• Journal of Pharmaceutical Investigation
• /
• v.32 no.1
• /
• pp.13-19
• /
• 2002

Water-lipid soluble multivitamin formulations were widely used to reduce the disease and stress of animals as husbandry has made a remarkable progress in recent. But the efficiency of these formulations is far from satisfactory. So, this study was attempted to develop the physically and chemically stable and useful multivitamin o/w emulsion. Multivitamin o/w emulsion composed of water, soybean oil (10%, v/v), vitamin A, D, E, K, $B_2,\;B_6,\;B_{12}$ and panthenol. To make a stable o/w emulsion, the egg lecithin (2%, w/v) and glycerin (2.5%, w/v) were used for emulsifier and thickening agent, respectively. The oil in water emulsion system was manufactured by microfluidizer and the physicochemical stability of this emulsion was evaluated. The average particle size and interfacial tension were measured. From the result of interfacial tension tested, critical micelle concentration of the egg lecithin was 0.5% (w/v) and optimal concentration for the preparation of emulsion was 2% (w/v). The mean particle size was about $0.6\;{\mu}m$ which was suitable for injections. Short-term accelerated stability as physical stability study was tested by centrifuging and freeze-thawing the emulsion samples. The additions of vitamins resulted in the increment of particle size and reduction of physical stability of emulsion. But it is not an enormous problem for the stability of emulsion. Also, we have performed the long-period preservation stability test for the vitamins. All vitamins were analysed by HPLC. The result of storage under $4^{\circ}C$ and dark conditions demonstrated that all vitamins were maintained stable at least 16 weeks, except for vitamin $B_{12}$.

• Elastomers and Composites
• /
• v.45 no.4
• /
• pp.272-279
• /
• 2010

Starch is an environmental-friendly natural source, more interests are attracted to use starch for synthesis of composites and coating sols. Starch-acrylic coating sols for architectural materials were synthesized by emulsion polymerization. The structures of synthesized materials were characterized by using Infrared spectra, $^1H$-NMR spectra, and physical characteristics were investigated by X-ray diffraction, foaming test, whiteness test, gloss test and tensile strength test. XRD results showed that starch in starch-acrylic copolymer matrix was in an amorphous state. Starch-acrylic emulsion was compounded with 1%, 3%, 5% foaming agent (n-pentane) and 60% $CaCO_3$ solution. The results showed that starch and foaming agent could increase the foamability. Tensile strength increased with the enhancement of starch and foaming agent concentration. But whiteness and gloss decreased with increase of starch and foaming agent concentration.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.39 no.3
• /
• pp.36-40
• /
• 2007

It has been problematic to repulp the dry broke treated with permanent wet strength agents like PAE, UF and MF. Solution type GPAM has the benefit of easy repulping but it has problems of cocross-linking and tends to gel. Therefore, the product concentration must be lower than 10% to reduce the gel generation problem. We developed emulsion type GPAM by an inverse emulsion technology to resolve both the repulping problem with permanent wet strength agents and the stability problem of GPAM solution products.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.29 no.1
• /
• pp.135-150
• /
• 2003

This study is described the stabilizing technology of water-in-oil (w/o) emulsion and the mechanism of emulsification with quaternium-18 hectorite (Q-18 HTRT) by swelling action. When Q-18 HTRT is dispersed in oil, it swells and constructs card-house structure adding ethanol, and formation of water phase is caused by hydrogen bonding. The gelling activities of Q-18 HTRT were excellent such as mineral oil, squalane, cetostearyl isononanoate, isostearic acid, cetyl octanoate, octyl dodecanol and so on. Especially, when oil gel containing Q-18 HTRT passed one to three times by Roll mill. It made the W/O emulsion cream (W/O-ECRM) having 2.0 w/w% of Q-18 HTRT and also produced the control sample (control) including 3.0 w/w% of cetyl PEG/PPG- l0/l dimethicone. The stability of after 24 weeks, Hardness of W/O-ECRM dropped 7.48%, whereas hardness of control went down 57 71%. As a result of these test emulsification of W/O-ECRM is superior compared with control. In cosmetic, 0-18 HTRT can use as suspending agent, oil adsorbent, emulsifying agent, dispersing agent, viscosifier and pigment.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.24 no.3
• /
• pp.38-44
• /
• 1998

The skin permeation and the skin primary irritation of two UV filters from caprylic capryl triglyceride (oil), oil in water (O/W) and water in oil (W/O) emulsions, were evaluated. We selected octyl moth-oxycinnamate (OMC) broadly used in cosmetics and polymeric sunscreen agent (PSA, average MW: 2,000) synthesized by the coupling reaction of 2-ethylhexyl 4-hydroxycinnamate with poly vinylbenzyl chloride, as model UV filters. For in vitro skin permeation experiments, Franz diffusion cells (effective diffusion area:1.766cm) and the excised skin of female hairless mouse aged 8 weeks were used. Oil or emulsion containing UV filters was applied in the donor compartment. The skin primary irritation was evaluated with fe-male guinea pigs (8-10 weeks,350-400 g). In oil and emulsions, the skin permeability and the skin primary irritation of PSA were lower than those of OMC. The skin permeability of UV filters was lower when they were in oil-in-water emulsion (OIW) than water-in-oil emulsion (W/O). We suggest that O/W system would be more useful when compared with W/O system, and PSA could be a good candidate for a future sunscreen agent for reducing the skin irritation.

