• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.208-208
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• 1999

It is found that with increasing power, the measured electron energy distribution by Langmuir probe evolves into a Druyvesteyn-like electron energy distribution in the low-pressure regime of 1mTorr in a small inductively coupled plasma. Electron bounce resonance is introduced to explain the transition of the electron energy distribution against the rf power, The energy diffusion coefficients which determine the shape of the electron energy distribution in elastic range are calculated with and without electron bounce resonance. This electron energy distribution transition is well explained by the electron bounce resonance.

• Journal of Welding and Joining
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• v.10 no.1
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• pp.43-51
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• 1992

The plastic zone formed around a notch tip is important in analyzing the fracture toughness of structures and particularly weld cracks existed in the weld HAZ (heat affected zone) which produces local plastic deformation at the crack tip. Therefore, in order to analyze the fracture toughness in weld HAZ, it is necessary to investigate the new fracture toughness parameter $K_{c}$ $^{*}$ and critical plastic strain energy $W_{p}$ $^{c}$ according to the shape and size of the plastic zone. 1) If the temperature corresponding to $K_{c}$ $^{*}$=130kg-m $m^{-3}$ 2/ is determined, transition temperature $T_{tr}$ the magnitude of plastic zone size, and heat input change depending on the fracture toughness. The blunted amounts of the parent and weld HAZ show mild linear variation until .delta.=0.4mm and then increase very steeply there after. 2) The relation between the plastic strain energy( $W^{p}$ ) and transition temperature( $T_{*}$tr) in parent metal is more sensitive than that of weld HAZ. However, the plastic strain energy depends on the transition temperature, and thus the yield stress, .sigma.$_{ys}$ becomes an important parameter for plastic strain energy. 3) The critical plastic strain energy( $W_{p}$ $^{c}$ ) absorbed by the plastic zone at the notch tip indicated in case of parent metal: 60J/mm, in case of heat input(20KJ/cm): 75J/mm, in case of heat input(30KJ/cm); 50J/mmJ/mm.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.2973-2978
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• 2009

The decomposition reaction mechanism of $CH_3CF_2O$ radical formed from hydroflurocarbon, $CH_3CHF_2$ (HFC-152a) in the atmosphere has been investigated using ab-initio quantum mechanical methods. The geometries of the reactant, products and transition states involved in the decomposition pathways have been optimized and characterized at DFT-B3LYP and MP2 levels of theories using 6-311++G(d,p) basis set. Calculations have been carried out to observe the effect of basis sets on the optimized geometries of species involved. Single point energy calculations have been performed at QCISD(T) and CCSD(T) level of theories. Out of the two prominent decomposition channels considered viz., C-C bond scission and F-elimination, C-C bond scission is found to be the dominant path involving a barrier height of 12.3 kcal/mol whereas the F-elimination path involves that of a 28.0 kcal/mol. Using transition-state theory, rate constant for the most dominant decomposition pathway viz., C-C bond scission is calculated at 298 K and found to be 1.3 ${\times}$ 10$^4s{-1}$. Transition states are searched on the potential energy surfaces involving both decomposition channels and each of the transition states are characterized. The existence of transition states on the corresponding potential energy surface are ascertained by performing Intrinsic Reaction Coordinate (IRC) calculation.

• Journal of the Korean Institute of Gas
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• v.19 no.6
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• pp.62-66
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• 2015

Considering for plants and structure under extreme conditions is required for the successful design, especially temperature and pressure. The ductile-brittle transition temperature (DBTT) for the materials under extreme condition needs to be considered. In this study, A-grade mild steel for the LNG carrier and offshore plant was examined by performing low-temperature Charpy V-notch (CVN) impact tests to investigate DBTT and the fracture toughness. The absorbed energy decreased gradually with the experimental temperature, which showed an upper-shelf energy region, lower shelf energy region, and transition temperature indicating DBTT. In addition, the fracture surface morphologies of the mild steels indicated ductile fractures at the upper-shelf energy level, with wide and large-sized dimples, whereas a brittle fracture surface, where was observed at the lower-shelf energy level, with both large and small cleavage facets. Based on the experimental results, ductile brittle transition temperature was estimated in about $-60^{\circ}C$.

• Nuclear Engineering and Technology
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• v.30 no.4
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• pp.364-376
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• 1998

The statistical analysis method was applied to the evaluation of fracture toughness in the ductile-brittle transition temperature region. Because cleavage fracture in steel is of a statistical nature, fracture toughness data or values show a similar statistical trend. Using the three-parameter Weibull distribution, a fracture toughness vs. temperature curve (K-curve) was directly generated from a set of fracture toughness data at a selected temperature. Charpy V-notch impact energy was also used to obtain the K-curve by a $K_{IC}$ -CVN (Charpy V-notch energy) correlation. Furthermore, this method was applied to evaluate the neutron irradiation embrittlement of reactor pressure vessel (RPV) steel. Most of the fracture toughness data were within the 95% confidence limits. The prediction of a transition temperature shift by statistical analysis was compared with that from the experimental data.

