• Title/Summary/Keyword: Energy distribution

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Applications of XPS and SIMS for the development of Si quantum dot solar cell

  • Kim, Gyeong-Jung;Hong, Seung-Hwi;Kim, Yong-Seong;Lee, U;Kim, Yeong-Heon;Seo, Se-Yeong;Jang, Jong-Sik;Sin, Dong-Hui;Choe, Seok-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.297-297
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    • 2010
  • Precise control of the position and density of doping elements at the nanoscale is becoming a central issue for realizing state-of-the-art silicon-based optoelectronic devices. As dimensions are scaled down to take benefits from the quantum confinement effect, however, the presence of interfaces and the nature of materials adjacent to silicon turn out to be important and govern the physical properties. Utilization of visible light is a promising method to overcome the efficiency limit of the crystalline Si solar cells. Si quantum dots (QDs) have been proposed as an emission source of visible light, which is based on the quantum confinement effect. Light emission in the visible wavelength has been reported by controlling the size and density of Si QDs embedded within various types of insulating matrix. For the realization of all-Si QD solar cells with homojunctions, it is prerequisite not only to optimize the impurity doping for both p- and n-type Si QDs, but also to construct p-n homojunctions between them. In this study, XPS and SIMS were used for the development of p-type and n-type Si quantum dot solar cells. The stoichiometry of SiOx layers were controlled by in-situ XPS analysis and the concentration of B and P by SIMS for the activated doping in Si nano structures. Especially, it has been experimentally evidenced that boron atoms in silicon nanostructures confined in SiO2 matrix can segregate into the Si/$SiO_2$ interfaces and the Si bulk forming a distinct bimodal spatial distribution. By performing quantitative analysis and theoretical modelling, it has been found that boron incorporated into the four-fold Si crystal lattice can have electrical activity. Based on these findings, p-type Si quantum dot solar cell with the energy-conversion efficiency of 10.2% was realized from a [B-doped $SiO_{1.2}$(2 nm)/$SiO_2(2\;nm)]^{25}$ superlattice film with a B doping level of $4.0{\times}10^{20}\;atoms/cm^2$.

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Algorithm of Detecting Ground Fault by Using Insulation Monitoring Device(IMD) in Ungrounded DC System (직류 비접지계통에서 절연저항측정장치(IMD)를 이용한 사고검출 알고리즘)

  • Kim, Ki-Young;Lee, Hu-Dong;Tae, Dong-Hyun;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.528-535
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    • 2020
  • Recently, the protection coordination method of DC systems has been presented because renewable energy and distributed resources are being installed and operated in distribution systems. On the other hand, it is difficult to detect ground faults because there is no significant difference compared to a steady-state current in ungrounded IT systems, such as DC load networks and urban railways. Therefore, this paper formulates the detection principle of IMD (Insulation Monitoring Device) to use it as a protection coordination device in a DC system. Based on the signal injection method of IMD, which is analyzed by a wavelet transform, this paper presents an algorithm of detecting ground faults in a DC system in a fast and accurate manner. In addition, this paper modeled an IMD and an ungrounded DC system using the PSCAD/EMTDC S/W and performed numerical analysis of a wavelet transform with the Matlab S/W. The simulation results of a ground fault case in an ungrounded DC system showed that the proposed algorithm and modeling are useful and practical tools for detecting a ground fault in a DC system.

Classification of Atmospheric Vertical Environment Associated with Heavy Rainfall using Long-Term Radiosonde Observational Data, 1997~2013 (장기간(1997~2013) 라디오존데 관측 자료를 활용한 집중호우 시 연직대기환경 유형 분류)

