• 제목/요약/키워드: Energy Generation Analysis

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단결정 초내열합금에 적용된 열차폐코팅의 등온열화에 따른 산화물 거동분석 (Analysis of Thermal Oxide Behavior with Isothermal Degradation of TBC Systems Applied to Single Crystal Superalloy)

  • 김기근;위성욱;최재구;김담현;송현우;이정민;석창성;정의석;권석환
    • 한국안전학회지
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    • 제34권4호
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    • pp.1-5
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    • 2019
  • In the field of combined cycle power generation, thermal barrier coating(TBC) protects the super-heat-resistant alloy, which forms the core component of the gas turbine, from high temperature exposure. As the turbine inlet temperature(TIT) increases, TBC is more important and durability performance is also important when considering maintenance cost and safety. Therefore, studies have been made on the fabrication method of TBC and super-heat-resistant alloy in order to improve the performance of the TBC. In recent years, due to excellent properties such as high temperature creep resistance and high temperature strength, turbine blade material have been replaced by a single crystal superalloy, however there is a lack of research on TBC applied to single crystal superalloy. In this study, to understand the isothermal degradation performance of the TBC applied to the single crystal superalloy, isothermal exposure test was conducted at various temperature to derive the delamination life. The growth curve of thermally grown oxide(TGO) layer was predicted to evaluate the isothermal degradation performance. Also, microstructural analysis was performed by scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the effect of mixed oxide formation on the delamination life.

건설기업 관점의 효과적인 시공 VE 수행을 위한 전략 도출 연구 (Establishing the Strategy of Effective Construction VE for Construction Firms)

  • 박찬영;윤성민;이동은
    • 한국건설관리학회논문집
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    • 제22권2호
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    • pp.80-87
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    • 2021
  • SOC 예산 부족과 불충분한 건설자금 문제 등으로 건설사의 체감경기가 악화되고 있다. 이러한 상황에서 건설 VE는 건설 수익향상을 통해 이러한 상황에 대처하는 수단이 될 수 있다. 본 연구는 Importance Performance Analysis를 실행하여 효과적인 시공VE의 전략을 수립하기 위한 건설사의 강점 항목과 약점 항목을 도출하였다. 건설사들은 건설VE에 대한 지원·협력·지식 등 12개 항목에서 강점을 지닌다. 반면, 'VE리더의 VE 경험', '상세비용 추정', '아이디어 생성·평가' 등은 약점이 있는 것으로 나타났다. 본 연구는 제도적 관점에서 VE 활성화에 중점을 두었던 기존 연구와 달리 건설기업 관점에서 효과적인 시공VE 수행을 위한 전략을 도출하였다는 점에서 의의가 있다.

Comparison of Numerical Analyses and Model Test for Evaluation on Hydroelastic and Higher-order Springing Responses of Fixed Cylindrical Structure

  • Kim, Hyun-Sung;Won, Younguk;Oh, Young Jae;Lee, Kangsu;Kim, Byoung Wan
    • 한국해양공학회지
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    • 제35권3호
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    • pp.191-202
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    • 2021
  • Studies on very large offshore structures are increasing owing to the development of deep sea, large-scale energy generation using ocean resources, and so on. The enlargement of offshore structures makes the hydroelastic effect and low natural frequency related responses important. Numerical analyses and model tests for hydroelastic and higher-order springing responses of fixed cylindrical structures are conducted in this study. The panel methods with and without the hydroelastic effect with shell elements, and the Morison analysis method with beam elements are applied. To observe the hydroelastic effect for structural strength, two structures are considered: bottom-fixed cylindrical structures with high and low bending stiffnesses, respectively. The surge motions at the top of the structure and bending stresses on the structure are observed under regular and irregular wave conditions. The regular wave conditions are generated considering the ratios of the cylindrical outer diameter to the wave lengths, and keeping the wave steepness constant. The model tests are performed in the three-dimensional ocean engineering basin in the KRISO (Korea Research Institute of Ships and Ocean Engineering). From the numerical and experimental results, in which the hydroelastic responses are only observed in the case of the structure with a low bending stiffness, it is confirmed that the hydroelastic responses are highly dependent on the structural stiffness. Additionally, the higher-order phenomenon on the specified wave condition is analyzed by observing the higher-order springing responses when the incident wave frequency or its multiples with the high wave height coincides with the natural frequency of the structure.

