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Comparison of Inclusion Complex Formation Capacity of Cyclodextrins with Various Molecules and Characterization of Cyclodextrin-fatty Acid Complex (Cyclodextrin의 Inclusion Complex 형성능과 Fatty Acid와의 Complex 형성조건과 특성)

  • 이용현;정승환박동찬
    • KSBB Journal
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    • v.10 no.2
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    • pp.149-158
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    • 1995
  • The capacity of inclusion complex formation between ${\alpha}$-, ${\beta}$-, ${\gamma}$-cyclodextrins(CDs) and various compounds, such as pH indicators, biloslalns, glycoside, amino acid, and fatty acids, was compared. Fatty acid was identified as the most suitable ligand for fractionation of CDs in terms of capacity and selectivity. The effects of complex formation conditions, such as, mixing ratio of CD and fatty acid, pH, ionic strength, and temperature, on the capacity of fatty acrid-CD complex was also investigated. The carbon number of fatty acids was identified as the most significant factor determining the capacity and selectivity of inclusion complex formation of CDs. Capric acid(C10) and palmitic acid(C16) showed high specificity for ${\alpha}$- and ${\beta}$-CDs, respectively. Under the optimal conditions, the molar ratio of complex formed was found to be 1.0:2.6 for ${\alpha}$-CD/capric acid and 1.0:1.9 for ${\beta}$-CD/palmitic acid. X-ray diffraction and infrared spectrum of the formed inclusion complex were analyzed. The changes of enthalpy($\Delta$H) of the inclusion complex formation reaction was evaluated by differential scanning calorimetry, showed that the reaction was endothermic.

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Test Gases for Gas Burning Appliances of New Gas Group (새 가스그룹의 가스기기 시험가스)

  • Ha, Young-Cheol;Kim, Sung-Min;Lee, Chang-Eon;Choi, Kyoung-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.439-444
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    • 2011
  • To determine the test gases for gas appliances of new gas group, the interrelation between gas interchangeability, including thermal efficiency, of 13A gas appliances and present 13A test gases was experimentally investigated. The test results show that the Wobbe indices in the case of incomplete combustion and the flame lifting limit gas for the new gas group are respectively 2% higher than the upper limit and 1% lower than the lower limit of the Wobbe index range. The most suitable composition of R gas is 96 mol% of methane and 4 mol% of propane; LNG could be also used as R gas. Further, analysis results showed that the hydrogen concentration of flash back limit gas could be lowered from 30 vol% to 23 vol%.

Performance Analysis and Design of a WCDMA Mobile Station's Multi-path Searcher for Down-link with Multiple Transmit Antennas (다수의 송신 안테나가 있는 하향 링크에서 W-CDMA 단말기 다중 경로 검색기의 설계 및 성능분석)

  • Kim Young Ju;Won Seung Hwan;Kim En Ki;Lee Insung
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.1 s.343
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    • pp.95-102
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    • 2006
  • In this paper, we present the performance analysis and design of a multi-path searcher operating over Rayleigh fading channels when multiple transmit antennas are employed in the down-link of W-CDMA system. The simulation results for the receiver operating characteristics (ROC) for 1, 2, and 4 transmit antennas are presented to corroborate the theoretical analyses. We also propose a procedure to find the optimum parameters of double-dwell serial searcher according to the number of the multiple transmit antennas. Our analyses and simulations indicate that post-detection integration is not necessary when the number of transmit antennas is more than two. Finally, we found that increasing transmit diversity order does not necessarily improve the detection performance when the received pilot signal strength is relatively low. Therefore, this gives us a practical criterion on increasing transmit diversity order.

