• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.319-319
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• 2011

Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

• Journal of Radiation Protection and Research
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• 제20권2호
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• pp.85-95
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• 1995

GM 계수관을 방사선 검출기로서 사용하고, 검출기의 신호를 디지탈 펄스로 변환하는 펄스처리회로와 디지탈 통신방식의 하나인 FSK(frequency shift keying) 변복조회로를 설계하였으며, 휴대용 무전기로 송수신되는 방사선 검출신호를 방사선량과 방사선량율로 개인용 컴퓨터의 화면에 표시하는 단일채널 무선 방사선측정 시스템을 개발하고 성능을 평가하였다. 성능검증 실험에서 펄스를 입력한 경우와 검출기에 방사선을 조사시킨 경우 펄스처리회로에서 약 5V의 동일한 디지탈 펄스가 출력되었고, 무선통신계통에서도 입력과 출력이 왜곡없이 송수신되고 있음을 확인하였다. 검출기에 표준방사선원(Cs-137)으로 방사선을 조사시켜 선량률을 측정한 결과 측정오차는 조사된 선량률의 10% 이내를 나타내었다. 본 시스템은 국내에선 처음으로 설계되었으며, 향후 다중채널로 구성하여 실시간 개인방사선피폭선량계, 방사선감시기 등 여러 용도의 방사선측정기에 응용함으로써 방사선방어에 기여할 것으로 기대된다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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• pp.68-73
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• 2011

This study was performed numerical analysis in order to analyze liquid film flow of heat exchanger tube arrangement and configuration of evaporative multi effect distillation system using medium-temperature. Simulation was accomplished the two-dimensional calculations using commercial analyses program FLUENT based on the FVM(finite volume method). Fresh water generator of this study used Shell & Tubes heat exchanger with Cu_Ni tube, configuration of tube used bare tube and corrugated tube, and arrangement of tube used in-line array and staggered array. Performance of heat exchanger through the formation of liquid film was compared and analyzed. Liquid film flow occurred that falling on heat exchanger tube wall. Result of simulation showed that liquid film thickness of in-line arrangement was found 0.57mm with bare tube and 0.67mm with corrugated tube, respectively. And liquid film thickness of staggered arrangement was found 0.39mm with bare tubes and 0.62mm with corrugated tubes, respectively. Liquid film thickness of corrugated tube showed thicker than bare tube, but heat transfer rates of corrugated tube showed higher than bare tube. The reason was considered that surface area of corrugated tube was wider than bare tube. And liquid film thickness of staggered arrangement showed thinner than in-line arrangement, so thermal performance of staggered arrangement showed higher than in-line arrangement.

• 한국전자통신학회논문지
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• 제12권2호
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• pp.301-308
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• 2017

본 논문은 외란관측기 개념을 이용하여 두 대의 협력적인 발전기를 갖는 풍력발전기의 발전 및 요잉 제어기 설계 방법을 제안한다. 협력형 풍력발전기란 날개축으로부터 공급된 풍력 에너지를 두 대의 발전기를 통하여 협력적으로 전기 에너지로 변환하는 차별화된 구조의 풍력발전기를 의미한다. 이 구조에서 두 대의 발전기는 독립적으로 제어가 가능하기 때문에 두 발전기의 발전부하를 적절하게 협력적으로 제어함으로써 발전과 동시에 추가적인 요잉 메커니즘 없이 넛셀의 요잉제어가 가능하다. 이러한 구조적 특징을 이용하여 본 논문에서는 협력형 풍력발전기의 발전 및 요잉제어가 안정적으로 실행될 수 있도록 외란관측기를 기반으로 하는 제어기를 설계하고 이를 소형발전기 시스템에 적용하여 그 성능을 실험적으로 검증하였다.

• 한국수소및신에너지학회논문집
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• 제23권4호
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• pp.373-381
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• 2012

To determine the performance characteristics of motorcycle engine using biogas for practical use, the intake system of a 110 cc motorcycle engine is properly modified to operate with biogas as a fuel. Biogas is a potentially renewable fuel for replacing gasoline in future, but it has high percentage of $CO_2$ that could lead to slow the burning rate of biogas-air mixture and cause instability in combustion. Thus, the performance characteristics of biogas-fueled motorcycle engines could be different from those of gasoline motorcycle engines. In this paper, the important parameters of performance characteristics (such as: power output, thermal efficiency, fuel consumption, exhaust emission,${\cdots}$) of biogas-fueled motorcycle engine are studied and estimated with change of engine speed and load. The obtained results when operating with biogas are used to compare with that of gasoline fuel under the same operating conditions. Engine speed in the experimental is changed from 1500 rpm (idle-mode) up to 3500 rpm by a step of 500 rpm. Engine load is changed from zero to maximum load with the help of an exciting voltage device from generator-type dynamometer. The experimental results show that the tested engine operated with richer biogas-air mixture than that of gasoline-air mixture under the same test conditions. Biogas-fueled engine gives a higher fuel consumption and lower thermal efficiency under the same power output. Brake thermal efficiency of biogas engine is found to be about 3% lower than gasoline-fueled motorcycle engine for whole range of speed. Exhaust emission of biogas-fueled motorcycle engine (such as: CO, HC) is found to be lower than the limitation level of the emission standards of Vietnam for motorcycle engines (CO <4.5% HC <1200 ppm).