퍼스의 기호학적 관점에서의 BTS 이미지 분석 (Analysis of BTS Images From Peirce's Semiotic Perspective)

  • 이지아;서승희
    • 패션비즈니스
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    • 제25권5호
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    • pp.114-130
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    • 2021
  • The purpose of this study is to analysis BTS's image based on Peirce's semiotics. Methodologies of this study are literature study to analyze the structure of idol image based on Peirce's theory of signs, case study and FGI analyzing the semiotic characteristics of BTS images. The research results of analyzing the semiotic features of BTS images by period of the BTS album are as follows. First, in the early days of their debut, they emphasized the image of hip-hop and expressed their will to resist and rebel against the older generation with a challenging and strong image. Second, during the 'The most beautiful day of life' period, image of wandering, rebellion, growth, and youth of teenagers was expressed. Third, in the 'Love Yourself' period, BTS showed various image changes between natural and pure image to splendid image by expressing the process of finding confidence during chaotic moment of growing. Fourth, during the 'Map of the Soul' period, the exploration and reflection on themselves were expressed in an outwardly splendid and bright manner, while at the same time expressing the inner darkness in a contrasting manner. Fifth, in the 'pandemic period', they expressed hopeful energy and willness with the image of mature and attractive man and bright and casual image. Their growth and change have been directly linked to the change of their image, and their image showed a successful signification with complementary combination of icons, indexes, and symbols.

NRC 증기압 암석 파쇄제에 의한 PMMA 블록의 동적 파괴 과정에 관한 실험 및 수치해석적 연구 (Experimental and Numerical Study on the Dynamic Fracture Processes of PMMA Block by NRC Vapor Pressure Fracture Agent)

  • 민경조
    • 한국방재안전학회논문집
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    • 제16권1호
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    • pp.91-103
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    • 2023
  • 본 연구의 목적은 테르밋 반응으로 결정화된 액체혼합물을 순간적으로 기화시켜, 이에 따라 발생되는 증기압을 이용하여 암석 및 콘크리트를 파쇄시키는 Nonex Rock Cracker(NRC) 암석 파쇄제의 동적 파괴 특성을 분석하고 파괴패턴을 예측할 수 있는 해석기법을 개발하기 위함이다. NRC 암석 파쇄제의 순간적의 증기압 발생 특성을 분석하기 위하여 인공취성재료로 알려진 Polymethyl methacrylate(PMMA) 블록을 대상으로 NRC를 장전하여 파쇄시험을 수행하였다. NRC의 증기압 발생순간을 촬영하기 위하여 초고속 카메라를 활용하였으며, 장약실과 연결된 관측공에 동적압력게이지를 부착하여 장약공 압력-시간이력을 계측하였다. 증기압 암석 파쇄제에 의한 PMMA 블록의 파괴패턴을 모사하기 위하여 2차원 동적 파괴 과정 해석 기법인 2D Dynamic Fracture Process Analysis(2DDFPA)가 활용되었으며, 계측된 장약공 압력-시간이력을 고려한 입사압력함수를 결정하였다. 제안된 해석조건을 활용하여 화강암재료와 고성능 폭약에 의하여 발생될 수 있는 파괴패턴에 대하여 고찰하였다.

부숙도에 따른 우분유래 바이오차의 표면특성과 질소 및 인의 침출 거동 연구 (Surface Characteristics of Cattle Manure-derived Biochar: Effects of Manure Aging and Nitrogen/Phosphorus Leaching)

  • 김나은;이희연;권기훈;송호철
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제28권6호
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    • pp.24-32
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    • 2023
  • Continuous increase of domestic meat consumption has inevitably increased generation of livestock manure and caused severe environmental impacts on ecosystem and human beings. This work produced biochar from cattle manure samples with different composting aging stages and investigated the properties of the produced biochar. The result of thermogravimetric analysis showed that thermal decomposition of the manure initiated at <600℃. The biochar yield was higher for the manure with a longer pre-composting period due to the elimination of microbially metabolized carbons during composting process. The result of FT-IR analysis showed that the number of surface functional groups were reduced during pyrolysis while enhancing the graphitic structures of the carbon framework. Manure samples tended to leach out N and P in leaching tests, with its amount higher for aged one than fresh one. However, their leaching was substantially suppressed when the manure was produced into biochar. In XPS spectra, it was found that N and P in the manure incorporated into biochar surface to form N-doped graphitic carbon and P-N-moieties, respectively. The findings of this work suggest that the thermochemical process can be of a viable option to valorize into biochar for potential environmental applications as well as to alleviate undesired nutrients loading to the environment.

