• Title/Summary/Keyword: Energy and mass exchange

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Effects of Turbulent Mixing and Void Drift Models on the Predictions of COBRA-IV-I

  • Yoo, Yeon-Jong;Hwang, Dae-Hyun;Nahm, Kee-Yil;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.284-289
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    • 1996
  • The predictions of the COBRA-IV-I code with the modified turbulent mixing and void drift models have been compared with the diabatic two-phase flow data on equilibrium quality. The turbulent mixing model based on an equal mass exchange of the existing COBRA-IV-I code has been modified to that based on an equal volume exchange between adjacent subchannels, and a void drift model has been newly incorporated in the code. To evaluate the performance of the equal volume exchange turbulent mixing model and the effects of the void drift model, the diabatic steam-water two-phase flow data obtained for the 9-rod bundle test under the typical operating conditions of the boiling water reactor(BWR) conducted by the General Electric (GE) were analyzed by the modified COBRA-IV-I code. The analysis indicates that the equal volume exchange turbulent mixing model with void drift predicts the observed two-phase flow data trends better than the equal mass exchange model, and to predict the correct data trends a more physically based void drift model need to be developed.

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MEASUREMENT OF THE SINGLE AND TWO PHASE FLOW USING A NEWLY DEVELOPED AVERAGE BIDIRECTIONAL FLOW TUBE

  • Yun, Byong-Jo;Euh, Dong-Jin;Kang, Kyunc-Ho;Song, Chul-Hwa;Baek, Won-Pil
    • Nuclear Engineering and Technology
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    • v.37 no.6
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    • pp.595-604
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    • 2005
  • A new instrument, an average BDFT (Birectional Flow Tube), was proposed to measure the flow rate in single and two phase flows. Its working principle is similar to that of the Pilot tube, wherein the dynamic pressure is measured. In an average BDFT, the pressure measured at the front of the flow tube is equal to the total pressure, while that measured at the rear tube is slightly less than the static pressure of the flow field due to the suction effect downstream. The proposed instrument was tested in air/water vertical and horizontal test sections with an inner diameter of 0.08m. The tests were performed primarily in single phase water and air flow conditions to obtain the amplification factor(k) of the flow tube in the vertical and horizontal test sections. Tests were also performed in air/water vertical two phase flow conditions in which the flow regimes were bubbly, slug, and churn turbulent flows. In order to calculate the phasic mass flow rates from the measured differential pressure, the Chexal drift-flux correlation and a momentum exchange factor between the two phases were introduced. The test results show that the proposed instrument with a combination of the measured void fraction, Chexal drift-flux correlation, and Bosio & Malnes' momentum exchange model could predict the phasic mass flow rates within a $15\%$ error. A new momentum exchange model was also proposed from the present data and its implementation provides a $5\%$ improvement to the measured mass flow rate when compared to that with the Bosio & Malnes' model.

Elucidating H/D-Exchange Mechanism of Active Hydrogen in Aniline and Benzene-1,2-dithiol

  • Ahmed, Arif;Islam, Syful;Kim, Sunghwan
    • Mass Spectrometry Letters
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    • v.12 no.4
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    • pp.146-151
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    • 2021
  • In this study, the hydrogen/deuterium (HDX) exchange mechanism of active hydrogen, nitrogen, and sulfur-containing polycyclic aromatic hydrocarbon (PAH) dissolved in toluene and deuterated methanol by atmospheric pressure photoionization (APPI) is investigated. The comparison of the data obtained using APPI suggests that aniline and benzene-1,2-dithiol contain two exchanging hydrogens. The APPI HDX that best explains the experimental findings was investigated with the use of quantum mechanical calculations. The HDX mechanism is composed of a two-step reaction: in the first step, analyte radical ion gets deuterated, and in the second step, the hydrogen transfer occurs from deuterated analyte to de-deuterated methanol to complete the exchange reaction. The suggested mechanism provides fundamentals for the HDX technique that is important for structural identification with mass spectrometry. This paper is dedicated to Professor Seung Koo Shin for his outstanding contributions in chemistry and mass spectrometry.

Performance Analysis of an Earth Tube Heat Exchanger(I) -Temperature Variation Characteristics and Heat Exchange Performance on the Mode of Continuous Operation (지중매설관 열교환장치의 성능분석(I) -연속운전실험에서의 온도특성 및 열교환성능-)

  • Kim, Y.B.;Paek, Y.
    • Journal of Biosystems Engineering
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    • v.21 no.4
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    • pp.436-448
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    • 1996
  • An earth tube soil air heat exchange system was designed, installed and operated as a single pass heat exchanger to utilize the geothermal energy as an natural energy source. This study was undertaken to investigate the potential of the heating and cooling, energy gain, heat exchange efficiency and coefficient of performance of the system. The system consisted of 30m in length and 30cm in diameter polyethylene pipes buried 2m deep in soil. Maximum heating and cooling performance were 2.51㎾ and 1.26㎾ at the air mass rate of 21cmm. Energy gain and coefficient of performance were the function of temperature difference between outside air and soil temperature. They were expressed as Q=0.33$ imes$$Delta T_{max}$+0.134(㎾) for energy gain and COP=0.44$ imes$$Delta T_{max}$+0.178 for coefficient of performance with correlation factor of 0.95. The mean of heat exchange efficiencies was 85.6%.

