• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1553-1558
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• 2009

A series of Eu(III) complexes with various neutral ligands (2,2’:6’,2"-terpyridine (T), diglyme (D), 1N-(2-dimethylamino) ethyl)-1N, 2N, 2N-trimethylethane-1,2-diamine (PT), di-(2-picolyl)-amine derivative (HT), and multidentate terpyridine derivative (DT)) were synthesized to investigate the effect of coordination environment on the sensitized luminescence of Eu(III) complexes. The nine coordination sites of the $Eu^{3+}$ ion are occupied by three bidentate carboxylate moieties and one neutral ligand. The highest emission intensity is obtained for $Eu^{3+}$- $[NA]_3$ (PT), due to the difference in energy transfer efficiency and symmetry of the first coordination sphere of $Eu^{3+}$ ion. But, the lowest emission intensity is obtained for $Eu^{3+}$-$[NA]_3$(T). Terpyridine may not play an important role antenna for photosensitizing $Eu^{3+}$ ion. It could be attributed to the weak spectral overlap integral J value between its phosphorescence band and $Eu^{3+}$ion absorption band. Therefore, different coordination environment of $Ln^{3+}$ ion play an important role in providing sensitization of lanthanide ion emission.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.71-84
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• 2020

In order to improve the performance of marine centrifugal pump, a centrifugal pump whose specific speed is 66.7 was selected for the research. Outlet diameter D2, outlet width b2, blade outlet angle β2, blade wrap φ and blade number z of the impeller were chosen as the variables. The maximum weighted average efficiency and the minimum vibration intensity at the base were calculated as objectives. Based on the Latin Hypercube method, the impeller was numerically optimized. The numerical results show that after optimization, the amplitudes of pressure fluctuation on the main frequency at different monitoring points decrease in varying degrees. The radial force on impeller decreases obviously under off-design flow rates and is more symmetrical during the operation of the pump. The variation of the axial force is relatively small, which has no obvious relationship with the rotating angle of the impeller. The energy performance and vibration experiment was performed for verifying. The test results show that the weighted average efficiency under 0.8Qd, 1.0Qd and 1.2Qd increases by 4.3% after optimization. The maximal vibration intensity at M1-M4 on the pump base reduced from 0.36 mm/s to 0.25 mm/s, decreasing by 30.5%. In addition, the vibration velocities of bracket in pump side and outlet flange also have significant reductions.

• 대한환경공학회지
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• 제27권2호
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• pp.163-169
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• 2005

본 연구에서는 인공 UV lamp의 대체에너지로 무한한 청정에너지인 태양광을 광원으로 이용하여 Cu(II)-EDTA 제거를 위한 광촉매 산화반응을 실시하였다. Cu(II)-EDTA의 광촉매 산화반응의 효율에 관한 연구를 위해 집광반사판의 형태, 집광반사판의 입사각, 광세기, 유량, 반응면적, $H_2O_2$의 효율, 그리고 광촉매 형태의 변화에 따라 실시하였다. Cu(II)와 DOC 제거율은 평판형의 집광반사판보다 반구형의 집광반사판 사용시 높게 나타났으며, 반사판의 각도를 $38^{\circ}$까지 증가시킬수록 제거속도 및 제거율이 각각 증가였다. $TiO_2$ 분말시스템은 $TiO_2$ 코팅 시스템보다 Cu(II)와 DOC 제거율에 있어서 약 4배 이상의 큰 제거율을 나타내어서 제거효율에 있어서는 우수한 것으로 조사되었다. Cu(II)와 DOC 모두 자외선 세기가 높은 맑은 날($0.372{\sim}2.265\;mW/cm^2$)에 제거효율이 가장 좋은 것으로 나타났는데, Cu(II)의 경우 흐린날($0.038{\sim}1.129\;mW/cm^2$에 비하여 약 3배, DOC의 경우 약 2배의 높은 제거율이 나타나서 광세기가 양자수율에 직접적으로 영향을 미침을 알 수 있었다. Cu(II)가 제거되는 경향은 반응기의 면적이 클수록 증가하였으며, 유량변동에는 비슷한 경향을 보였지만 일정유량 이상에서는 방해요인이 되는 것으로 나타났다. 코팅된 $TiO_2$를 광촉매로 사용하였을 때 $H_2O_2$ 농도증가에 따라 Cu(II)의 제거효율은 크게 증가하였지만 분말형 $TiO_2$ 사용시에는 이에 비해 $H_2O_2$ 주입효과가 크게 나타나지 않았다.

