• 제목/요약/키워드: Energy Diagram

검색결과 302건 처리시간 0.026초

전면 유기발광 다이오드 제작시 Mg:Ag 캐소드 최적화 및 LiF 전자주입층 유무에 따른 소자 특성에 관한 연구 (Optimization of Mg:Ag Cathodes and Effect of LiF Electron Injection Layer on the Characteristics of Top Emission Organic Light Emitting Diodes)

  • 송민석;권상직;조의식
    • 반도체디스플레이기술학회지
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    • 제21권1호
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    • pp.71-74
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    • 2022
  • For the process simplification in the fabrication of organic light emitting diode(OLED), top emission OLED (TEOLED) was fabricated without lithium fluoride(LiF) used as an electron injection layer (EIL). After co-deposition of Mg and Ag with a different process conditions, a cathode material adjacent to EIL was optimized when Mg and Ag have a ratio of 1:9 considering sheet resistance and transmittance. From the energy band diagram of TEOLED, band gap difference between Trisaluminium (Alq3) and Mg:Ag cathode show the difference of 0.4 eV according to the usage of LiF The fabricated TEOLED without LiF showed the improvement of 5.2 % and 2.7 % in the luminance and the current density comparing that with LiF. The results show there is no significant difference in OLED characteristics regardless of LIF layer in the TEOLED structures.

수소생산시설에서의 요오드-황 공정에 대한 안전성 평가연구 (Safety Assessments for the IS(Iodine Sulfur) Process in a Hydrogen Production Facility)

  • 이현우;제무성;조남철;양준언;이원재
    • 한국안전학회지
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    • 제24권3호
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    • pp.54-58
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    • 2009
  • 화석연료의 고갈과 환경문제로 인해 대체에너지 개발의 필요성이 대두되고 있다. 이에 거론되고 있는 대체에너지 중에서 물로부터 수소를 생산하는 기술은 탄소발생이 없는 매우 장래가 유망한 기술이다. IS 열화학적 물분해 공정은 거론되는 방법 중 매우 유망한 기술로 에너지원으로 900$^{\circ}C$ 이상의 열을 공급할 수 있는 고온가스냉각로(HTGR)를 시용하여 매우 능률적으로 수소를 생산할 수 있는 방법이다. 본 연구에서는 IS공정 의 초기사건을 도출하기 위해 주논리도(MLD)방법이 사용되어 화학물질의 유출을 야기할 수 있는 초기사건 9가지가 도출되었다. 또한 도출된 9가지 초기사건 중 6가지를 선정, 사건수목을 이용하여 정량화하였다.

Aryl Benzoates와 Amine류의 반응에 관한 구조-반응성 관계 (Structure-Reactivity Relationships for the Reaction of Aryl Benzoates with Amines)

  • 정덕영;권정민;여수동;박병수
    • 대한화학회지
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    • 제39권7호
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    • pp.572-577
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    • 1995
  • 아세토니트릴 용매계에서 aryl 치환(Z)-benzoate류와 아민류의 반응속도를 15, 25, 및 35 $^{\circ}C$에서 분광학적 방법으로 구했다. 2차 반응속도 상수로부터 Hammett $\rho$값, Bronsted ${\beta}$값, 및 활성화 parameter를 구했으며 이들값과 M-O-F-J diagram 등의 해석으로부터 본 반응은 $S_AN$ 메카니즘으로 진행됨을 알 수 있었다.

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변전소 자동화 시스템의 신뢰도 해석에 관한 연구 (A Study on Reliability Analysis of Substation Automation System)

  • 박철원
    • 전기학회논문지P
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    • 제64권4호
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    • pp.281-285
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    • 2015
  • Electrical energy supply interruption degrades reliability of power supply as well as social costs and economic loss. It is important to assess the reliability of the power system. Nowadays IEC61850 based substation automation system(SAS) has been developed for an updating of automation and interoperability. In this study, three kinds of reliability block diagram(RBD) were proposed to examine of network availability of the three types SAS. And reliability and unreliability of the SAS was formulated using the RBD. Finally, while varying the value of reliability and unreliability, the reliability and the unreliability of the overall system were evaluated.

왕복동 압축기의 성능해석 시뮬레이션 (Numerical Simulation of a Reciprocating Compressor)

  • 김정우;김현진;박희용
    • 대한기계학회논문집
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    • 제17권2호
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    • pp.475-483
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    • 1993
  • A computer simulation model of a hermetic reciprocating type of refrigeration compressor has been developed. The compressor simulation model constitutes 6 control volumes, to each of which conservation laws of mass and energy are applied to yield full description of the refrigerant state along its passage. Instead of ideal gas assumption. real gas equation is employed. Some of valve-related input data required for the simulation are acquired from test bench experiments. The refrigerant states such as pressure and temperature, etc., mass flow rates, and valve motions can be predicted by the simulation. The calculated P-V diagram shows a good agreement with experimental result.

o-Terphenyl型 化合物의 光고리화反應에 대한 HMO 相關圖 (HMo Correlation Diagram for Photocyclization of o-Terphenyl Type Compounds)

  • 임용진;이광조;박병각
    • 대한화학회지
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    • 제23권3호
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    • pp.119-124
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    • 1979
  • o-Terphenyl형 화합물들의 고리화반응을 궤도대칭이론과 에너지 상관도로서 해석하였다. 그 결고ㅓㅏ o-terphenyl형 화합물들의 고리화반응은 광고리화반응이었다. 이것은 실험적 사실 및 타이론적 결과와 잘 일치하였다.