Purification and Characterization of Fibrinolytic Enzyme Produced by Bacillus subtilis K7 Isolated from Korean Traditional Soy Sauce (한국재래간장 발효균 Bacillus subtilis K7 유래의 혈전용해 Protease의 정제 및 특성)

  • Kim, Doo-Young;Lee, Eun-Tag;Kim, Sang-Dal
    • Applied Biological Chemistry
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    • v.46 no.3
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    • pp.176-182
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    • 2003
  • An alkaline fibrinolytic protease-producing bacteria was isolated front Korean traditional soy sauce and identified as Bacillus subtilis K7 from the results of analyses of its morphological and physiological properties, $API^{\circledR}$, and Biolog system. The enzyme was purified by 75% ammonium sulfate fractionation, QAE-Sephadex anion and SP-Sephadex cation exchange column chromatography and Sephadex G-100 gel filtration. The specific activity of the purified enByme was 233.9 unit/mg protein and the yield of enzyme was 3.8%. The homogeneity of the purified enzyme was confirmed by polyacrylamide gel electrophoresis. Molecular mass of the enzyme was estimated about 21,500 Da by SDS-polyacrylamide get electrophoresis and gel chromatography. The optimum temperature and pH for the enzyme activity were $40^{\circ}C$ and 9.0, respectively. The enzyme was stable in a pH range of 5.0 to 12.0, and 60% of its activity was lost on heat treatment at $50^{\circ}C$ for 20 min. The activity of the purified enzyme was inhibited by the presence of $Fe^{2+},\;Ag^{2+},\;Cu6{2+}$, iodoacetate, ethylene diamine tetraacetic acid (EDTA), and trans-1,2-diaminocycloheane-N,N,N',N'-tetraacetic acid (CDTA). The results indicates that the enzyme requires a metal ion for its enzymatic activity.

Traitements sur $R\'{e}sines$ des Euax de Purge de $G\'{e}n\'{e}rateur$ de P. W. R. $Condition\'{e}es$ $\`{a}$ L' Ammoniaque (P.W.R 형(型) 원자로(原子爐)의 증기발생기배수(蒸氣發生器排水)의 Ion 교환처리(交換處理) 연구(硏究))

  • Lee, Sang-Hoon;Park, Sang-Hoon
    • Journal of Radiation Protection and Research
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    • v.2 no.1
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    • pp.24-30
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    • 1977
  • Les eaux de $g\'{e}n\'{e}rateur$ de vapeur d'un $r\'{e}acteur$ P. W. R peuvent $\^{e}tre$ $contamin\'{e}es$ par des $radio-\'{e}lements$. Ces eaux sont habituellement $condition\'{e}es$ 'phosphate' pour limiter leur $agressivit\'{e}$ et la tendence actuelle est de remplacer les phosphate par un conditionment 'Amoniaques'. La $pr\'{e}sente$ $\'{e}tude$ a pour but de definir la $possibilit\'{e}$ $d'{\'{e}}purer$ des eaux $condition\'{e}es$ $\'{a}$ l'ammoniaque $\'{a}$ l'aide $d'{\'{e}}changeurs$ d'ion organiques. Des Facteurs de $D\'{e}contamination$ (F. D) en Cesium 137 et Strontium 90 et la $dur\'{e}e$ du cycle $d'{\'{e}}puration$ ont $d\^{u}$ $\^{e}tre$ bien meilleurs avec une colonne de 10 ml de $r\'{e}sine$ Carborylique Duolite $CC_4$ mise sous forme acide, suivie d'une colonne de 10 ml de $r\'{e}sine$ cationique Amberlite IR 120 mise sous forme acide et suivie d'une colonne de 10 ml de $r\'{e}sine$ anionique Amberlite IRA 400 mise sous forme hydroxyde.