• 한국자동차공학회논문집
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• 제22권5호
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• pp.84-90
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• 2014

The aim of this paper is to investigate the application of solar energy in reducing cabin thermal load. When a vehicle is parked under the sun in summer, the interior temperature can reach up to $70^{\circ}C$ depending on the solar intensity. Solar power, one of the green energies, is used in automobile air conditioning systems, in order to operate the blower. The power supply of a blower's voltage has been used in a solar sunroof experiment. At the climate wind tunnel, cabin temperature changes were conducted with various operating modes of an air handling system and the preventilation parking conditions of several vehicles, outdoors, was also examined. The test results of the solar sunroof, 39.3W power and 14.1% efficiency were obtained. The thermal load behavior was analysed with the air handling system operating mode differently according to the cabin temperature. By simply operating the blower, average cabin temperature decreased between $5^{\circ}C{\sim}10^{\circ}C$ in those vehicles parked outdoors in summer. This reveals that cabin thermal comfort can be improved without consuming the vehicle's extra energy, and that the performance of the air-conditioning system is better than those currently found in vehicles. Moreover, fuel economy will be increased as a result of the reduction in the use of the air-conditioning system, and many other human advantages will be gained. Such advantages include minimized VOCs and a healthy cabin environment.

• 한국인터넷방송통신학회논문지
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• 제14권6호
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• pp.235-243
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• 2014

본 논문에서는 지능형 LED 실내조명을 위한 효율적인 제어 시스템을 제안한다. 제안된 지능형 LED 실내조명을 위한 효율적인 제어 시스템은 스케줄 정의에 의한 조명 스타일과 재실 감지에 의한 조명 스타일에 PIR 센서와 조도 센서에 의해 측정되는 주광강도와 같은 요소를 포함시켜 무선 센서 네트워크로 점등제어를 하고 에너지 절감을 할 수 있도록 설계하였다. 또한, 재실감지에 의한 실내조명 점등제어는 PIR 센서를 사용하여 미세 움직임을 감지하고, 창측과 내측의 불필요한 조명 밝기 제어는 조도센서를 이용하여 주광의 수준을 측정하여 제어하였으며, 주광 유입량이 많은 경우 창측 조명은 자동으로 어두워지고, 적으면 조명이 자동으로 밝아지도록 설계하였다. 제안하는 지능형 LED 실내조명을 위한 효율적인 제어 시스템의 효율성 검증 결과, 외부 조명이나 주광이 조금이라도 실내로 유입되면 실내조명의 밝기를 실시간으로 제어하여 에너지 절감 효과를 극대화할 수 있었다.

• 공업화학
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• 제30권1호
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• pp.88-94
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• 2019

삼중항-삼중항 소멸에 의한 광에너지 상향전환 기술(triplet-triplet annihilation upconversion, TTA-UC)은 특정 조건을 만족시키는 유기물들의 에너지 전달 및 융합 과정에 의해 저에너지의 광자를 고에너지의 광자로 변환시키는 신개념 에너지 전환기술이다. 본 연구에서는 실리카 마이크로입자(silica microparticle, SM)를 UC가 구현되는 폴리우레탄 박막 내에 담지 시켜 입사되는 광원의 광산란 효과를 도모함으로써 TTA-UC 효율을 향상시키고, 그 기작에 대해 탐구하였다. Seeded growth method를 통하여 약 950 nm의 균일한 크기를 갖는 SM을 합성하였으며, UC 박막 내에 담지 된 SM의 농도를 증가시킴에 따라 635 nm 광원 조사 시 430-570 nm 영역에서의 UC 세기가 최대 1.64배 증가함을 확인하였다. 삼중항 lifetime 측정을 통하여 광감응제 PdTPBP와 전자수용체 perylene 간의 triplet-triplet energy transfer(TTET) 효율을 분석한 결과, 박막 내에 담지 된 SM이 chromophore 간의 TTET에 미치는 영향은 미미한 것으로 나타났다. 또한, 입사 강도-UC 세기의 상관관계를 분석하여 TTA-UC 효율을 분석한 결과, SM이 박막 내에 존재할 경우 UC 양자효율이 최대 1.5배 향상됨을 확인하였다.