• Corrosion Science and Technology
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• 제9권2호
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• pp.57-66
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• 2010

Since nuclear power plants are being operated under high temperature and high pressure, on-line monitoring technique to detect corrosion could be more effective than off-line method in shut-off period. In this operating condition, electrochemical noise method may be suitable to monitor the corrosion. This paper aims the analysis on the relation between the cracking and electrochemical noise signal of Alloy 600 under U-bending. When electrochemical noise monitoring technique was used during SCC test, it was judge to be obvious that if cracks generate, its generation can be detected by electrochemical current noise. Cracking-related noise was defined as the noise showing 5~10 times greater than the average value of background noise bands. On the base of crack noise, crack initiation time was determined. From SCC test and electrochemical noise monitoring in $25^{\circ}C$, 0.1 M $Na_2S_4O_6$ solution (Reverse U-Bended Alloy 600 SE+), average crack initiation time was obtained as 9,046 seconds and from its initiation time, it could be defined that net crack propagation rate is the crack length divided by ${\Delta}T$(= total test period - crack initiation time). Therefore, average net crack propagation rate was obtained to be $1.18{\times}10^{-9}\;m/s$.

• Journal of Advanced Marine Engineering and Technology
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• 제40권10호
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• pp.894-898
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• 2016

Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

• 설비공학논문집
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• 제25권1호
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• pp.7-13
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• 2013

Bio Clean Room(BCR) and pharmaceutical product manufacturing facilities require careful assessment of many factors, including HVAC, controls, room finishes, process equipment, room operations, and utilities. Flow of equipment, personnel, and product must also be considered along with system flexibility, redundancy, and maintenance shutdown strategies. It is important to involve designers, operators, commissioning staff, quality control, maintenance, constructors, validation personnel, and the production representative during the conceptual stage of design. Critical variables for room environment and types of controls vary greatly with the clean space's intended purpose. It is particularly important to determine critical parameters with quality assurance to set limits and safety factors for temperature, humidity, room pressure, and other control requirements. In this paper, oxygen cluster ion equipment was utilized in order to enhance the indoor air quality and to prevent the airborne infection of ward in hospital. Moreover, the performance test of the equipment was also performed in order to develop the optimal sterilization system of BCR using the equipment.

• 한국지능시스템학회논문지
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• 제22권6호
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• pp.675-680
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• 2012

전 세계적으로 풍력발전은 전력생산을 위해 사용되는 신재생 에너지원 중 가장 빨리 성장하고 있는 분야로 새로 건설되는 풍력발전단지는 전체 전력 생산량에서 많은 부분을 차지해가고 있다. 풍력발전단지의 설치 증가는 더욱 효율적인 운영과 유지보수에 대한 기술 개발을 요구하게 된다. CMS(Condition Monitoring System)는 풍력발전 시스템의 효율적 운영을 가능케 하는 중요한 도구로 운영자에게 기계의 운전 상태에 대한 정보를 제공함과 동시에 유지보수와 관련된 체계적인 정보를 제공한다. 이에 본 연구에서는 풍력발전기의 너셀에 부착된 가속도 센서로부터의 신호에 대한 FFT 분석을 통해 풍력발전기에서 발생될 수 있는 블레이드의 질량 불평형 및 공력 비대칭의 검출을 가능케 하는 진단기법을 제안하고자 하며 제안된 기법의 유용성 확인을 위해 3W급 소형 풍력발전기에의 적용을 통해 제안된 기법의 유용성을 확인하고자 한다.

• Journal of Radiation Protection and Research
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• 제23권1호
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• pp.17-23
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• 1998

자주달개비 4430 클론에 있어서 $^{252}Cf$ 중성자에 의해 유발되는 유전자 돌연변이의 선량반응 관계를 확립함과 동시에 TSH 분홍돌연변이를 유발함에 있어서 X-선에 대비한 중성자의 생물학적 효과비를 산출하였다. 돌연변이의 분석은 공시재료의 방사선조사 후 4주 이상 이뤄졌으며 최대변이율을 보이는 조사후 6일부터 13일까지의 분석결과로부터 돌연변이빈도를 산출하였다 가용한 실험범위 내에서 중성자 선량의 증가에 따라 돌연변이빈도의 선형적 증가 양상을 나타내었다. X-선에 비교하여 산출한 중성자의 RBE값은 3.1에서 6.8의 범위를 보였으며 이러한 값은 일반적으로 인지되고 있는 중성자의 RBE값에 비해 상당히 낮은 값이다.