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A Study on the Improvement of Safety of Unloading Site by Comparison of Hydrogen Fluoride Leakage Accident (불화수소 누출사고 비교를 통한 하역작업장의 안전성 향상방안에 관한 연구)

  • Woo, Jongwoon;Shin, Changsub
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.32-38
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    • 2018
  • The purpose of this study is to assess quantitatively the amount of leaks and the extent of dispersion in case of a leak at a hydrogen fluoride tank container unloading station, and to suggest a safety improvement plan to prevent recurrence of similar accidents. In 2012, Company H leaks 8 tonnes of tank containers with a maximum storage capacity of 18 Ton, causing it to become a social issue. As a result of calculation using Gaussian plume model, the concentration was estimated to be more than 20ppm from the leak point to 1,321 m radius. The leakage of hydrogen fluoride from the company R in 2014 was estimated to be 11.02 kg, of which 2.9 kg was treated by the scrubber. As a result of calculation using Gaussian plum model, the damage range with a concentration of 20ppm or more from the leak source was estimated to be 69 m in radius. As a result of comparing the above two accidents, it was found that the leakage amount was about 987 times different and the damaged site was more than 19 times different. Therefore, it was concluded that it was necessary to control the wearing of the protective equipment, the enclosure of the unloading site, the installation of the scrubber, and the emergency training to avoid the accidental leakage of a hydrogen fluoride from the unloading site.

Greenhouse Gas (CH4, CO2, N2O) Emissions from Estuarine Tidal and Wetland and Their Characteristics (온실기체 (CH4, CO2, N2O)의 하구언갯벌 배출량과 배출특성연구)

  • Kim, Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.225-241
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    • 2007
  • A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.

An Analysis on the Landscape Structure of Anuisamdong-Dongcheon in the 19th Century (19세기 안의삼동(安義三洞) 동천(洞天)의 경관구조 해석)

  • Kim, Dong-Hyun;Lee, Won-Ho
    • The Journal of the Korea Contents Association
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    • v.16 no.11
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    • pp.742-753
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    • 2016
  • This study aims to reproduce of Anuisamdong's landscape structure and improve the value of Scenic site. It was extract main spot from Geography book published by government in the 19th Century. And analyzed landscape architecture of Dongcheon. Extract main spot from Geography book published by government. Consequently, Hwarim-dong main spot 6 places, Simjin-dong main spot 9 places, and Wonhak-dong main spot 25 places were identified. Hwarim-dong's main spot was divided into 3 places of pavilion and scenery, respectively. Simjin-Dong's main spots was all that natural elements as a scenery. Wonhak-dong's main spot was the most elements of the Anuisamdong in geography book published by government. Hwarim-dong was pavilion-based scenery area complex, Simjin-dong was continues scenery spot along the valley, and Wonhak-dong was hybrid distribution that landscape structure. Each dongcheon in Anuisamdong was created a separate area through isolated geographical, visually for structure of collectively means. Also, a narrow entrance and enclosure topography are areas which arouse atmosphere of paradise. In addition, Aunuisamdong's landscape structure, which was previously divided into individual Dongcheon, was expanded into a single integrated landscape structure of Dongcheon. This is different from the general landscape development of common Dongcheon with the same starting and ending points and sightseeing routes.

Analysis Method for Damage Patterns of Low Voltage Switches for PL Judgment (PL 판정을 위한 저압용 스위치의 소손 패턴 해석기법)

  • Choi, Chung-Seog
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.136-141
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    • 2010
  • The purpose of this study is to examine the structure and heat generation mechanism of low voltage switches used to turn on or off the power supply to an indoor lighting system and investigate how the fixtures and movable contacts of the switches are damaged depending on the types of energy sources in order to secure the judgment base for expected PL disputes. Based on the Korean Standard (KS) testing method for incombustibility, this study applied a general flame to the switch. In addition, current was supplied to the switch using the PCITS (Primary Current Injection Test System). The ambient temperature and humidity were maintained at $22{\pm}2^{\circ}C$ and 40~60% respectively while performing the test. It is thought that the switch generated heat due to a defective connection of the wire and clip, insulation deterioration and defective contact of the movable contact, etc. The surface of the switch damaged by the general flame was uniformly carbonized. When the flame source was removed, the fire on the switch was extinguished naturally. From the result obtained by disassembling the switch carbonized by the general flame, it could be seen that fixtures and movable contacts remained in comparatively good shape but the enclosure, clip support, movable contact, indicating lamp, etc. showed carbonization and discoloration. In the case of the switch damaged by overcurrent, the clip connecting the wires, clip support, etc. showed almost no trace of damage, but the fixtures, movable contact, indicating lamp, etc. were severely carbonized. That is, the sections with high contact resistance were intensively damaged and showed a damage pattern indicating that carbonization progressed from the inside to the outside. Therefore, it is possible to judge the initial energy source by analyzing the characteristics of the carbonization pattern and the metal fixtures of damaged switches.