• 한국수자원학회논문집
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• 제30권6호
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• pp.731-741
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• 1997

동일한 원수에 대하여 탁도제거 지배인자를 변화시켜가며 임펠러 형태별 탁도제거효율을 비교함으로써 관습적으로 설계 운영해오던 혼화과정의 문제점과 정수장의 최적 혼화저건을 만족시킬 수 있는 혼화기의 임펠러 타입 및 체류시간에 대한 운전기준을 제시하고자 하였다. 실험결과 혼화기의 종류는 탁도제거 효율을 물론 정수장의 경제적 운영을 위한 전력비 절감에도 효과가 있는 것으로 판명되었다. 또한 혼화지와 혼화기 설계기준에 일반적으로 활용되어 오던 속도구매 G이외에도 원수의 단위체적당 필요한 혼화에너지를 제시하여 정수효율은 물론 정수장의 경제적 운영효과를 극대화시킬 수 있는 참고자료로 제시하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.686-686
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• 2013

Crystalline silicon solar cell is a semiconductor device that converts light into electrical energy. Screen printing is commonly used to form the front/back electrodes in silicon solar cell. Screen printing method is convenient but usually shows high resistance and low aspect ratio, which cause the efficiency decrease in crystalline silicon solar cell. Recently the plating method is applied in c-Si solar cell to reduce the resistance and improve the aspect ratio. In this paper, we investigated the effect of additional electroless Ag plating into screen-printed c-Si solar cell and compared their electrical properties. All wafers used in this experiment were textured, doped, and anti-reflection coated. The electrode formation was performed with screen-printing, followed by the firing step. Aften then we carried out electroless Ag plating by changing the plating time in the range of 20 sec~5 min and light intensity. The light I-V curve and optical microscope were measured with the completed solar cell. As a result, the conversion efficiency of solar cells was increased mainly due to the decreased series resistance.

• 한국재료학회지
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• 제17권9호
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• pp.489-492
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• 2007

Temperature and injection current dependence of elctroluminescence(EL) spectral intensity of the $In_{0.27}Ga_{0.73}N/GaN$ multi-quantum-well(MQW) have been studied over a wide temperature and as a function of injection current level. EL peaks also show significant broadening into higher photon energy region with the increase of injection current. This is explained by the band-filling effect. When temperature is slightly increased to 300 from 15 K, the EL emission peak showed red-blue-red shift. It can be explained by the carrier localization by potential fluctuation of multiple quantum well and band-gap shrinkage as temperature increase. It is found that a temperature-dependent variation pattern of the EL efficiency under very low and high injection currents show a drastic difference. This unique EL efficiency variation pattern with temperature and current is explained field effects due to the driving forward bias in presence of internal(piezo and spontaneous polarization) fields.

• KEPCO Journal on Electric Power and Energy
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• 제7권1호
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• pp.153-159
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• 2021

A two-step process for increasing the leaching efficiency of yttrium and neodymium from coal fly ash were investigated at solid loadings of 5.0 g ash ~1,000 g ash/l of 1.0 N~10.0 N H₂SO₄, temperature ranging from 30℃ to 90℃, ultrasonic leaching time of 1~10 hours, and ultrasonic power of 25~200 W. The yttrium and neodymium from coal fly ash were effectively leached into ion phases by step change of the first conventional dissolution at room temperature and then the second heating process with the aid of ultrasonic wave, and maximum leaching efficiency of yttrium and neodymium obtained were 66 % and 63 %, respectively. The activation energies for the leaching reaction of yttrium and neodymium at second heating process dependent on leaching time and temperature were derived to be 41.540 kJmol^-1 and 507.92 kJmol^-1, respectively. The optimum conditions for the maximum leaching of yttrium and neodymium were found to be the solid loading of 250 g ash/l of H₂SO₄, solvent concentration of 2.0 N H₂SO₄, and second step process of temperatures of 30℃ for 3 hours and then 90℃ for 4 hours with ultrasonic intensity of 100 W.