• Title/Summary/Keyword: Energetic Material

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Solid State Cesium Ion Beam Sputter Deposition

  • Baik, Hong-Koo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.5-18
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    • 1996
  • The solid state cesium ion source os alumino-silicate based zeolite which contains cerium. The material is an ionic conductor. Cesiums are stably stored in the material and one can extract the cesiums by applying electric field across the electrolyte. Cesium ion bombardment has the unique property of producing high negative ion yield. This ion source is used as the primary source for the production of a negative ion without any gas discharge or the need for a carrier gas. The deposition of materials as an ionic species in the energy range of 1.0 to 300eV is recently recognized as a very promising new thin film technique. This energetic non-thermal equilibrium deposition process produces films by “Kinetic Bonding / Energetic Condensation" mechansim not governed by the common place thermo-mechanical reaction. Under these highly non-equilibrium conditions meta-stable materials are realized and the negative ion is considered to be an optimum paeticle or tool for the purpose. This process differs fundamentally from the conventional ion beam assisted deposition (IBAD) technique such that the ion beam energy transfer to the deposition process is directly coupled the process. Since cesium ion beam sputter deposition process is forming materials with high kinetic energy of metal ion beams, the process provider following unique advantages:(1) to synthesize non thermal-equilibrium materials, (2) to form materials at lower processing temperature than used for conventional chemical of physical vapor deposition, (3) to deposit very uniform, dense, and good adhesive films (4) to make higher doposition rate, (5) to control the ion flux and ion energy independently. Solid state cesium ion beam sputter deposition system has been developed. This source is capable of producing variety of metal ion beams such as C, Si, W, Ta, Mo, Al, Au, Ag, Cr etc. Using this deposition system, several researches have been performed. (1) To produce superior quality amorphous diamond films (2) to produce carbon nitirde hard coatings(Carbon nitride is a new material whose hardness is comparable to the diamond and also has a very high thermal stability.) (3) to produce cesiated amorphous diamond thin film coated Si surface exhibiting negative electron affinity characteristics. In this presentation, the principles of solid state cesium ion beam sputter deposition and several applications of negative metal ion source will be introduced.

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A Design of Solar Proton Telescope for Next Generation Small Satellite

  • Sohn, Jongdae;Oh, Suyeon;Yi, Yu;Min, Kyoung-Wook;Lee, Dae-Young;Seon, Jongho
    • Journal of Astronomy and Space Sciences
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    • v.29 no.4
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    • pp.343-349
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    • 2012
  • The solar proton telescope (SPT) is considered as one of the scientific instruments to be installed in instruments for the study of space storm (ISSS) which is determined for next generation small satellite-1 (NEXTSat-1). The SPT is the instrument that acquires the information on energetic particles, especially the energy and flux of proton, according to the solar activity in the space radiation environment. We performed the simulation to determine the specification of the SPT using geometry and tracking 4 (GEANT4). The simulation was performed in the range of 0.6-1,000 MeV considering that the proton, which is to be detected, corresponds to the high energy region according to the solar activity in the space radiation environment. By using aluminum as a blocking material and adjusting the energy detection range, we determined total 7 channels (0.6~5, 5~10, 10~20, 20~35, 35~52, 52~72, and >72 MeV) for the energy range of SPT. In the SPT, the proton energy was distinguished using linear energy transfer to compare with or discriminate from relativistic electron for the channels P1-P3 which are the range of less than 20 MeV, and above those channels, the energy was determined on the basis of whether silicon semiconductor detector (SSD) signal can pass or not. To determine the optimal channel, we performed the conceptual design of payload which uses the SSD. The designed SPT will improve the understanding on the capture and decline of solar energetic particles at the radiation belt by measuring the energetic proton.

The Manufacturing Process and Characteristic Analysis of BKNO3 Metal-Explosive for PMD (PMD용 BKNO3 금속화약의 제조공정 및 특성분석)

  • Shim, Jungseob;Kim, Sangbaek;Ahn, Gilhwan;Kim, Junhyung;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.3
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    • pp.90-96
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    • 2018
  • This study investigated the manufacturing process and characteristics of $BKNO_3$ (Boron Potassium Nitrate) as a pyrotechnic propellant that is commonly used in the aerospace, defense, and automobile industries. The solid mixture was composed of oxidizing agent, fuel, and binder. Evaporation process was used to uniformly mix the raw materials. The optimal ratio of composition was designed through the CEA program analysis of the material characteristics and thermal responses. Further the size, shape, sensitivity, and calorimetry characteristics were studied.

Systhesis New Precursors for Hexanitrohexa-azaisowurtzitane(HNIW) (새 전구체에 의한 고폭화약 Hexanitrohexa-azaisowurtzitane(HNIW) 합성 연구)

  • Cheun, Young Gu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.5 no.3
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    • pp.56-61
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    • 2002
  • The hexanitrohexaazaisowurtzitane(HNIW) is a polycyclic caged nitramine oxidizer. For most existing weapons systems, the most critical ingredient in explosive and propellant applications is the oxidizer, HNIW, with its increase in performance output and energy capabilities for future in explosive and propellant systems. Two new polyacylhexaazaisowurtzitanes were synthesized. Pentaacetylhexaaza-isowurtzitane(PAIW) or pentaacetylformylhexaazaisowurtzitane(PAFIW) can be a precursor in the preparation of HNIW, recently developed highly energetic material.

