• 제목/요약/키워드: Energy Diagram

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(Photosensitive Polymers VII) Mechanism of Photosensitized Curing Reaction of Cinnamoylated Polymers ((感光性 高分子에 關한 硏究 VII) Cinnamoylated Polymers의 光增感 硬化反應機構)

  • Kim, Kwang-Sup;Shim, Jyong-Sup
    • Journal of the Korean Chemical Society
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    • 제10권4호
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    • pp.166-174
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    • 1966
  • The multistep mechanism of photosensitized curing reaction cinnamoylated photosensitive polymer is proposed from the energy level diagram of cinnamic acid and sensitizer, and from the fact that excess of sensitizer brings the sensitivity to a limiting value etc. Various factors which have effects on the ability of sensitizer are also discussed. The mechanism involves following steps: activation to the first excited singlet states of cinnamoyl group(C) and sensitizer(S) by their absorption of photon, their intersystem crossing to the lowest triplet state, bimolecular internal quenching by formation of excimer of sensitizer, triplet excitation energy transfer and intermolecular addition between cinnamoyl group in ground state and that in triplet state. The rate equation derived from this mechanism is $-\frac{d[C]}{dt} = \frac{K_1[C]}{K_2 + [C]}[\frac{I^c_{abs}}{K_3 + [S]} + \frac{K_4[C]}{(K_5 + [C])(K_6 + [S])}(I^s_{abs} + \frac{K_7I^c_{abs}[S]}{K_8 + [S]})]$ where $I^c_{abs}\;and\;I^s_{abs}$: the rates of absorption of photon by cinnamoyl group and sensitizer $K_n$: Constants. It is proved with the cinnamate of poly(glyceryl phthalate)(PGC) in the absence of sensitizer using the infrared analytical method and successfully applied for the experimental data reported on the effects of the degree of cinnamoyl esterification and the concentration of sensitizer upon the sensitivity.

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C-V 측정을 통한 다이오드 소자의 온도 특성 분석

  • Choe, Pyeong-Ho;Kim, Sang-Seop;Choe, Byeong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.284-284
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    • 2012
  • 본 연구에서는 다이오드 소자의 온도 증가에 따른 C-V 특성을 분석하였다. 180 kHz 주파수 조건에서 온도는 300 K에서 450 K까지 50 K 간격으로 가변하였다. 측정 결과 reverse bias 영역에서는 커패시턴스의 온도 의존성이 없었으나, forward bias 영역에서는 온도가 증가함에 따라 동일 전압에서의 커패시턴스가 증가하였다. 이로부터 온도가 증가 할수록 소자가 반전(inversion) 상태에서 축적(accumulation) 상태로 빨리 전환함을 확인하였으며, 1/C2-V 그래프로부터 온도 증가에 따른 전위장벽(Built-in potential, Vbi) 감소를 확인하였다. 전위장벽은 0.63 V에서 0.31 V로 온도 상승에 따라 약 0.1 V씩 감소하였다. 이는 energy band diagram에서 p-type 영역과 n-type 영역의 energy band 차가 감소해 공핍층 영역의 폭이 좁아짐을 의미한다. 공핍층의 두께 감소로 다이오드 전류의 급격한 증가뿐 아니라 위에서 언급한 바와 같은 C-V 특성을 보였다. 이번 연구에서는 기존의 보편화 된 I-V 측정을 통한 다이오드 소자 분석과는 달리 온도 변화에 따른 C-V 분석을 통해 소자 내부의 전위 장벽 및 공핍층 폭 감소에 따른 소자 특성 변화를 분석하였다.

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Transient Stability Analysis Based on OOP (객체지향기반 과도 안정도 해석)

  • Park, Ji-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • 제57권3호
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    • pp.354-362
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    • 2008
  • This paper presents the new method of power system transient stability simulation, which combines the desirable features of both the time domain technique based on OOP(Object-oriented Programming) and the direct method of transient stability analysis using detailed generator model. OOP is an alternative to overcome the problems associated with the development, maintenance and update of large software by electrical utilities. Several papers have already evaluated this approach for power system applications in areas such as load flow, security assessment and graphical interface. This paper applied the object-oriented approach to the problem of power system dynamics simulation. The modeling method is that each block of dynamic system block diagram is implemented as an object and connected each other. In the transient energy method, the detailed synchronous generator model is so-called two-axis model. For the excitation model, IEEE type1 model is used. The developed mothed was successfully applied to New England Test System.

A Study of Hydrogen-Induced Metal Atom Rearrangement

  • Noh, Hak;Park, Choong-Nyeon;Flanagan, Ted B.
    • Journal of Hydrogen and New Energy
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    • 제7권1호
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    • pp.111-115
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    • 1996
  • Metal atom rearrangement has been shown to take place under the influence of hydrogen-induced atomic diffusion (HIAD) in initially homogeneous fee palladiumalloys by electron microprobe analysis, optical microscopy, mechanical property tests and hydrogen isotherms. HIAD takes place in palladium alloys at moderate to elevated temperatures leading to phase segregation under conditions where segregation does not normally occur, i.e., in the absence of H over the time scale of the experiments. From these results, it is confirmed that dissolved hydrogen plays a dual role in some of these alloys, i.e. it catalyzes metal atom diffusion. This research demonstrates the potential utility of employing H-induced changes for phase diagram determination of Pd alloys and possibly for other alloy system.

