• Title/Summary/Keyword: Energy and mass exchange

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A Study on the Reactor Design of Solid-Solid-Gas Chemical Heat Pump System (고체-고체-기체 화학 열펌프 시스템의 반응기 설계에 관한 연구)

  • Kim, S.J.;Lee, T.H.;Neveu, P.;Choi, H.K.;Lee, J.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.406-416
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    • 1994
  • In this study the reactor design procedure and method of solid-solid-gas chemical heat pump system using STELF technology were investigated. For manufacturing IMPEX block which is the kernel of reactor, proper salt pair should be selected, and equilibrium temperature drop and COP should be examined for selected salt pair. Moreover, apparent density, residual porosity, and graphite ratio should be calculated to give minimum block volume and mass, and maximum energy density without causing heat and mass transfer problems. Since heat exchange area can be changed with operating condition, reactor diameter, length, and stainless steel thickness should be decided for desired specifications. These procedure and method were applied to the case study of 6kW cold production and 8 hours storage capacity reactor.

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Characteristics of Sensible Heat and Latent Heat Fluxes over the East Sea Related with Yeongdong Heavy Snowfall Events (영동대설 사례와 관련된 동해상의 현열속과 잠열속 분포 특성)

  • Kim, Ji-Eon;Kwon, Tae-Yong;Lee, Bang-Yong
    • Ocean and Polar Research
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    • v.27 no.3
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    • pp.237-250
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    • 2005
  • To investigate the air mass modification related with Yeongdong Heavy snowfall events, we examined sensible and latent heat fluxes on the East Sea, the energy exchange between atmosphere and ocean in this study. Sensible and latent heats were calculated by a bulk aerodynamic method, in which NCEP/NCAR reanalysis data and NOAA/AVHRR weekly SST data with high resolution were used. Among winter precipitation events in the Yeongdong region, 19 heavy precipitation events $(1995{\sim}2001)$ were selected and classified into three types (mountain, cold-coastal, and warm types). Mountain-type precipitation shows highly positive anomalies of sensible and latent heats over the southwestern part of the East Set When separating them into the two components due to variability of wind and temperature/ specific Humidity, it is shown that the wind components are dominant. Cold-coastal-type precipitation also shows strong positive anomalies of sensible and latent heats over the northern part and over the central-northern part of the East Sea, respectively. It is shown that the sensible heat anomalies are caused mostly by the decrease of surface air temperature. So it can be explained that cold-coastal-type precipitation is closely related with the air mass modification due to cold air advection over warm ocean surface. But in warm-type precipitation, negative anomalies are found in the sensible and latent heat distributions. From this result, it may be postulated that warm-type precipitation is affected by the internal process of the atmosphere rather than the atmosphere-ocean interaction.

Recent Developments of Metal-N-C Catalysts Toward Oxygen Reduction Reaction for Anion Exchange Membrane Fuel Cell: A Review

  • Jong Gyeong Kim;Youngin Cho;Chanho Pak
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.207-219
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    • 2024
  • Metal-N-C (MNC) catalysts have been anticipated as promising candidates for oxygen reduction reaction (ORR) to achieve low-cost polymer electrolyte membrane fuel cells. The structure of the M-Nx moiety enabled a high catalytic activity that was not observed in previously reported transition metal nanoparticle-based catalysts. Despite progress in non-precious metal catalysts, the low density of active sites of MNCs, which resulted in lower single-cell performance than Pt/C, needs to be resolved for practical application. This review focused on the recent studies and methodologies aimed to overcome these limitations and develop an inexpensive catalyst with excellent activity and durability in an alkaline environment. It included the possibility of non-precious metals as active materials for ORR catalysts, starting from Co phthalocyanine as ORR catalyst and the development of methodologies (e.g., metal-coordinated N-containing polymers, metal-organic frameworks) to form active sites, M-Nx moieties. Thereafter, the motivation, procedures, and progress of the latest research on the design of catalyst morphology for improved mass transport ability and active site engineering that allowed the promoted ORR kinetics were discussed.

Experimental Study on the Characteristics of Heat Exchanger of 1 kW PEMFC System for UAV (무인항공기용 고분자전해질형 연료전지 시스템의 열교환기 성능 특성 연구)

  • Kang, Sang-Gyu;Kim, Byung-Jun;Kim, Han-Seok
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.819-826
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    • 2011
  • The proton exchange membrane fuel cell (PEMFC) is regarded as the most promising alternative power sources for unmanned aerial vehicle (UAV) due to its high energy density and silent operation. Since there are many load changes during UAV flight, thermal management is one of the important factor for the performance of PEMFC. In order to reduce the UAV weight for the stable operation of UAV, thermal management system (TMS) studied in this work does not use the fan but use the air flowing into UAV by UAV flight. In order to develop the passive type heat exchanger (HEX) for 1kW PEMFC, four types of HEXs are fabricated and their cooling performances are compared. The parametric study on the cooling performance of HEXs has performed with the variation of operating parameters such as mass flow rates and inlet temperature of air and coolant. Type 4 has the best performance in every case. This study can be helpful to achieve the optimal design of HEX for PEMFC powered UAV.