An intelligent monitoring of greenhouse using wireless sensor networks

  • Touhami, Achouak;Benahmed, Khelifa;Parra, Lorena;Bounaama, Fateh;Lloret, Jaime
    • Smart Structures and Systems
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    • v.26 no.1
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    • pp.117-134
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    • 2020
  • Over recent years, the interest for vegetables and fruits in all seasons and places has much increased, from where diverse countries have directed to the commercial production in greenhouse. In this article, we propose an algorithm based on wireless sensor network technologies that monitor the microclimate inside a greenhouse and linear equations model for optimization plant production and material cost. Moreover, we also suggest a novel design of an intelligent greenhouse. We validate our algorithms with simulations on a benchmark based on experimental data made at lNRA of Montfavet in France. Finally, we calculate the statistical estimators RMSE, TSSE, MAPE, EF and R2. The results obtained are promising, which shows the efficiency of our proposed system.

Structural Characterization and Thermal Behavior of a Novel Energetic Material: 1-Amino-1-(2,4-dinitrophenylhydrazinyl)-2,2-dinitroethylene

  • Ren, Xiaolei;Zuo, Xiangang;Xu, Kangzhen;Ren, Yinghui;Huang, Jie;Song, Jirong;Wang, Bozhou;Zhao, Fengqi
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2267-2273
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    • 2011
  • A novel energetic material, 1-amino-1-(2,4-dinitrophenylhydrazinyl)-2,2-dinitroethylene (APHDNE), was synthesized by the reaction of 1,1-diamino-2,2-dinitroethylene (FOX-7) and 2,4-dinitrophenylhydrazine in N-methyl pyrrolidone (NMP) at 110 $^{\circ}C$. The theoretical investigation on APHDNE was curried out by B3LYP/6-311+$G^*$ method. The IR frequencies analysis and NMR chemical shifts were performed and compared with the experimental results. The thermal behavior of APHDNE was studied by DSC and TG/DTG methods, and can be divided into two crystal phase transition processes and three exothermic decomposition processes. The enthalpy, apparent activation energy and pre-exponential factor of the first exothermic decomposition reaction were obtained as -525.3 kJ $mol^{-1}$, 276.85 kJ $mol^{-1}$ and $10^{26.22}s^{-1}$, respectively. The critical temperature of thermal explosion of APHDNE is 237.7 $^{\circ}C$. The specific heat capacity of APHDNE was determined with micro-DSC method and theoretical calculation method, and the molar heat capacity is 363.67 J $mol^{-1}K^{-1}$ at 298.15 K. The adiabatic time-to-explosion of APHDNE was also calculated to be a certain value between 253.2-309.4 s. APHDNE has higher thermal stability than FOX-7.

Study on the Performance Evaluation of the Explosive Bolt that has been Natural Aging (자연 노화된 폭발볼트의 성능 평가에 관한 연구)

  • Kim, Dongjin;Jeong, Donghee;Lee, Yeungjo;Lee, Youngwoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.84-90
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    • 2017
  • Explosive bolt is coupled in a variety of guided weapons and space projectiles, to perform the separation function. Thus, the role of the explosive bolt in guided weapons systems is very important, as it can cause failure of the entire system in the case of mission failure. For this reason, the design life prediction for explosive bolt is highly and frequently required recently, but its accurate prediction method has not been presented. In order to apply the existing accelerated aging process, we should know the activation energy and the acceleration factor of the explosive bolt. Since the information required for accelerated aging is not presently secured, it is difficult to predict the design life of explosive. Thus, in the present study, we have evaluated the performance of actual explosive bolts in the condition of natural aging over 10 years in order to present a minimum design life.

The influence of a magnetic field on a crystalline structure of carbon nitride deposition (질화탄소 박막 증기 증착 시 자장이 결정 구조 성장에 미치는 영향)

  • 김종일;배선기;박희석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.165-169
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    • 2001
  • Carbon nitride films were grown on Si (100) substrate by a laser-electric discharge method with and without a magnetic field assistance. The magnetic field leads to vapor plume plasma expending upon the ambient arc discharge plasma area. Influence of the magnetic field has resulted in increase of a crystallite size in the films due to bombardment (heating) of Si substrates by energetic carbon and nitrogen species generated during cyclotron motion of electrons in the discharge zone. Many crystalline grains were observed in the morphology of the deposited films by scanning electron microscopy. In order to determine the structural crystalline parameters, X-ray diffraction (XRD) was used to analysis the grown films.

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Influence of a Magnetic Field on High voltage Discharge Plasma Area for Carbon Nitride Film Deposition (질환탄소 박막 증착 시 고전압 방전 플라즈마에 가한 자장의 영향)

  • 김종일;배선기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.184-189
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    • 2002
  • Carbon nitride films were grown on Si (100) substrate by a laser-electric discharge method with/without a magnetic field assistance. The magnetic field leads to vapor plume plasma expending upon the ambient arc discharge plasma area. Influence of the magnetic field has resulted in increased of a crystallite size int he films due to bombardment (heating) of Si substrates by energetic carbon and nitrogen species generated during cyclotron motion of electrons in the discharge zone. The surface morphology of the films with a deposition time of 2 hours was studied using a scanning electron microscopy (SEM). In order to determine the structural crystalline parameters, X-ray diffraction (XRD) was used to analysis the grown films.