  • Jung, Sueng-Pil;In, So-Ra;Kim, Hyun-Wook;Sim, JaeKwan;Han, Sang-Ok;Choi, Byoung-Choel
    • Atmosphere
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    • v.25 no.4
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    • pp.611-622
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    • 2015
  • Heavy rainfall ($>30mm\;hr^{-1}$) over the Korean Peninsula is examined in order to understand thermo-dynamic characteristics of the atmosphere, using radiosonde observational data from seven upper-air observation stations during the last 17 years (1997~2013). A total of 82 heavy rainfall cases during the summer season (June-August) were selected for this study. The average values of thermo-dynamic indices of heavy rainfall events are Total Precipitable Water (TPW) = 60 mm, Convective Available Potential Energy (CAPE) = $850J\;kg^{-1}$, Convective Inhibition (CIN) = $15J\;kg^{-1}$, Storm Relative Helicity (SRH) = $160m^2s^{-2}$, and 0~3 km bulk wind shear = $5s^{-1}$. About 34% of the cases were associated with a Changma front; this pattern is more significant than other synoptic pressure patterns such as troughs (22%), migratory cyclones (15%), edges of high-pressure (12%), typhoons (11%), and low-pressure originating from Changma fronts (6%). The spatial distribution of thermo-dynamic conditions (CAPE and SRH) is similar to the range of thunderstorms over the United States, but extreme conditions (supercell thunderstorms and tornadoes) did not appear in the Korean Peninsula. Synoptic conditions, vertical buoyancy (CAPE, CIN), and wind parameters (SRH, shear) are shown to discriminate among the environments of the three types. The first type occurred with high CAPE and low wind shear by the edge of the high pressure pattern, but Second type is related to Changma front and typhoon, exhibiting low CAPE and high wind shear. The last type exhibited characteristics intermediate between the first and second types, such as moderate CAPE and wind shear near the migratory cyclone and trough.

Effect of Deposition Parameter and Mixing Process of Raw Materials on the Phase and Structure of Ytterbium Silicate Environmental Barrier Coatings by Suspension Plasma Spray Method (서스펜션 플라즈마 스프레이 코팅법으로 제조된 Ytterbium Silicate 환경차폐코팅의 상형성 및 구조에 미치는 증착인자 및 원료혼합 공정의 영향)

  • Ryu, Ho-lim;Choi, Seon-A;Lee, Sung-Min;Han, Yoon-Soo;Choi, Kyun;Nahm, Sahn;Oh, Yoon-Suk
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.437-443
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    • 2017
  • SiC-based composite materials with light weight, high durability, and high-temperature stability have been actively studied for use in aerospace and defense applications. Moreover, environmental barrier coating (EBC) technologies using oxide-based ceramic materials have been studied to prevent chemical deterioration at a high temperature of $1300^{\circ}C$ or higher. In this study, an ytterbium silicate material, which has recently been actively studied as an environmental barrier coating because of its high-temperature chemical stability, is fabricated on a sintered SiC substrate. $Yb_2O_3$ and $SiO_2$ are used as the raw starting materials to form ytterbium disilicate ($Yb_2Si_2O_7$). Suspension plasma spraying is applied as the coating method. The effect of the mixing method on the particle size and distribution, which affect the coating formation behavior, is investigated using a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and X-ray diffraction (XRD) analysis. It is found that the originally designed compounds are not effectively formed because of the refinement and vaporization of the raw material particles, i.e., $SiO_2$, and the formation of a porous coating structure. By changing the coating parameters such as the deposition distance, it is found that a denser coating structure can be formed at a closer deposition distance.

Locations and Topographical Character of the MAEULSOOP in the Southwestern and the Eastern Region (마을숲의 분포 위치와 지형적 공간특성 유형화 방안 - 경북 의성, 전북 진안 및 전남 함평지역을 대상으로)

  • Kwon, Jino;Oh, Jeong-Hak;Lee, Jeong-Youn;Park, Chan-Ryul;Choi, Myoung-Sub
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.4
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    • pp.85-93
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    • 2008
  • The MAEULSOOP, Korean traditional village groves have been installed and survived since 7th Century to serve local village dwellers as a community forest. The common sense of their reasons for being is related to the surroundings such as hills, waterways and wind-ways. To understand the roles in a local community, spatial characteristics of distribution, locations and shapes were tested at the two-characterized regions, the Southwestern Flat Region and the Eastern Hilly Region. Approximately more than 500 written evidences related to trees and forests were surveyed, for example village names, folk tales and lists of designated trees for protection. Twenty sites in each region were selected and tested for the spatial analysis. Aerial photographs, DEM and the ArcGIS with a modified AML for slope analysis are applied based on the criteria of the KLCIS(Kwon, 2002; 권진오, 2008). The major factors in the role of the MAEULSOOP based on the spatial character of two regions are; the array and locations of hills for encircling or exposure, locations against corridors and waterway or not, locations of the community to serve, the conservation of energy. Although locations and shapes of the MAEULSOOP are slightly different, it seems that one of the prime roles is what makes their everyday life difficult the most in the community.