Effect of Double Porous Layer on a Polymer Electrolyte Unitized Regenerative Fuel Cell (수전해·연료전지 가역셀에서 이중 가스 확산층의 효과)

  • Hwang, Chul-Min;Park, Dae-Heum;Jung, Young-Guan;Kim, Kyunghoon;Kim, Jongsoo
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.320-325
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    • 2013
  • TUnitized reversible fuel cells (URFC) combine the functionality of a fuel cell and electrolyzer in one unitized device. For a URFC with proton exchange membrane, a titanium (Ti)-felt is applied to the gas diffusion layer (GDL) substrate at the oxygen electrode, and additionally titanium (Ti)-powders and TiN-powders are loaded in the GDL substrate as a micro porous layer (MPL). Double porous layer with TiN MPL was not acceptable for the URFC because both of fuel cell performance and electrolysis performance are degraded. The double porous layer with Ti-powder loading in the Ti-felt substrate influence rearly for the electrolysis performance. In contrast, the change of pore-size distribution brings a significant improvement of fuel cell performance under fully humidification conditions. This fact indicates that the hydrophobic meso-pores in the GDL play an important role for mass transport.

The design and fabricationt for ion fraction measurement of plasma generator (플라즈마발생기의 이온분율 측정 장치 설계 및 제작)

  • Lee, Chan-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.368-368
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    • 2008
  • Ion implantation has been widely developed during the past decades to become a standard industrial tool. To comply with the growing needs in ion implantation, innovative technology for the control of ion beam parameters is required. Beam current, beam profile, ion fractions are of great interest when uniformity of the implant is an issue. Especially, it is important to measure the spatial distribution of beam power and also the energy distribution of accelerated ions. This energy distribution is influenced by the proportion of mass for ion in the plasma generator(ion source) and by charge exchange and dissociation within the accelerator structure and also by possible collective effects in the neutralizer which may affect the energy and divergence of ions. Hydrogen atom has been the object of a good study to investigate the energy distribution. Hydrogen ion sources typically produce multi-momentum beams consisting of atomic ion ($H^+$) and molecular ion ($H_2^+$ and $H_3^+$). In the beam injector, the molecular ions pass through a charge-exchanges gas cell and break up into atomic with one-half (from $H_2^+$) or one-third (from $H_3^+$) according to their accelerated energy. Burrell et al. have observed the Doppler shifted lines from incident $H^+$, $H_2^+$, and $H_3^+$ using a Doppler shift spectroscopy. Several authors have measured the proportion of mass for hydrogen ion and deuterium using an ion source equipped with a magnetic dipole filter. We developed an ion implanter with 50-KeV and 20-mA ion source and 100-keV accelerator tube, aiming at commercial uses. In order to measure the proportion of mass for ions, we designed a filter system which can be used to measure the ion fraction in any type of ion source. The hydrogen and helium ion species compositions are used a filter system with the two magnets configurations.

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Burnup Measurement of Spent $U_3$Si/Al Fuel by Chemical Method Using Neodymium Isotope Monitors

  • Kim, Jung-Suk;Jeon, Young-Shin;Park, Kwang-Soon;Song, Byung-Chul;Han, Sun-Ho;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.33 no.4
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    • pp.375-385
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    • 2001
  • The total burnup in the spent U$_3$Si/Al fuel samples from Hanaro reactor was determined by destructive methods using $^{148}$ Nd, the sum of $^{143}$ Nd and $^{144}$ Nd, the sum of $^{145}$ Nd and $^{146}$ Nd, and the sum of total Nd isotopes($^{143}$ Nd, $^{144}$ Nd, $^{145}$ Nd, $^{146}$ Nd, $^{148}$ Nd and $^{150}$ Nd) monitors. The fractional($^{235}$ U) turnup in the spent fuel samples was also determined by U and Pu mass spectrometric method. The samples were dissolved in a mixture of 4 M HCI and 10 M HNO$_3$ without any catalyst. The separation of U, Pu and Nd from the spiked and unspiked sample solutions was achieved by two sequential anion exchange separation methods. The isotope compositions of these elements, after their separation from the fuel samples were measured by mass spectrometry. The contents of the elements in the spent fuel samples were determined by isotope dilution mass spectrometric method(IDMS) using $^{233}$ U, $^{242}$ Pu and $^{150}$ Nd as spikes. The effective fission yield was calculated from the weighted fission yields averaged over the irradiation period. The difference between total turnup values determined by various Nd monitors were in the range of 1.8%.