• Nuclear Engineering and Technology
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• v.27 no.4
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• pp.503-517
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• 1995

A mechanistic model for forced convective transition boiling has been developed to predict transition boiling heat flux realistically. This model is based on a postulated multi­stage boiling process occurring during the passage time of an elongated vapor blanket specified at a critical heat flux condition. Between the departure from nucleate boiling (DNB) and the departure from film boiling (DFB) points, the boiling heat transfer is established through three boiling stages, namely, the macrolayer evaporation and dryout governed by nucleate boiling in a thin liquid film and the unstable film boiling. The total heat transfer rate during the transition boiling is the sum of the heat transfer rates after the DNB weighted by the time fractions of each stage, which are defined as the ratio of each stage duration to the vapor blanket passage time. The model predictions are compared with some available experimental transition boiling data. From these comparisons, it can be seen that the transition boiling heat fluxes including the maximum heat flux and the minimum film boiling heat flux are nil predicted at low qualities/high pressures near 10 bar.

• Advances in nano research
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• v.3 no.1
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• pp.13-27
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• 2015

Size dependent emission properties and the interband optical transition energies in group-III nitride based quantum dots are investigated taking into account the geometrical confinement. Exciton binding energy and the optical transition energy in $Ga_{0.9}In_{0.1}N$/GaN and $Al_{0.395}In_{0.605}N$/AlN quantum dots are studied. The largest intersubband transition energies of electron and heavy hole with the consideration of geometrical confinement are brought out. The interband optical transition energies in the quantum dots are studied. The exciton oscillator strength as a function of dot radius in the quantum dots is computed. The interband optical absorption coefficients in GaInN/GaN and AlInN/AlN quantum dots, for the constant radius, are investigated. The result shows that the largest intersubband energy of 41% (10%) enhancement has been observed when the size of the dot radius is reduced from $50{\AA}$ to $25{\AA}$ of $Ga_{0.9}In_{0.1}N$/GaN ($Al_{0.395}In_{0.605}N$/AlN) quantum dot.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.10
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• pp.795-803
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• 2015

The boundary layer developing over the suction surface of a first-stage turbine blade for power generation has been investigated in this study. For three locations selected in the region where local thermal load changes dramatically, mean velocity, turbulence intensity, and one-dimensional energy spectrum are measured with a hot-wire anemometer. The results show that the suction-surface boundary layer suffers a transition from a laminar flow to a turbulent one. This transition is confirmed to be a "separated-flow transition", which usually occurs in the shear layer over a separation bubble. The local minimum thermal load on the suction surface is found at the initiation point of the transition, whereas the local maximum thermal load is observed at the location of very high near-wall turbulence intensity after the transition process. Frequency characteristics of turbulent kinetic energy before and after the transition are understood clearly from the energy spectrum data.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.572-572
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• 2012

Growth of metal oxides on graphene may lead to a better understanding of delicate effects of their growth habits on their underlying physics. The vanadium dioxide ($VO_2$) is well known for its metal-to-insulator transition accompanied by a reversible first order structural phase transition at 340 K. This transition makes $VO_2$ a potentially useful material for applications in electrical and optical devices. We report a successful growth of $VO_2$ nanostructures on a graphene substrate via a vapor-solid transport route. As-grown $VO_2$ nanostructures on graphene were systematically characterized by field emission scanning electron microscopy, x-ray diffraction, Raman spectroscopy, FT-IR spectroscopy and high resolution transmission electron microscopy. These results indicate that the strain between $VO_2$ and graphene layers may be easily controlled by the number of underlying graphene layer. We also found that the strain in-between $VO_2$ and graphene layer affected its metal-to-insulator transition characteristics. This study demonstrates a new way for synthesizing $VO_2$ in a desired phase on the transparent conducting graphene substrate and an easy pathway for controlling metal-to-insulator phase transition via strain.

• Journal of Science and Technology Studies
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• v.18 no.1
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• pp.219-265
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• 2018

Recently, interest in energy tranisition is rising. Energy transition requires active participation and cooperation of diverse stakeholders, including users / citizens, in that it requires not only changes in technological factors but also changes and coordination of various social factors. Living labs are attracting attention as one of the ways to do this. This article is a detailed analysis of the activities of the mini-PV living lab in the urban area from 2016 to 2017 at the Seoul, Sung Dae Goal. Through the Living Lab, mini PV DIY products, backup centers, local financial services, and the development of a variety of education and training strategies have been achieved. These activities and achievements were analyzed through questions raised on strategic, tactical, and operational levels, as well as through multi-level perspective and interaction between initiative, regime, and niche. In conclusion, this living lab activity confirmed the possibility of a 'transition lap' to solve social problems such as sustainability of energy production and utilization. In particular, it gained remarkable results in terms of the operational leves of transition management governance, that is, transition experiment, and it was also remarkable in that it was the initiative of citizens. However, it did not proceed without difficulty. In particular, structural problems such as the conflict between the flexibility inherent in living lab and the bureaucratic rigidity of the financial support organization have appeared. There was also a limitation that there was no 'transition field' on the strategic level necessary to replicate and expand strategic niches while spreading the knowledge gained from the transition experiment, forming the vision of transition.