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Influence of Surfactants on Enhancing Transport of Bacteria in Geological Materials (지질매질체내에서 계면활성제가 박테리아 이동 증진에 미치는 영향)

  • Choi, Nag-Choul;Park, Seong-Jik;Kim, Song-Bae;Kim, Dong-Ju;Lee, Seong-Jae
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1017-1023
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    • 2010
  • This study investigated the effect of surfactants (nonionic surfactant (Tween 20), biosurfactant) on enhancing transport of bacteria (Bacillus subtilis ATCC 6633) in geological materials. Column experiments were performed under various surfactant conditions with columns packed with quartz sand (particle size distribution: 0.5~2.0 mm, mean diameter: 1.0 mm). Bacterial mass recovery, sticking efficiency, and other parameters were quantified from breakthrough curves. Results indicate that bacterial attachment to sand surfaces increased considerably in the presence of mineral salt medium (MSM), especially at the inlet, which was due to the increase of ionic strength by MSM. It was observed that bacterial transport in sand columns was enhanced in the presence of surfactant. Results also show that simultaneous injection of both surfactant and MSM or pre-injection of surfactant was more effective in bacterial transport enhancement than after-injection of surfactant. This study suggests that transport of bacteria in geological materials could be influenced by surfactants and their injection methods.

Development and Evaluation of Natural Hydroxyapatite Ceramics Produced by the Heat Treatment of Pig Bones

  • Lim, Ki-Taek;Kim, Jin-Woo;Kim, Jangho;Chung, Jong Hoon
    • Journal of Biosystems Engineering
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    • v.39 no.3
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    • pp.227-234
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    • 2014
  • Purpose: The aim of this research was to develop and evaluate natural hydroxyapatite (HA) ceramics produced from the heat treatment of pig bones. Methods: The properties of natural HA ceramics produced from pig bones were assessed in two parts. Firstly, the raw materials were characterized. A temperature of $1,200^{\circ}C$ was chosen as the calcination temperature. Fine bone powders (BPs) were produced via calcinations and a milling process. Sintered BPs were then characterized using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared (FTIR) spectroscopy, and a 2-year in vitro degradability test. Secondly, an indirect cytotoxicity test was conducted on human osteoblast-like cells, MG63, treated with the BPs. Results: The average particle size of the BPs was $20{\pm}5{\mu}m$. FE-SEM showed a non-uniform distribution of the particle size. The phase obtained from XRD analysis confirmed the structure of HA. Elemental analysis using XRF detected phosphorus (P) and calcium (Ca) with the Ca/P ratio of 1.6. Functional groups examined by FTIR detected phosphate ($PO{_4}^{3-}$), hydroxyl ($OH^-$), and carbonate ($CO{_3}^{2-}$). The EDX, XRF, and FTIR analysis of BPs indicated the absence of organic compounds, which were completely removed after annealing at $1,200^{\circ}C$. The BPs were mostly stable in a simulated body fluid (SBF) solution for 2 years. An indirect cytotoxicity test on natural HA ceramics showed no threat to the cells. Conclusions: In conclusion, the sintering temperature of $1,200^{\circ}C$ affected the microstructure, phase, and biological characteristics of natural HA ceramics consisting of calcium phosphate. The Ca-P-based natural ceramics are bioactive materials with good biocompatibility; our results indicate that the prepared HA ceramics have great potential for agricultural and biological applications.

GAMMA-RAY BURST FORMATION ENVIRONMENT: COMPARISON OF REDSHIFT DISTRIBUTIONS OF GRB AFTERGLOWS (감마선 폭발체의 생성 환경: 에너지 영역별 잔유휘광의 거리 분포 비교)