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A Single Mobile Target Tracking in Voronoi-based Clustered Wireless Sensor Network

  • Chen, Jiehui;Salim, Mariam B.;Matsumoto, Mitsuji
    • Journal of Information Processing Systems
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    • 제7권1호
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    • pp.17-28
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    • 2011
  • Despite the fact that the deployment of sensor networks and target tracking could both be managed by taking full advantage of Voronoi diagrams, very little few have been made in this regard. In this paper, we designed an optimized barrier coverage and an energy-efficient clustering algorithm for forming Vonoroi-based Wireless Sensor Networks(WSN) in which we proposed a mobile target tracking scheme (CTT&MAV) that takes full advantage of Voronoi-diagram boundary to improve detectability. Simulations verified that CTT&MAV outperforms random walk, random waypoint, random direction and Gauss-Markov in terms of both the average hop distance that the mobile target moved before being detected and lower sensor death rate. Moreover, we demonstrate that our results are robust as realistic sensing models and also validate our observations through extensive simulations.

지속 방출형 염산에탐부톨 마이크로캅셀의 제조에 있어서 스테아린산알루미늄의 효과 (Effects of Aluminum Tristearate in the Preparation of Sustained Release Ethambutol Hydrochloride Microcapsules)

  • 유봉신
    • Journal of Pharmaceutical Investigation
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    • 제18권4호
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    • pp.175-180
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    • 1988
  • The role and effect of aluminum tristearate in microencapsulation were investigated based on the dispersion system of ethambutol hydrochloride in acetone-liquid paraffin. Eudragit RS was used as a wall-forming material. Eudragit RS microcapsules prepared using aluminum tristearate were uniform, free-flowing particles. The phase diagram of ethambutol hydrochloride-Eudragit RS-aluminum tristearate indicated that spherical microcapsules ranging from 250 to 1400 ${\mu}m$ in diameter could be prepared only in a very limited region. Instrumental analysis using an energy dispersive-type X-ray microanalyser and a scanning electron microscope showed that aluminum tristearate was localized near the surface of microcapsules. From these results, it was presumed that aluminum tristearate reduced the phase tension between Eudragit microcapsules and liquid paraffin. The dissolution rates of ethambutol hydrochloride from Eudragit RS microcapsules were consideraly lower than those from ethambutol hydrochloride powders and decreased as the amount of aluminum tristearate decreased.

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Polymer Bland에서의 상평형에 관한 연구 (Study on the Phase Diagram for the Polymer Bland)

  • 김상민
    • 한국포장학회지
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    • 제9권1호
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    • pp.19-24
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    • 2003
  • We study on the phase diagram of the polymer blend. For this purpose, one PS (polystyrene) and two PI(polyisoprene) were employed whose molecular weights were low enough to make the experimental determinations possible. The weight-average molecular weight(Mw) of PS was 2514, and Mws of two PIs were 2700. Interaction energy density (IED) of the Flory-Huggins lattice theory was defined as a function of temperature and composition, and the consequent equations for the binodal, and critical points were derived. By fitting the experimental binodal points to the derived binodal curve with a nonlinear regression method, the expression for the IED was determined. And the expression for the IED obtained from this study was compared with those reported in the literatures. Also were discussed the importance of accuracy in the expression the IED, and the IED's dependency on the temperature, composition and molecular weights.

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DGEBA계 에폭시 수지의 양이온 열 개시 반응에 의한 유변학적 특성연구 (A Study of Rheological Properties on Thermoinitiated Cationic Catalyst/DGEBA Curing System)

  • 이재락
    • 유변학
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    • 제10권2호
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    • pp.92-97
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    • 1998
  • 열잠재성 경화제인 N-benzylpyrazinium hexafluoroantimonate (BPH)를 이용하여 함 량에 따른 DGEBA계 에폭시 수지의 경화반응에서의 유변학적 특서 및 반응속도를 연구하 였다. 경화시의 활성화 에너지를 Barrett 방법을 이용한 동적 DSC 측정방법으로 조사 하였 다. DSC 실험 결과 BPH의 함량이 증가할수록 활성화 에너지는 감소함을 알수 있었다. Rheomter를 이용하여 DGEBA/BPH 계의 유변학적 특성을 등온경화와 tdmdhsrud화 조건하 에서 살펴보았다. BPH의 함량이 증가함에 따라 겔화점 도달시간 빠르게 나타나는데 이는 낮아진 활성화 에너지에 기인한 것으로 사료된다. 두 번째 damping 피크를 이용하여 유리 화점을 측정하여 Time-Temperature-Transformation (T-T-T) cure diagram을 작성한 결 과 열잠재성 경화제의 특성인 일정온도 이상에서 활성이 나타남을 확인할수있었다.

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