• 제목/요약/키워드: Emulsion Stability

검색결과 572건 처리시간 0.027초

물/n-데칸 에멀젼 연료의 제조 및 유변학적 안정성 평가 (Production of Water/n-decane Emulsion Fuel and Evaluation of Rheological Stability)

  • 김혜민
    • 항공우주시스템공학회지
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    • 제11권4호
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    • pp.8-14
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    • 2017
  • 본 연구에서는 n-데칸과 물을 혼합한 에멀젼 연료를 제조하고, 연료의 유변학적 안정성을 측정하였다. 에멀젼 연료는 n-데칸과 순수, 유화제로 Span 80을 혼합하여 제조되었다. 연료 내부 물 부피비 및 연료온도 증가는 연료의 상분리를 촉진시키는 요소로 확인되었다. 연료의 물 부피비, 온도 및 제조시간 경과에 따른 유변학적 변화를 관찰하였을 때, 물 부피비가 증가할수록 연료의 비뉴턴 유체거동이 확인되었으며, 온도가 높아질수록 연료 내부 물액적 응집으로 인한 점도감소가 관찰되었다. 낮은 물 부피비에서는 연료 제조시간에 따른 점도변화가 크지 않았으나, 혼합비가 3:7 인 경우 3시간 이후부터 점도의 점진적인 감소가 관찰되었다.

Triton X 系를 乳化劑로 하는 Vinyl Acetate 의 乳化重合 (Emulsion Polymerization of Vinyl Acetate with Triton-X as Emulsifier)

  • 정기현;한상구
    • 대한화학회지
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    • 제6권1호
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    • pp.19-24
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    • 1962
  • In the emulsion polymerization of vinyl acetate with Triton-X(Alkyl-aryl-polyether alcohol) and polyvinyl alcohol as emulsifier, some relations between the conditions of polymerization and the polymerization rate, polymerization degree and stability of the emulsion are studied and discussed.

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A study of Polymerization and Thermal Characteristics of Core-Shell Emulsion particles

  • Kim, Nam-Seok
    • 한국응용과학기술학회지
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    • 제28권1호
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    • pp.10-14
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    • 2011
  • Emulsion polymerization was carried out using RMA like MMA, EMA, BMA and Styrene(St.) as monomer for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS. FT-IR, TGA and DSC analysis are used to confirm synthesized core-shell emulsion latexes and to investigate the thermal characteristics of them. From analysis of TGA and DSC, the differences of the decomposition rate and the activation energy are not so large. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene.

Synthesis and Thermo-mechanical Property of Multi-walled Carbon Nanotubes/Poly(methyl methacrylate-co-butyl acrylate) Nanocomposites Prepared Using Emulsion Polymerizations in the Presence of Amphiphilic Random Terpolymer

  • Chang, Woo-Hyuck;Ki, Ho-Seong;Cheong, In-Woo
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.289-289
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    • 2006
  • The carboxylated MWNTs were successfully prepared by conventional acid treatment, and their structures were confirmed by FT-IR, Raman and TEM analysis. The water-dispersibility of the surface modified WNTs were good. The COOH-MWNT will show better stability during the emulsion polymerization as compared with Pristine MWNT. In-situ emulsion polymerizations of methyl methacrylate N(MMA) and n-butyl acrylate (BA) were carried out. Aggregate size and dispersion stability of the CNTs in water phase were measured using dynamic light scattering, turbidity, UV-visible spectrophotometer, and electron microscope. In addition, thermo-mechanical properties of MWNT/polymer nanocomposites were investigated.

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에멀젼을 이용한 Al2O3-ZrO2 복합분체의 제조 : I. 에멀젼 안정화에 대한 열역학적 모델 (Preparation of Al2O3-ZrO2 Composite Powders by the Use of Emulsions: I. Thermodynamic Model of the Emulsion Stability)

  • 한상훈;백종규;송승룡
    • 한국세라믹학회지
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    • 제24권6호
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    • pp.593-601
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    • 1987
  • A thermodynamic model to predict the stability of the water-in-oil type emulsion and the size of the droplets in stable emulsions was developed. Using this model, the effects of various factors government the droplet size in the metal salt solution-kerosene-span 80 system for the preparation of Al2O3-ZrO2 composite powders were investigated. It was shown that the given emulsion systems were thermodynamically unstable in every case but could be kinetically meta stable. When radius ofthe droplet was below nm, the increase in entropy change due to the configurational contribution of small droplets dominated the total free energy change for emulsification. The optimum conditions under which smaller deoplet was obtained were proposed and the validity of the model was proved with diameters of the droplet and composite powders experimentally determined.