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Conservation strategies and vegetation characteristics of Echinosophora koreensis of Korean endemic plants in DMZ (DMZ 일원 특산식물 개느삼의 생태적 특성 및 보전 방안)

  • An, Jong-Bin;Bak, Gippeum;Park, Jinsun;Jung, JI-Young;Kim, Jun-Il;Shin, Hyun-Tak;Park, Wan-Geun
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.04a
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    • pp.27-27
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    • 2019
  • 본 연구는 한국 특산식물이고, IUCN Red List의 EN(위기종) 등급에 속하는 개느삼(Echinosophora koreensis)을 대상으로 자생지 분포, 식생구조 등의 생태적 특성과 현지 내외 보전 방안을 제시하기 위해 수행되었다. 개느삼의 자생지 분포 조사 결과 강원도 양구군 13곳, 인제군 3곳, 춘천시 2곳, 홍천군 1곳 총 19곳에 분포하는 것을 확인하였다. 개느삼 자생지의 해발고도는 169-711m에 분포하는 것으로 나타났고, 평균 해발고도는 375m 인 것으로 조사되었다. 개느삼 자생지의 면적 조사 결과, $8,000-734,000m^2$인 것으로 분석되었고, 평균 $202,789m^2$으로 조사되었다. 개느삼 자생지의 입지환경 분석을 수행한 결과, 자생지 내 우점종은 교목층에서 소나무가 대부분 우점하였고, 아교목층에서는 신갈나무가 우점하는 것으로 분석되었다. 관목층은 생강나무가 우점하였고, 초본층은 모든 조사구에서 개느삼이 우점하는 것으로 분석되었다. 개느삼 자생지의 식생군집분석 결과, 신갈나무, 소나무, 굴참나무 우점 군집 3개 군집으로 분류되었다. 개느삼 자생지를 대상으로 관속식물상을 조사한 결과, 총 82과 204속 289종 4아종 43변종 5품종 341분류군으로 확인되었다. 개느삼의 출현지점을 이용하여 자생지 분포역 예측 model 중 하나인 MaxEnt 분석을 통하여 잠재 분포지 분석을 수행한 결과, AUC값은 0.9762로 분석되었다. 분포예측 자생지는 강원도 양구군, 인제군, 춘천시, 화천군 지역에 집중되어 분포하는 것으로 나타났다.

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A Power Analysis Attack Countermeasure Not Using Masked Table for S-box of AES, ARIA and SEED (마스킹 테이블을 사용하지 않는 AES, ARIA, SEED S-box의 전력 분석 대응 기법)

  • Han, Dong-Guk;Kim, Hee-Seok;Song, Ho-Geun;Lee, Ho-Sang;Hong, Seok-Hie
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.21 no.2
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    • pp.149-156
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    • 2011
  • In the recent years, power analysis attacks were widely investigated, and so various countermeasures have been proposed. In the case of block ciphers, masking methods that blind the intermediate values in the en/decryption computations are well-known among these countermeasures. But the cost of non-linear part is extremely high in the masking method of block cipher, and so the countermeasure for S-box must be efficiently constructed in the case of AES, ARIA and SEED. Existing countermeasures for S-box use the masked S-box table to require 256 bytes RAM corresponding to one S-box. But, the usage of the these countermeasures is not adequate in the lightweight security devices having the small size of RAM. In this paper, we propose the new countermeasure not using the masked S-box table to make up for this weak point. Also, the new countermeasure reduces time-complexity as well as the usage of RAM because this does not consume the time for generating masked S-box table.

Composition and Cell Cytotoxicity of Essential Oil from Caryopteris incana Miq. in Korea (층꽃나무(Caryopteris incana Miq) 정유의 성분 분석과 세포 독성 평가)

