• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.319-319
• /
• 2011

Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

• Journal of Radiation Protection and Research
• /
• v.20 no.2
• /
• pp.85-95
• /
• 1995

Radiation measuring system using wireless communication method with single channel has been diveloped and tested. In this system, radiation signals from GM tube are transformed into digital pulses in pulse processing circuit and modulated in FSK (frequency shift keying) circuit for digital communication and then wirelessly transmitted to a receiving unit. The digital pulses received are then demodulated in FSK circuit and converted into radiation dose/dose rate in the data acquisition unit to display on the screen of a personal computer. The performance of this system was evaluated by using both a pulse generator and a standard radiation source(Cs-137). In both cases, digital pulses with 5V were observed in pulse processing circuit without distortion of their shape through wireless communication system. The experimental results of radiation measurement by this system after several test-irradiation of GM detector to a standard radiation source(Cs-137), showed good agreement with irradiation dose rate within 10% difference, and proved that this system could be effectively utillized as radiation measuring instrument. It is expected that this wireless radiation measuring system developed for the first time in Korea, can be used as a radiation monitor as well as a personal dosimeter if we can further improve this system to adopt wireless multichannel communication system.

• 한국태양에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.68-73
• /
• 2011

This study was performed numerical analysis in order to analyze liquid film flow of heat exchanger tube arrangement and configuration of evaporative multi effect distillation system using medium-temperature. Simulation was accomplished the two-dimensional calculations using commercial analyses program FLUENT based on the FVM(finite volume method). Fresh water generator of this study used Shell & Tubes heat exchanger with Cu_Ni tube, configuration of tube used bare tube and corrugated tube, and arrangement of tube used in-line array and staggered array. Performance of heat exchanger through the formation of liquid film was compared and analyzed. Liquid film flow occurred that falling on heat exchanger tube wall. Result of simulation showed that liquid film thickness of in-line arrangement was found 0.57mm with bare tube and 0.67mm with corrugated tube, respectively. And liquid film thickness of staggered arrangement was found 0.39mm with bare tubes and 0.62mm with corrugated tubes, respectively. Liquid film thickness of corrugated tube showed thicker than bare tube, but heat transfer rates of corrugated tube showed higher than bare tube. The reason was considered that surface area of corrugated tube was wider than bare tube. And liquid film thickness of staggered arrangement showed thinner than in-line arrangement, so thermal performance of staggered arrangement showed higher than in-line arrangement.

• The Journal of the Korea institute of electronic communication sciences
• /
• v.12 no.2
• /
• pp.301-308
• /
• 2017

This paper proposes a disturbance observer based controller design method for generating and yawing control of windturbine with two cooperative generators. Windturbine system with two cooperative generators is a distinct structure in which the wind energy supplied by blade axis is converted into electrical energy by two cooperative generators. In this structure, two generators can be controlled independently and therefore they can generate power, simultaneously performing yawing control of nacelle without extra yawing mechanism by cooperatively controlling generating load in appropriate manner. Using this structural trait, this paper designs a disturbance observer based controller that enables the windturbine system with cooperative generators to generate and yaw stably, and verifies the performance of the controller experimentally by applying it to a small-scale windturbine system with the same structure.

• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.4
• /
• pp.373-381
• /
• 2012

To determine the performance characteristics of motorcycle engine using biogas for practical use, the intake system of a 110 cc motorcycle engine is properly modified to operate with biogas as a fuel. Biogas is a potentially renewable fuel for replacing gasoline in future, but it has high percentage of $CO_2$ that could lead to slow the burning rate of biogas-air mixture and cause instability in combustion. Thus, the performance characteristics of biogas-fueled motorcycle engines could be different from those of gasoline motorcycle engines. In this paper, the important parameters of performance characteristics (such as: power output, thermal efficiency, fuel consumption, exhaust emission,${\cdots}$) of biogas-fueled motorcycle engine are studied and estimated with change of engine speed and load. The obtained results when operating with biogas are used to compare with that of gasoline fuel under the same operating conditions. Engine speed in the experimental is changed from 1500 rpm (idle-mode) up to 3500 rpm by a step of 500 rpm. Engine load is changed from zero to maximum load with the help of an exciting voltage device from generator-type dynamometer. The experimental results show that the tested engine operated with richer biogas-air mixture than that of gasoline-air mixture under the same test conditions. Biogas-fueled engine gives a higher fuel consumption and lower thermal efficiency under the same power output. Brake thermal efficiency of biogas engine is found to be about 3% lower than gasoline-fueled motorcycle engine for whole range of speed. Exhaust emission of biogas-fueled motorcycle engine (such as: CO, HC) is found to be lower than the limitation level of the emission standards of Vietnam for motorcycle engines (CO <4.5% HC <1200 ppm).