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A study for a Performance analysis of Hybrid heat pump Air conditioning system (복합열원형 히트펌프 냉난방 시스템의 성능분석에 관한 연구)

  • Lim, Hyun-Mook;Park, Hee-Moon;Cho, Soo;Sung, Uk-Joo;Park, Jin-Hoon;Park, Tae-Jin
    • Proceedings of the SAREK Conference
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.1373-1378
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    • 2009
  • This study is aiming comparison and analization between efficiency of hybride air conditioning system which uses low temperature water under dam and air and EHP(Electric Heat Pump). The experimental was carried out with air cooling tests for EHP system having 80HP and composition heat pump system. P-i diagram of both systems and COP was used to derive schemetic and calcuations. As results of the tests, hybride system has 1.4 time higher efficiency coefficient.

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Harmonic Simulation and Measurement Analysis for a Skyscraper (초고층빌딩에 대한 고조파 시뮬레이션 및 실측데이터 분석)

  • Cho, Soo-Hwan;Lee, Han-Sang;Jung, Jae-Ahn;Jang, Gil-Soo;Lee, Kyung-Ho
    • Proceedings of the KIEE Conference
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.265-266
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    • 2008
  • The interest on harmonics which is one of the matters related with power quality problem is not limited in only the system where the large scale industrial load is connected. The harmonics phenomenon not only causes the malfunction of devices, but also lowers the energy efficiency of power system. This paper focuses on the harmonic analysis process to establish the harmonic mitigation method, considering the harmonics distortion as a major cause to reduce the energy efficiency of a skyscraper. A system diagram of building is modelled with PSCAD simulator. Based on the harmonic analysis results of it, the electrical locations with the high priority to install the mitigating devices are selected. Finally, the result of PSCAD simulations and the site-measured data are compared, verifying that they reach a common conclusion.

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A Study on Classification of Electric Shock Disasters and Countermeasures (전격재해의 유형 및 대책에 관한 연구)

  • 권영준;손병창;이명희;신승헌
    • Journal of the Korean Society of Safety
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    • 제15권4호
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    • pp.47-55
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    • 2000
  • In this modern age which electric energy is the fundamental source of energy in the industry, electric shock disasters are unavoidable. Although numerous efforts, time, and money have been invested to prevent such electric shock disasters, the number of electric shock disasters are on the increase. In this study, models for equivalent electric circuit are developed for the different types of electric shock which are classified into three groups. The objective of these models is to calculate the electric current flowing through the body at the time of the shock. Based on the analysis, countermeasures to prevent the shock are suggested. The data used in this study are based on 28 actual incidents which occurred in the Daegu area during January of 1995 through June of 1999. The results of this study can be used as a technical manual for workers treating electrical facilities.

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A method of calculating strain state and forming severity analysis for axisymmetric sheet formed parts. (축대칭 프레스가공 제품의 변형률 예측기술과 변형여유 해석에의 적용)

  • 박기철;남재복;최원섭
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 한국소성가공학회 1994년도 박판성형기술의 진보
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    • pp.173-184
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    • 1994
  • A method of obtaining deformation severity of axisymmetric shape deep-drawn products was developed. Strain states of products produced by single or multi-stage drawing were predicted by using finite element analysis. This method used minimization of potential energy between the known shape of final product and the unknown in initial blank. And that was done numerically by nonlinear finite element method. Deformation theory of plasticity was used for practical purposes. From predicted strain states of drawn parts, deformation severity was found by using forming limit diagrams.

A comparing on the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle

  • Thawichsri, Kosart;nilnont, Wanich
    • International Journal of Advanced Culture Technology
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    • 제3권2호
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    • pp.58-66
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    • 2015
  • This paper aims to compare the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle (ORC) Machine using Isopentane as working fluid expanding. The working fluid has boiling point below boiling water and works in low-temperature sources between $80-120^{\circ}C$ which can be produced from waste heat, solar-thermal energy and geothermal energy etc. The experiment on ORC machine reveals that the suitability of high pressure pump for working fluid has result on the efficiency of work. In addition, Thermodynamics theory on P-h diagram also presented the effect of heat sources' temperature and flow rate on any work. Thus, the study and design on ORC machine has to concern mainly on pressure pump, flow rate and optimized temperature. Result experiment and calculate ORC Machine using centrifugal Turbine efficiency better than Tesla turbine 30% but Tesla Turbine is cheaper and easily structure. Further study on the machine can be developed throughout the county due to its low cost and efficiency.

International Standardization of Reliability Assessment for Wind Turbines and Wind Farms (풍력발전기 및 풍력발전단지 신뢰성 평가 국제 표준화)

  • Kim, Seokwoo
    • Journal of Wind Energy
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    • 제9권4호
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    • pp.5-8
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    • 2018
  • Optimum performance and reliable operation of wind turbines and/or wind farms are crucial parameters for stakeholders such as OEMs, operators, owners and investors. The efficiency and life time of wind power heavily depends on operation and maintenance efforts. Every manufacturer or owner wants to have wind turbines with high reliability, which can be defined as the probability that a wind turbine will perform its designed function for a certain period of time under stated conditions. In this regard, IEC WG26 is now developing a technical specification defining information categories from which reliability metrics can be identified and reported.