Effects of Change in Heat Release Rate on Unsteady Fire Characteristics in a Semi-Closed Compartment (반밀폐된 구획에서 발열량 변화에 따른 비정상 화재특성)

  • Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.2
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    • pp.75-83
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    • 2012
  • An experimental study was conducted to investigate the effects of change in heat release rate on unsteady fire characteristics of under-ventilated fire in a semi-closed compartment. A standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time using a spray nozzle located at the center of enclosure. Temperature, heat flux, species concentrations and heat release rate were continuously measured and then global equivalence ratio (GER) concept was adopted to represent the unsteady thermal and chemical characteristics inside the compartment. It was observed that there was a significant difference in unsteady behavior between global and local combustion efficiency, and the GERs predicted by ideal and measured heat release rate were also shown different results in time. The unsteady behaviors of temperature, heat flux and species concentrations were represented well using the GER concept. It was important to note that CO concentration was gradually decreased with the increase in GER after reaching its maximum value in the range of 2.0~3.0 of global equivalence ratio. In addition, the experimental data on unsteady thermal and chemical behaviors obtained in a semi-closed compartment will be usefully used to validate a realistic fire simulation.

Energy Density Control for the Global Attenuation of Broadband Noise Fields (광대역 잡음의 전역 감쇠를 위한 에너지 밀도 제어)

  • Park, Young-Cheol;Yun, Jeong-Hyeon;Youn, Dae-Hee;Cha, Il-Whan
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.2
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    • pp.21-32
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    • 1996
  • The performance of the energy density control algorithm for controlling a broadband noise is evaluated in a one-dimensional enclosure. To avoid noncausality problem of a control filter, which often happens in a frequency domain optimization, analyses presented in this paper are undertaken in the time domain. This approach provides the form of the causally constrained optimal controller. Numerical results are presented to predict the performance of the active noise control system, and indicate that imp개ved global attenuation of the broadband noise can be achieved by minimizing the energy density, rather than the squared pressure. It is shown that minimizing the energy density at a single location yields global attenuation results that are comparable to minimizing the potential energy. Furthermore, unlike the squared pressure control, the energy density control does not demonstrate any dependence on the error sensor location for this one-dimensional field. A practical implementation of the energy-based control algorithm is presented. Results show that the energy density control can be implemented using the two sensor technique with a tolerable margin of performance degradation.

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Indepth Study of Numerical Heat Transfer and Fluid Flow for Energy Saving of Greenhouse (시설하우스 에너지 절감을 위한 열유동 수치 해석 심층 연구)

  • Shin, Mi-Soo;Kim, Hey-Suk;Choi, Jun-Ho;Jang, Dong-Soon
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.466-471
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    • 2007
  • The purpose of study is to obtain basic but important information for the operation of the greenhouse facility located in the suburb of town. Special emphasis is given on the aspect of energy saving method, which can be easilyapplicable in a practical sense. For this end numerical calculation has been made systematically in order to increase the energy efficiency by the evaluation of the temperature distribution in greenhouse. Major parameters considered are primarily the overall shape of greenhouse together with the various conditions of baffle installion inside greenhouse. Further, the performance of heating system is also carefully compared each other for a number of typical arrangements of heating duct. The performance of the computer program developed in this study is evaluated by the observation of the famous fluid trapping phenomenon occurred in staggered baffle condition in the enclosure of greenhouse. Based on the this study, a number of useful conclusions can be drawn, that is, the installation of baffles are quite effective in energy saving method with a minor modification of facility. Also, it is found that the change of the heating duct system can contribute significantly to the uniform temperature distribution in greenhouse. Further other findings obtained by numerical calculation were not only physically consistent and meaningful but also useful for the determination of optimum condition of practical operation of greenhouse.