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Effects of Soil and Air Flow Characteristics on the Soil-Air Heat Exchanger Performances (토양과 공기유동특성이 토양-공기 열교환기 성능에 미치는 영향)

  • 김영복;김기영
    • Journal of Biosystems Engineering
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    • v.23 no.1
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    • pp.21-30
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    • 1998
  • A theoretical model was developed to evaluate the effects of soil and airflow characteristics on the soil-air heat exchanger performances. The model, which includes three-dimensional transient energy and mass equilibrium-equation, was solved by using a computer program that uses Finite Difference Methods and Gauss-Seidel iteration computation. Energy gains, heat exchange efficiencies, and outlet air temperature are presented including the effects of soil moisture content, soil conductivity, soil thermal diffusivity, and soil initial temperature. Also, data related to the effects of airflow rate and inlet air temperature on the thermal performance of the system are presented. The results indicated that energy gains depend on soil conductivity, soil thermal diffusivity, and soil initial temperature. Heat exchange efficiencies relied on air mass flow rate and soil moisture content.

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Dependence of Na+ leakage on intrinsic properties of cation exchange resin in simulated secondary environment for nuclear power plants

  • Hyun Kyoung Ahn;Chi Hyun An;Byung Gi Park;In Hyoung Rhee
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.640-647
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    • 2023
  • Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na+. This study was conducted to understand the Na+ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na+ was inappreciably escaped throughout the channel created in resin layer. Na+ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na+ capture and with increasing the fraction of ETAH-form resin. Na+ did not reach the breakthrough earlier than ETAH+ and NH4+ due to the increased selectivity of Na+ to the cation-exchange resin (H+ < ETAH+ < NH4+ ≪ Na+) at the feed composition. Na+ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na+ leakage from the condensate polishing plant (CPP) in NPPs.

Physical Property Models and Single Cells Analysis for Solid Oxide Fuel Cell (고체산화물 연료전지를 위한 물성치 모델 및 단전지 해석)

  • Park, Joon-Guen;Kim, Sun-Young;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.379-381
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    • 2009
  • The simulation model for metal-supported Solid Oxide Fuel Cell(SOFC) is developed in this study. Open circuit voltage is calculated using Nernst equation and Gibbs free energy is required by thermodynamic. The exchange current densities are compared with experimental results since exchange current density is most effective factor for the activation loss. Liu's study is used for the exchange current density of cathode, BSCF, and Koide's result is applied for the exchange current density of anode, Ni/YSZ. For the ohmic loss, ionic conductivity of YSZ is described from Kilner's mode and the data are compared with Wanzenberg's experimental data. Diffusivity is an important factor for the mass transfer through the porous medium. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results.

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Burnup Measurement of Irradiated Uranium Dioxide Fuel by Chemical Methods (화학적 방법에 의한 핵연료의 연소도 측정)

  • Kim, Jung-Suk;Han, Sun-Ho;Suh, Moo-Yul;Joe, Kih-Soo;Eom, Tae-Yoon
    • Nuclear Engineering and Technology
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    • v.21 no.4
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    • pp.277-286
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    • 1989
  • Destructive methods are used for the turnup determination of an irradiated PWR fuel. One of the methods includes U, Pu, Nd-148 and Nd-(145+146) determination by an isotope dilution mass spectrometry using triple spikes (U-233, Pu-242 and Nd-150). The method involves two sequential ion exchange resin separation procedures. Pu is eluted from the first anion exchange resin column (Dowex AG 1$\times$8) with 12 M HCl-0.1 M HI mixed solution, followed by U elution with 0.1 M HCl. Nd is isolated from other fission products on the second anion exchange resin column (Dowex AG 1$\times$4) with a nitric acid-methanol eluent. Each fraction is analysed by thermal ionization mass spectrometry. The difference between Nd-148 and Nd-(145+146) method is found with an average 2.07%. The results are compared with those by the heavy element method using U and Pu isotopes and by the destructive y-spectrometric measurement of Cs-137. The dependences of isotope composition of U and Pu on burn-up, and correlation between those isotopes are illustrated graphically.

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The Public Opinion of Corporate Social Responsibility Activities in South Korea: Examining the Effects of Communal and Exchange Relationships Between Citizens and Corporations

  • Lee, Soobum;Jin, Bumsub
    • Asian Journal for Public Opinion Research
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    • v.4 no.2
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    • pp.108-122
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    • 2017
  • This study explores how South Korean citizens evaluate corporate social responsibility (CSR) practices based on communal and exchange relationships. Specifically, it examines whether their evaluations of the two types of relationships are related to their supportive opinions, such as positive attitudes toward corporations and behavioral intentions to purchase products. The findings show that the communal relationship between an energy corporation and its local residents is more related to their supportive opinions than exchange relationship. That is, a communal relationship tends to generate more positive business outcomes than an exchange relationship. This study concludes that corporations should prepare for useful community outreach and CSR programs for their local community. Practitioners need to focus on building communal relationships with community members through their programs.

Sea-air Energy Exchange in the Eastern Yellow Sea (한국서해의 해양과 대기간 에너지의 효과)

  • Lee, Dong-Young;Chang, Sun-Duck
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.12 no.2
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    • pp.37-42
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    • 1976
  • Each term of heat badget equation in the eastern Yellow Sea was calculated and the variation in relation to meteorological condition was shown for the period from September 1973 to February 1974, At Mal-do near Gunsan the maximum heat exchange occurred at the last ten days of December (--522 1y/day), while at Sunmi-do near Incheon it occurred at the middle ten days of November (--665 1y /day), The contribution of the sensible heat to total heat exchange increased rapidly, while the effect of cloudiness decreased to be negligible in winter. The values of the heat exchange fluctuated considerably with the periodic occurrence of the cold Siberiaa air mass. The mean evaporation heat estimated indirectly from the aerological data was 32 ly/day at the northern part and 269 ly/dlY at the southern part of the Yellow Sea in December 1973.

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