  • Kim, Song-Mun
    • Applied Biological Chemistry
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    • v.51 no.3
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    • pp.238-244
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    • 2008
  • The essential oil was obtained from the aerial part of Caryopteris incana Miq. by steam distillation, samples were collected by headspace (HS) and solid-phase microextraction (SPME) methods, and the compositions of the essential oil were analyzed by gas chromatography-mass spectrometry (GCMS). The fragrance of the essential oil was fougere and woody. There were sixty-nine constituents in the essential oil: 28 carbohydrates, 22 alcohols, 7 acetates, 7 ketones, 3 aldehydes, and 2 others. Major constituents were 4,6,6-trimethyl [1S-($1{\alpha},2{\beta},5{\alpha}$)]-bicyclo[3.1.1]hept-3-en-2-ol (11.8%), taucadinol (9.4%), myrtenyl acetate (9.2%), pinocarvone (7.0%), 1-hydroxy-1,7-dimethyl-4-isopropyl-2,7-cyclodecadiene (6.3%), ${\delta}$-3-carene (6.2%). By SPME extraction, forty-nine constituents were identified: 22 hydrocarbons, 16 alcohols, 6 acetates, 3 ketones, and 2 ethers. Major constituents of the SPME-extracted sample were ${\delta}$-3-carene (12.6%), (-)-myrtenyl acetate (11.2%), 6,6-dimethyl-2-methylene-bicycol [3.1.1] heptan-3-o1 (10.9%), pinocarvone (9.3%). By HS extraction, ten constituents were identified: 5 hydrocarbons, 2 amines, 1 alcohol, and 2 others. Major constituents of the HS-extracted sample were (Z)-2-fluoro-2-butene (34.9%), ${\delta}$-3-carene (6.9%), 6-(4-chlorophenul)tetrahydro-2-methyl-2H-1,2-oxazine (5.9%). The $IC_{50}$ value (0.011 ${\mu}g/mg$) in MTT assay using HaCaT keratinocyte cell line was lower than those of commercially-selling rosemary and tea tree, suggesting more toxicological studies are needed for commercial use of the essential oil of Caryopteris incana Miq.

Declustering Method for Moving Object Database (이동체 데이터베이스를 위한 디클러스터링 정책)

  • Seo YoungDuk;Hong EnSuk;Hong BongHee
    • The KIPS Transactions:PartD
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    • v.11D no.7 s.96
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    • pp.1399-1408
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    • 2004
  • Because there are so many spatio-temporal data in Moving Object Databases, a single disk system can not gain the fast response time and tota throughput. So it is needed to take a parallel processing system for the high effectiveness query process. In these existing parallel process-ing system. it does not consider characters of moving object data. Moving object data have to be thought about continuous report to the Moving Object Databases. So it is necessary think about the new Declustering System for the high performance system. In this paper, we propose the new Dechustering Policies of Moving objet data for high effectiveness query processing. At first, consider a spatial part of MBB(Minimum Bounding Box) then take a SD(SemiAllocation Disk) value. Second time, consider a SD value and time value which is node made at together as SDT-Proximity. And for more accuracy Declustering effect, consider a Load Balancing. Evaluation shows performance improvement of aver-age %15\%$ compare with Round-Robin method about $5\%\;and\;10\%$ query area. And performance improvement of average $6\%$ compare with Spatial Proximity method.

A Development of System for Efficient Quantitative Risk Assessment on Natural Gas Supply Facilities (천연가스 공급시설에 대한 효율적 정량적 위험성 평가를 위한 시스템 구축과 적용)

  • Yoon, Ik-Keun;Oh, Shin-Kyu;Seo, Jae-Min;Lim, Dong-Yeon;Yoon, En-Sup
    • Journal of the Korean Institute of Gas
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    • v.16 no.1
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    • pp.39-45
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    • 2012
  • While the natural gas supply industry has continuously been growing, its potential hazard has also risen since the natural gas facilities essentially require installations that carry highly flammable and pressurized gas close to the populated areas, posing a serious consequence of significant property damage as well as human casualties in the event of accident. Therefore Quantitative Risk Assessment (QAR) has been recognized as a appropriate method to reduce the risk as far as possible, considering the reality of unachievable zero-risk. However, it is hard to perform effective QRA on hundreds of gas facilities because of insufficient number of expert and long-term analysis. In this paper, we suggest a conceptual QRA system framework to support more efficient risk analysis in gas supply facilities. In this system, the experts make questionnaires and internal calculation formula needed in accident frequency/consequence analysis of the facility through pre-analysis on the point of analysis, called incident point, and general users locate the point on the map and input the value required by the questionnaire to obtain the risk. Ultimately, this is suggested based on the idea that the specialization is available in QRA analysis process and the validity of the system is verified through actual system construction and application.