• Corrosion Science and Technology
• /
• v.9 no.2
• /
• pp.57-66
• /
• 2010

Since nuclear power plants are being operated under high temperature and high pressure, on-line monitoring technique to detect corrosion could be more effective than off-line method in shut-off period. In this operating condition, electrochemical noise method may be suitable to monitor the corrosion. This paper aims the analysis on the relation between the cracking and electrochemical noise signal of Alloy 600 under U-bending. When electrochemical noise monitoring technique was used during SCC test, it was judge to be obvious that if cracks generate, its generation can be detected by electrochemical current noise. Cracking-related noise was defined as the noise showing 5~10 times greater than the average value of background noise bands. On the base of crack noise, crack initiation time was determined. From SCC test and electrochemical noise monitoring in $25^{\circ}C$, 0.1 M $Na_2S_4O_6$ solution (Reverse U-Bended Alloy 600 SE+), average crack initiation time was obtained as 9,046 seconds and from its initiation time, it could be defined that net crack propagation rate is the crack length divided by ${\Delta}T$(= total test period - crack initiation time). Therefore, average net crack propagation rate was obtained to be $1.18{\times}10^{-9}\;m/s$.

• Journal of Advanced Marine Engineering and Technology
• /
• v.40 no.10
• /
• pp.894-898
• /
• 2016

Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.25 no.1
• /
• pp.7-13
• /
• 2013

Bio Clean Room(BCR) and pharmaceutical product manufacturing facilities require careful assessment of many factors, including HVAC, controls, room finishes, process equipment, room operations, and utilities. Flow of equipment, personnel, and product must also be considered along with system flexibility, redundancy, and maintenance shutdown strategies. It is important to involve designers, operators, commissioning staff, quality control, maintenance, constructors, validation personnel, and the production representative during the conceptual stage of design. Critical variables for room environment and types of controls vary greatly with the clean space's intended purpose. It is particularly important to determine critical parameters with quality assurance to set limits and safety factors for temperature, humidity, room pressure, and other control requirements. In this paper, oxygen cluster ion equipment was utilized in order to enhance the indoor air quality and to prevent the airborne infection of ward in hospital. Moreover, the performance test of the equipment was also performed in order to develop the optimal sterilization system of BCR using the equipment.

• Journal of the Korean Institute of Intelligent Systems
• /
• v.22 no.6
• /
• pp.675-680
• /
• 2012

Wind energy is currently the fastest growing source of renewable energy used for electrical generation around the world. Wind farms are adding a significant amount of electrical generation capacity. The increase in the number of wind farms has led to the need for more effective operation and maintenance. CMS(Condition Monitoring System) can be used to aid plant operator in achieving these goals. Its aim is to provide operators with information regarding th e health of their machine, which in turn, can help them improve operation efficiency. In this work, wind turbine fault diagnostic algorithm which can diagnose the mass unbalance and aerodynamic asymmetry of the blades is proposed. Proposed diagnostic algorithm utilizes both FFT(Fast Feurier Transform) of the signal from accelerometers installed inside of nacelle and simple diagnostic logic. Furthermore, to verify the applicability of the proposed system, 3W small sized wind turbine system is tested and physical experiments are carried out.

• Journal of Radiation Protection and Research
• /
• v.23 no.1
• /
• pp.17-23
• /
• 1998

Dose response relationships for one of biological end-points (gene mutation) in somatic cells of Tradescantia 4430 clones were studied using neutrons coming out of a californium-252 isotopic source. And the relative biological effectiveness (RBE) of neutrons in relation to X-rays in the induction of TSH pink mutations was assessed. Inflorescences were irradiated with X-ray from X-ray generator and neutrons from $^{252}Cf$ source. Irradiated cuttings were incubated with aeration in neutrient solution under the controlled condition. For more than 4 weeks after irradiation cell mutations were scored. Pink mutation frequencies were calculated from the pooled data for the peak interval (days 6 to 13 post-irradiation). Somatic cell mutations in TSH showed linear dose response relationships in the range of neutron doses available for the experiment. The RBE values estimated for neutrons in relation to X-rays were in the range 3.1 to 6.8, which were much lower than normally recognized value.