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A STUDY ON THE STABILITY, EFFICACY, AND EFFECT OF COLLOIDAL SILVER EMULSION

  • Yun, Kyung-Rho;Ji, Hong-Geun;Seo, Bong-Seok
    • 대한화장품학회지
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    • 제25권4호
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    • pp.75-95
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    • 1999
  • A colloid refers to dispersed particles of a solid or liquid having the diameter of about $10^{-5}-10^{-7}cm$. Such colloidal silver is produced by electrolysis. In this paper, colloidal silvers of various concentrations according to charge amount and time are produced, and their anti-microbial activities are measured. And optimum conditions for emulsion are measured by varying the concentration of colloidal silvers. Further, stability of the emulsion is measured with a Zeta potential, chrome meter by applying colloidal silvers to creams (W/Si, O/W, MLV).

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비 유지방 분말크림 제조시 유화 안정성의 비교 (A Comparison of Emulsion Stability as Non-Dairy Coffee Whitener Preparation)

  • 이병영
    • 한국식품영양학회지
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    • 제4권1호
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    • pp.91-98
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    • 1991
  • This study was carried out to investigate the effect of the emulsion stability according to the quantity of emulsifiers and the pressure of homogenizer in coffee whitener preparation. The results of this study are as follow : 1. To obtain a standard emulsifier, the ratio of mono and triglycerides(Atoms 150), sorbitan monostearate (Span 60) and polyoxylene(20) sorbitan monostearate(Tween 60) was 60 . 20 : 20 and the optimum quantity was about 0.9fS for stable emulsion. 2. Characteristics as coffee whitner were markedly improved when the pressure of homogenizer was 200∼250kg1cmz and homogenizing times are over 4. 3. The good whitening capacity was showed when fat glouble's average diameter was under 0.5 Um.

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Influence of Xanthan, Emulsification Temperature, and Environmental Stresses on the Preparation of Water-in-Corn Oil Emulsions Droplets Coated by Polyglycerol Polyricinoleate

  • Surh, Jeong-Hee
    • Food Science and Biotechnology
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    • 제18권2호
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    • pp.299-306
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    • 2009
  • The purpose of this study was to prepare stable water-in-corn oil (W/O) emulsion droplets coated by polyglycerol polyricinoleate (PGPR). W/O emulsions (20 wt% aqueous phase, 80 wt% oil phase containing 8 wt% PGPR) were produced by high pressure homogenization (Emulsions 1), however, appreciable amount of relatively large water droplets (d>$10{\mu}m$) were found. To facilitate droplet disruption, viscosity of each phase was adjusted: (i) increased the viscosity of aqueous phase by adding 0.1 wt% xanthan (Emulsions 2); (ii) decreased the viscosity of oil phase and aqueous phase by heating them separately at $50^{\circ}C$ for 1 hr immediately before emulsification (Emulsions 3). Homogenizing at the elevated temperature clearly led to a smaller water droplet size, whereas xanthan neither improved nor adversely affected on the microstructures of the emulsions. In addition, the Emulsions 3 had good stability to droplet aggregation under shearing stress, thermal processing, and long term storage.

A STUDY ON THE STABILITY, EFFICACY, AND EFFECT OF COLLOIDAL SILVER EMULSION

  • Yun, Kyung-Rho;Ji, Hong-Geun;Seo, Bong-Seok
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 1999년도 IFSCC . ASCS 학술대회 발표 논문
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    • pp.75-95
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    • 1999
  • A colloid refers to dispersed particles of a solid or liquid having the diameter of about $10^{-5}$ - $10^{-7}$. Such colloidal silver is produced by electrolysis. In this paper. colloidal silvers of various concentrations according to charge amount and time are produced, and their anti-microbial activities are measured. And optimum conditions for emulsion are measured by varying the concentration of colloidal silvers. Further, stability of the emulsion is measured with a Zeta potential. chrome meter by applying colloidal silvers to creams (W/Si. O/W, MLV).

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Stabilization of Ascorbic Acid using Anhydrous Multiple Emulsion

  • Jeon, Jong-Taek;Kim, Yoon-Suk;Ko, Min-Su;Kim, Jong-Geun;Kim, Ik-Soo
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.313-318
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    • 2003
  • Vitamin C's function and mechanism are comparatively well known among the several kinds of vitamins. Inhibition of free radical. promotion of collagen synthesis, restraint of melanin formation and resolution of melanin are its main functions. But Vitamin C is very easy to oxidize by heat, moisture or air so it causes stability problem to make formulation. To solve these problems unique formulating method or derivatives using method could be effective. Object: First, stabilize 10% of Ascorbic acid as polyol/silicone emulsion and try to make polyol/silicone/polyol anhydrous multiple emulsion secondly. And then, encapsulate with porous power to enhance the stability of Ascorbic Acid from formulating method.

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