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Characterization of Polyester Cloth as an Alternative Separator to Nafion Membrane in Microbial Fuel Cells for Bioelectricity Generation Using Swine Wastewater

  • Kim, Taeyoung;Kang, Sukwon;Sung, Je Hoon;Kang, Youn Koo;Kim, Young Hwa;Jang, Jae Kyung
    • Journal of Microbiology and Biotechnology
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    • v.26 no.12
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    • pp.2171-2178
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    • 2016
  • Polyester cloth (PC) was selected as a prospective inexpensive substitute separator material for microbial fuel cells (MFCs). PC was compared with a traditional Nafion proton exchange membrane (PEM) as an MFC separator by analyzing its physical and electrochemical properties. A single layer of PC showed higher mass transfer (e.g., for $O_2/H^+/ions$) than the Nafion PEM; in the case of oxygen mass transfer coefficient ($k_o$), a rate of $50.0{\times}10^{-5} cm{\cdot}s^{-1}$ was observed compared with a rate of $20.8{\times}10^{-5}cm/s$ in the Nafion PEM. Increased numbers of PC layers were found to reduce the oxygen mass transfer coefficient. In addition, the diffusion coefficient of oxygen ($D_O$) for PC ($2.0-3.3{\times}10^{-6}cm^2/s$) was lower than that of the Nafion PEM ($3.8{\times}10^{-6}cm^2/s$). The PC was found to have a low ohmic resistance ($0.29-0.38{\Omega}$) in the MFC, which was similar to that of Nafion PEM ($0.31{\Omega}$); this resulted in comparable maximum power density and maximum current density in MFCs with PC and those with Nafion PEMs. Moreover, a higher average current generation was observed in MFCs with PC ($104.3{\pm}15.3A/m^3$) compared with MFCs with Nafion PEM ($100.4{\pm}17.7A/m^3$), as well as showing insignificant degradation of the PC surface, during 177 days of use in swine wastewater. These results suggest that PC separators could serve as a low-cost alternative to Nafion PEMs for construction of cost-effective MFCs.

Experimental and numerical study on the dynamic behavior of a semi-active impact damper

  • Zheng Lu;Mengyao Zhou;Jiawei Zhang;Zhikuang Huang;Sami F. Masri
    • Smart Structures and Systems
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    • v.31 no.5
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    • pp.455-467
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    • 2023
  • Impact damper is a passive damping system that controls undesirable vibration with mass block impacting with stops fixed to the excited structure, introducing momentum exchange and energy dissipation. However, harmful momentum exchange may occur in the random excitation increasing structural response. Based on the mechanism of impact damping system, a semi-active impact damper (SAID) with controllable impact timing as well as a semi-active control strategy is proposed to enhance the seismic performance of engineering structures in this paper. Comparative experimental studies were conducted to investigate the damping performances of the passive impact damper and SAID. The extreme working conditions for SAID were also discussed and approaches to enhance the damping effect under high-intensity excitations were proposed. A numerical simulation model of SAID attached to a frame structure was established to further explore the damping mechanism. The experimental and numerical results show that the SAID has better control effect than the traditional passive impact damper and can effectively broaden the damping frequency band. The parametric studies illustrate the mass ratio and impact damping ratio of SAID can significantly influence the vibration control effect by affecting the impact force.

Analysis of Heat Exchanging Performance of Heat Recovering Device Attached to Exhaust Gas Duct (열회수장치에 의한 열교환 성능 분석(농업시설))

  • 서원명;강종국;윤용철;김정섭
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.333-339
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    • 2000
  • This study was performed to investigate the performance of heat recovery device attached to exhaust gas funnel connected to combustion chamber of greenhouse heating system. The experiment heat recovery system is mainly consisted of LPG combustion chamber and two heat recovery units; unit-A is attached directly to the exhaust gas funnel, and unit-B is connected with unit-A. Heat recovery performance was evaluated by estimating total energy amount by using enthalpy difference between two measurement points together with mass flow rate of gas and/or air passing through each heat recovery unit depending on 5 different flow rates controlled by voltage meter. The results of this experimental study, such as heat exchange behavior of supply air pipes and exhaust air passages crossing the pipes, pressure drop between inlet and outlet, heat recovery performance of exchange unit, etc., will be used as fundamental data for designing optimum heat recovery device to be used for fuel saving purpose by reducing heat loss amounts mostly wasted outside of greenhouse through funnels.

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