit same when applying only the rapid mixing process or rapid mixing with slow mixing processes together. In case of MF membrane, the flux was improved when rapid mixing process applied with slow mixing process together.