4H-SiC PiN 다이오드의 깊은 준위 결함에 따른 전기적 특성 분석 (Analysis of Electrical Characteristics due to Deep Level Defects in 4H-SiC PiN Diodes)

  • 이태희;박세림;김예진;박승현;김일룡;김민규;임병철;구상모
    • 한국재료학회지
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    • 제34권2호
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    • pp.111-115
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    • 2024
  • Silicon carbide (SiC) has emerged as a promising material for next-generation power semiconductor materials, due to its high thermal conductivity and high critical electric field (~3 MV/cm) with a wide bandgap of 3.3 eV. This permits SiC devices to operate at lower on-resistance and higher breakdown voltage. However, to improve device performance, advanced research is still needed to reduce point defects in the SiC epitaxial layer. This work investigated the electrical characteristics and defect properties using DLTS analysis. Four deep level defects generated by the implantation process and during epitaxial layer growth were detected. Trap parameters such as energy level, capture-cross section, trap density were obtained from an Arrhenius plot. To investigate the impact of defects on the device, a 2D TCAD simulation was conducted using the same device structure, and the extracted defect parameters were added to confirm electrical characteristics. The degradation of device performance such as an increase in on-resistance by adding trap parameters was confirmed.

Analysis of the thermal-mechanical behavior of SFR fuel pins during fast unprotected transient overpower accidents using the GERMINAL fuel performance code

  • Vincent Dupont;Victor Blanc;Thierry Beck;Marc Lainet;Pierre Sciora
    • Nuclear Engineering and Technology
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    • 제56권3호
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    • pp.973-979
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    • 2024
  • In the framework of the Generation IV research and development project, in which the French Commission of Alternative and Atomic Energies (CEA) is involved, a main objective for the design of Sodium-cooled Fast Reactor (SFR) is to meet the safety goals for severe accidents. Among the severe ones, the Unprotected Transient OverPower (UTOP) accidents can lead very quickly to a global melting of the core. UTOP accidents can be considered either as slow during a Control Rod Withdrawal (CRW) or as fast. The paper focuses on fast UTOP accidents, which occur in a few milliseconds, and three different scenarios are considered: rupture of the core support plate, uncontrolled passage of a gas bubble inside the core and core mechanical distortion such as a core flowering/compaction during an earthquake. Several levels and rates of reactivity insertions are also considered and the thermal-mechanical behavior of an ASTRID fuel pin from the ASTRID CFV core is simulated with the GERMINAL code. Two types of fuel pins are simulated, inner and outer core pins, and three different burn-up are considered. Moreover, the feedback from the CABRI programs on these type of transients is used in order to evaluate the failure mechanism in terms of kinetics of energy injection and fuel melting. The CABRI experiments complete the analysis made with GERMINAL calculations and have shown that three dominant mechanisms can be considered as responsible for pin failure or onset of pin degradation during ULOF/UTOP accident: molten cavity pressure loading, fuel-cladding mechanical interaction (FCMI) and fuel break-up. The study is one of the first step in fast UTOP accidents modelling with GERMINAL and it has shown that the code can already succeed in modelling these type of scenarios up to the sodium boiling point. The modeling of the radial propagation of the melting front, validated by comparison with CABRI tests, is already very efficient.

Highly Doped Nano-crystal Embedded Polymorphous Silicon Thin Film Deposited by Using Neutral Beam Assisted CVD at Room Temperature