• Journal of the Korean Applied Science and Technology
• /
• v.6 no.1
• /
• pp.1-7
• /
• 1989

To developed new process for obtaining maximum molecular weight of anionic acrylamide and acrylic acid copolymer by inverse emulsion polymerization. Concentration of initiator, reducing agent, surfactant and mole ratio of acrylamide-acrylic acid were studied for the process. Semi-batch processes with method of redox, control of reaction temperature, feeding method of monomer and reaction time, was suitable for maximum molecular weight of P(AMAC) from this process obtained $3.09\;{\time}\;10^6({\bar{M}}n.)$ and $4.41\;{\time}\;10^6({\bar{M}}w.)$ in molecular weight measured by the intrinsic viscosity method. inverse emulsion polymerization mechanism of P(AMAC) does not followed the Smith-Ewart and Medvedev theory, but selected for concentration of initiator, reducing agent, surfactant, water solubility of monomer.

• Membrane and Water Treatment
• /
• v.10 no.5
• /
• pp.373-379
• /
• 2019

One of the real issues of the recent years is water contamination because of harmful synthetic dyes. Liquid Membranes (LM) resemble a promising alternative to the current separation processes, demonstrating various points of interest as far as effectiveness, selectivity, and operational expenses. The improvement of various Liquid Membranes designs has been a matter of examination by few researchers, particularly for the expulsion of dyes from aqueous solutions. The choice of organic surfactants plays an essential role in the efficiency of the dye removal. In LM design, the most significant step towards productivity is the decision of the surfactant type and its concentration. Liquid emulsion membrane (LEM) was used to remove safranin from aqueous solutions in which the emulsion was made with the help of D2EHPA as carrier, kerosene was used as a diluent and Span 80 (Sorbiton monooleate) was used as an emulsifying agent or surfactant. Various sorts of internal stages were utilized, to be specific sulphuric acid and sodium hydroxide. The impact of parameters influencing extraction efficiency such as pH of feed solution, concentrations of surfactant and emulsifying agent in membrane phase, volume ratio of internal phase to membrane phase, internal phase concentration, agitation speed and time of extraction were analyzed.

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.04a
• /
• pp.291-292
• /
• 2003

Amphiphilic block copolymer는 self-assembly특성을 가지고 있기 때문에 선택된 용매 속에서 nanoscale-domain 즉 micelle을 형성할 수 있다. 이러한 특성은 기타 불용성 물질을 가용화하고 colloidal particle을 안정화시키거나 micro-emulsion을 형성할 수 있어 pharmaceutics, drug delivery system등 영역, 그리고 emulsion stabilizer, thickener, dispersion agent등으로 사용될 수 있다. (중략)

• Microbiology and Biotechnology Letters
• /
• v.23 no.3
• /
• pp.337-345
• /
• 1995

Biosurfactants produced by Pseudomonas aeroginosa KK-7 were purified and their properties were studied. The bacterial surfactant was seperated into two sorts of biosufactants (Type I, 11) by silica gel column chromatograpgy. On the basis of physiochemical analysis, Type I was found to be mixture of two glycolipids with M.W. 800, and Type II was peptide with M.W. 1300. The Type 11 biosurfactant was compose of glutamic acid, proline, glycine, leucine, histidine. The crude extract was used to dertermine some properties as a surfactant. The biosurfactant had the properties as stronger emulsification agent and a stronger stabilizing agent emulsion than any other surfactants tested.

• Journal of Hydrogen and New Energy
• /
• v.20 no.5
• /
• pp.424-431
• /
• 2009

Treatment for water repellency on the carbon supports of GDL which composed a part of MEA has been suggested as a solution to prevent flooding. PTFE is a fluoropolymer that has hydrophobic property and a PTFE emulsion was selected as waterproof agent in this investigation. Carbon paper was coated by PTFE emulsion with different particle size of 5~500 nm and 3~$5\;{\mu}m$ as various concentration. PTFE coated carbon paper has difference in weight variation changed proportionally at PTFE concentration and coating times. Then gas permeability of the coated carbon paper with emulsion of 3~$5\;{\mu}m$ PTFE was changed vastly. Characteristics of carbon paper coated with different PTFE emulsion were analyzed by FE-SEM, FT-IR spcetroscopy and were evaluated by weight variations, gas permeability and water contact angle.