  • Kim, Sung-Eun;Chang, Heon-Young
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.377-384
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    • 2005
  • Since gamma-ray bursts(GRBs) have been first known to science societites in 1973, many scientists are involved in their studies. Observations of GRB afterglows provide us with much information on the environment in which the observed GRBs are born. Study of GRB afterglows deals with longer timescale emissions in lower energy bands (e.g., months or even up to years) than prompt emissions in gamma-rays. Not all the bursts accompany afterglows in whole ranges of waveleogths. It has been suggested as a reason for that, for instance, that radio and/or X-ray afterglows are not recorded mainly due to lower sensitivity of detectors, and optical afterglows due to extinctions in intergalactic media or self-extinctions within a host galaxy itself. Based on the idea that these facts may also provide information on the GRE environment, we analyze statistical properties of GRB afterglows. We first select samples of the redshift-known GRBs according to the wavelength of afterglow they accompanied. We then compare their distributious as a function of redshift, using statistical methods. As a results, we find that the distribution of the GRBs with X-ray afterglows is consistent with that of the GRBs with optical afterglows. We, therefore, conclude that the lower detection rate of optical afterglows is not due to extinctions in intergalactic media.

Exposure Characteristics of Particles during the After-treatment Processes of Aluminum Oxide Fibers and Nickel Powders (산화알루미늄 섬유와 니켈분말 후처리공정에서 입자의 노출특성)

  • Kim, Jong Bum;Kim, Kyung Hwan;Ryu, Sung Hee;Yun, Seong-Taek;Bae, Gwi-Nam
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.2
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    • pp.225-236
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    • 2016
  • Objectives: Nanomaterials have been used in various fields. As use of nanoproducts is increasing, workers dealing with nanomaterials are also gradually increasing. Exposure assessments for nanomaterials have been carried out for protection of worker's health in workplace. Exposure studies were mainly focused on manufacturing processes, but these studies on after-treatment processes such as refinement, weighing, and packing were insufficient. So, we investigated exposure characteristics of particles during after-treatment processes of $Al_2O_3$ fibers and Ni powders. Methods: Mass-production of Ni powder process was carried out in enclosed capture-type canopy hood. In a developing stage, $Al_2O_3$ was handled with a local ventilation unit. Exposure characteristics of particles were investigated for $Al_2O_3$ fiber and Ni powder processes during the periods of 10:00 to 16:00, 20 May 2014 and 13:00 to 16:00, 21 May 2014, respectively. Three real-time aerosol instruments were utilized in exposure assessment. A scanning mobility particle sizer(SMPS, nanoscan, model 3910, TSI) and an optical particle counter(OPC, portable aerosol spectrometer, model 1.109, Grimm) were used to determine the particle size distribution in the size range of 10-420 nm and $0.25-32{\mu}m$, respectively. In addition, a nanoparticle aerosol monitor(NAM, model 9000, TSI) was used to measure lung-deposited nanoparticle surface area. Membrane filters(isopore membrane filter, pore size of 100 nm) were also used for air sampling for the FE-SEM(model S-5000H, Hitachi) analysis using a personal sampling pump(model GilAir Plus by 2.5 L/min, Gilian). Conclusions: For Ni powder after-treatment process, only 27% increase in particle concentration was found during the process. However, for $Al_2O_3$ fiber after-treatment process, significant exposure(1.56-3.34 times) was observed during the process.

A Study on the Performance Evaluation of Standard Gamma Irradiation System Using Monte Carlo Code (몬테카를로 코드를 활용한 표준 감마선 조사장치의 성능평가에 관한 연구)

  • Park, Won-Seok;Heo, Seung-Uk;Kim, Jang-Oh;Min, Byung-In
    • Journal of the Korean Society of Radiology
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    • v.12 no.2
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    • pp.179-184
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    • 2018
  • In this study, we compared the measured values of the effective beam size of standard gamma irradiator with the simulation results to provide a useful means to the effective beam area determination. Results of the simulation and measured using ion chamber was distributed in a relative error of 4.5 ~ 7.3% of the case of air kerma rate. The size of the effective beam area is when the simulation was implemented in the horizontal direction 27cm, 21.6cm vertical direction, the measured result using a film was obtained similar results with the horizontal direction 26.5cm, 21.9cm vertical direction. The relative error in the horizontal direction is 1.85% and 1.38% vertical effective beam area was also similarly distributed around the field gamma rays. As a result of the study, it was confirmed that the effectiveness of the simulation was sufficient for the gamma irradiation system. In particular, it is small relative errors in the effective beam size than the air kerma rate is considered to be due to the size of the beam is determined by geometric factors rather than the capacity of the standard source. A further study is needed to improve the reliability of the photon energy distribution diagram using simulation.