  • 장진녕;이동혁;소현욱;홍문표
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.154-155
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    • 2012
  • The promise of nano-crystalites (nc) as a technological material, for applications including display backplane, and solar cells, may ultimately depend on tailoring their behavior through doping and crystallinity. Impurities can strongly modify electronic and optical properties of bulk and nc semiconductors. Highly doped dopant also effect structural properties (both grain size, crystal fraction) of nc-Si thin film. As discussed in several literatures, P atoms or radicals have the tendency to reside on the surface of nc. The P-radical segregation on the nano-grain surfaces that called self-purification may reduce the possibility of new nucleation because of the five-coordination of P. In addition, the P doping levels of ${\sim}2{\times}10^{21}\;at/cm^3$ is the solubility limitation of P in Si; the solubility of nc thin film should be smaller. Therefore, the non-activated P tends to segregate on the grain boundaries and the surface of nc. These mechanisms could prevent new nucleation on the existing grain surface. Therefore, most researches shown that highly doped nc-thin film by using conventional PECVD deposition system tended to have low crystallinity, where the formation energy of nucleation should be higher than the nc surface in the intrinsic materials. If the deposition technology that can make highly doped and simultaneously highly crystallized nc at low temperature, it can lead processes of next generation flexible devices. Recently, we are developing a novel CVD technology with a neutral particle beam (NPB) source, named as neutral beam assisted CVD (NBaCVD), which controls the energy of incident neutral particles in the range of 1~300eV in order to enhance the atomic activation and crystalline of thin films at low temperatures. During the formation of the nc-/pm-Si thin films by the NBaCVD with various process conditions, NPB energy directly controlled by the reflector bias and effectively increased crystal fraction (~80%) by uniformly distributed nc grains with 3~10 nm size. In the case of phosphorous doped Si thin films, the doping efficiency also increased as increasing the reflector bias (i.e. increasing NPB energy). At 330V of reflector bias, activation energy of the doped nc-Si thin film reduced as low as 0.001 eV. This means dopants are fully occupied as substitutional site, even though the Si thin film has nano-sized grain structure. And activated dopant concentration is recorded as high as up to 1020 #/$cm^3$ at very low process temperature (< $80^{\circ}C$) process without any post annealing. Theoretical solubility for the higher dopant concentration in Si thin film for order of 1020 #/$cm^3$ can be done only high temperature process or post annealing over $650^{\circ}C$. In general, as decreasing the grain size, the dopant binding energy increases as ratio of 1 of diameter of grain and the dopant hardly be activated. The highly doped nc-Si thin film by low-temperature NBaCVD process had smaller average grain size under 10 nm (measured by GIWAXS, GISAXS and TEM analysis), but achieved very higher activation of phosphorous dopant; NB energy sufficiently transports its energy to doping and crystallization even though without supplying additional thermal energy. TEM image shows that incubation layer does not formed between nc-Si film and SiO2 under later and highly crystallized nc-Si film is constructed with uniformly distributed nano-grains in polymorphous tissues. The nucleation should be start at the first layer on the SiO2 later, but it hardly growth to be cone-shaped micro-size grains. The nc-grain evenly embedded pm-Si thin film can be formatted by competition of the nucleation and the crystal growing, which depend on the NPB energies. In the evaluation of the light soaking degradation of photoconductivity, while conventional intrinsic and n-type doped a-Si thin films appeared typical degradation of photoconductivity, all of the nc-Si thin films processed by the NBaCVD show only a few % of degradation of it. From FTIR and RAMAN spectra, the energetic hydrogen NB atoms passivate nano-grain boundaries during the NBaCVD process because of the high diffusivity and chemical potential of hydrogen atoms.

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후속열처리 및 고온고습 조건에 따른 Cu 배선 확산 방지층 적용을 위한 ALD RuAlO 박막의 계면접착에너지에 관한 연구 (Effects of Post-annealing and Temperature/Humidity Conditions on the Interfacial Adhesion Energies of ALD RuAlO Diffusion Barrier Layer for Cu Interconnects)

  • 이현철;정민수;배병현;천태훈;김수현;박영배
    • 마이크로전자및패키징학회지
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    • 제23권2호
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    • pp.49-55
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    • 2016
  • 차세대 반도체의 초미세 Cu 배선 확산방지층 적용을 위해 원자층증착법(atomic layer deposition, ALD) 공정을 이용하여 증착한 RuAlO 확산방지층과 Cu 박막 계면의 계면접착에너지를 정량적으로 측정하였고, 환경 신뢰성 평가를 수행하였다. 접합 직후 4점굽힘시험으로 평가된 계면접착에너지는 약 $7.60J/m^2$으로 측정되었다. $85^{\circ}C$/85% 상대습도의 고온고습조건에서 500시간이 지난 후 측정된 계면접착에너지는 $5.65J/m^2$로 감소하였으나, $200^{\circ}C$에서 500시간 동안 후속 열처리한 후에는 $24.05J/m^2$으로 계면접착에너지가 크게 증가한 것으로 평가되었다. 4점굽힘시험 후 박리된 계면은 접합 직후와 고온고습조건의 시편의 경우 RuAlO/$SiO_2$ 계면이었고, 500시간 후속 열처리 조건에서는 Cu/RuAlO 계면인 것으로 확인되었다. X-선 광전자 분광법 분석 결과, 고온고습조건에서는 흡습으로 인하여 강한 Al-O-Si 계면 결합이 부분적으로 분리되어 계면접착에너지가 약간 낮아진 반면, 적절한 후속 열처리 조건에서는 효과적인 산소의 계면 유입으로 인하여 강한 Al-O-Si 결합이 크게 증가하여 계면접착에너지도 크게 증가한 것으로 판단된다. 따라서, ALD Ru 확산방지층에 비해 ALD RuAlO 확산방지층은 동시에 Cu 씨앗층 역할을 하면서도 전기적 및 기계적 신뢰성이 우수할 것으로 판단된다.