The Effects of the Area of Openings on the Performance of a $CO_2$ Extinguishing System -The CFD Simulations of the Oil Surface Fire in a Machine Room- (개구부 면적이 $CO_2$ 소화설비의 소화성능에 미치는 영향 -기계실 석유 표면화재의 CFD simulations-)

  • Jeon, Heung-Kyun;Choi, Young-Sang;Park, Jong-Tack
    • Fire Science and Engineering
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    • v.22 no.1
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    • pp.1-9
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    • 2008
  • Carbon dioxide($CO_2$) agent, which has more safely extinguished fire than any other gaseous fire extinguishing agents, has been widely used in various protected enclosures and types of fires. According to the concept of performance-based design(PBD). $CO_2$ extinguishing system to be designed is needed to be evaluated for the performance of fire suppression with possible fire scenarios in an enclosure. In this paper, CFD simulations were carried out to study the effects of opening area on the performance of $CO_2$ extinguishing system and the flow characteristics in the machine room of $100m^3$ in which kerosene spill fire happened. This study showed that time of fire suppression increased linearly in proportion to the size of opening area, and fires for each model were completely suppressed prior to the end of discharge of $CO_2$ agent. It was shown that mass flow rate through opening was influenced by the combined effects of heat release rate of fire and discharge of $CO_2$ agent. After $CO_2$ agent was completely discharged, oxygen concentrations in enclosures for each model were lower than the limit concentration of combustion.

Performance Evaluation of FDS for Predicting the Unsteady Fire Characteristics in a Semi-Closed ISO 9705 Room (반밀폐된 ISO 9705 화재실에서 비정상 화재특성 예측을 위한 FDS의 성능평가)

  • Mun, Sun-Yeo;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.21-28
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    • 2012
  • The objective of this study is to evaluate the prediction accuracy of FDS(Fire Dynamic Simulator) for the thermal and chemical characteristics of under-ventilated fire with unsteady fire growth in a semi-closed compartment. To this end, a standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time (until maximum 2.0 MW based on ideal heat release rate) using a spray nozzle located at the center of enclosure. To verify the capability of FDS, the predicted results were compared with a previous experimental data under the identical fire conditions. It was observed that with an appropriate grid system, the numerically predicted temperature and heat flux inside the compartment showed reasonable agreement with the experimental data. On the other hand, there were considerable limitations to predict accurately the unsteady behaviors of CO and $CO_2$ concentration under the condition of continuous fire growth. These results leaded to a discrepancy between the present evaluation of FDS and the previous evaluation conducted for steady-state under-ventilated fires. It was important to note that the prediction of transient CO production characteristics using FDS was approached carefully for the under-ventilated fire in a semi-closed compartment.

Comparison of Panicle and Spikelet Development in Rice Cultivars Milyang 23 and Koshihikari (벼 품종 밀양 23호와 고시히카리의 유수 및 영화 발달 비교)

  • 강시용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.503-514
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    • 1997
  • The morphogenesis of panicle and spikelet in paddy rice has been studied in high yielding Indica$\times$Japonica hybrid cultivar, Milyang 23 and a Japonica type cultivar, Koshihikari. Germinated seeds planted in $5000^{-1}$ a pots filled with submerged soil and cultured under natural conditions. The young panicle of main stem were continuously dissected and observered by Cryo-SEM from the panicle initiation stage until heading stage. Although the date of panicle differentiation and heading in Koshihikari earlier than those of Milyang 23. the sequence of panicle development in two cultivars begins when first bract primordium at opposite side of flag-leaf primordium differentiated, synchronously followed by growth of the primary branch primordia (PBPs) and secondary branch primordia (SBPs), spikelet primordia(SPs), glumes as lateral organs on rachilla and organs composing single floret, and successive sporogenesis in the young spikelets continue after the enclosure by lemma and palea. The PBPs are acropetally initiated from the base of the panicle primordium, and the SBPs alternately differentiate from the base of upper PBP which differentiate later than the lower PBP. Spikelet development starts at the top of upper side PBP of the young panicle and continue basipetally even though SBPs continue to develop at the lower primary branch. Each PBP, SBP and SP differentiate with differentiation bract or bract hair cell around the base of each their primordia. The observation could confirm that Milyang 23 has not only 2~3 more defferentiated PBPs, but also more SBPs and SPs especially from middle-lower primary branch, at end of their differentiation stages, as compared to those of Koshihikari.

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