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Characteristics of $Al_2O_3/TiO_2$ multi-layers as moisture permeation barriers deposited on PES substrates using ECR-ALD

  • Gwon, Tae-Seok;Mun, Yeon-Geon;Kim, Ung-Seon;Mun, Dae-Yong;Kim, Gyeong-Taek;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.457-457
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    • 2010
  • Flexible organic light emitting diodes (F-OLEDs) requires excellent moisture permeation barriers to minimize the degradation of the F-OLEDs device. Specifically, F-OLEDs device need a barrier layer that transmits less than $10^{-6}g/m^2/day$ of water and $10^{-5}g/m^2/day$ of oxygen. To increase the life time of F-OLEDs, therefore, it is indispensable to protect the organic materials from water and oxygen. Severe groups have reported on multi-layerd barriers consisting inorganic thin films deposited by plasma enhenced chemical deposition (PECVD) or sputtering. However, it is difficult to control the formation of granular-type morphology and microscopic pinholes in PECVD and sputtering. On the contrary, atomic layer deoposition (ALD) is free of pinhole, highly uniform, conformal films and show good step coverage. Thus, $Al_2O_3/TiO_2$ multi-layer was deposited onto the polyethersulfon (PES) substrate by electron cyclotron resonance atomic layer deposition (ECR-ALD), and the water vapor transmission rates (WVTR) were measured. WVTR of moisture permeation barriers is dependent upon density of films and initial state of polymer surface. A significant reduction of WVTR was achieved by increasing density of films and by applying low plasma induced interlayer on the PES substrate. In order to minimize damage of polymer surface, a 10 nm thick $TiO_2$ was deposited on PES prior to a $Al_2O_3$ ECR-ALD process. High quality barriers were developed from $Al_2O_3$ barriers on the $TiO_2$ interlayer. WVTR of $Al_2O_3$ by introducing $TiO_2$ interlayer was recorded in the range of $10^{-3}g/m^2.day$ at $38^{\circ}C$ and 100% relative humidity using a MOCON instrument. The WVTR was two orders of magnitude smaller than $Al_2O_3$ barriers directly grown on PES substrate without the $TiO_2$ interlayer. Thus, we can consider that the $Al_2O_3/TiO_2$ multi-layer passivation can be one of the most suitable F-OLEDs passivation films.

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Direct Imaging of Polarization-induced Charge Distribution and Domain Switching using TEM

  • O, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.99-99
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    • 2013
  • In this talk, I will present two research works in progress, which are: i) mapping of piezoelectric polarization and associated charge density distribution in the heteroepitaxial InGaN/GaN multi-quantum well (MQW) structure of a light emitting diode (LED) by using inline electron holography and ii) in-situ observation of the polarization switching process of an ferroelectric Pb(Zr1-x,Tix)O3 (PZT) thin film capacitor under an applied electric field in transmission electron microscope (TEM). In the first part, I will show that strain as well as total charge density distributions can be mapped quantitatively across all the functional layers constituting a LED, including n-type GaN, InGaN/GaN MQWs, and p-type GaN with sub-nm spatial resolution (~0.8 nm) by using inline electron holography. The experimentally obtained strain maps were verified by comparison with finite element method simulations and confirmed that not only InGaN QWs (2.5 nm in thickness) but also GaN QBs (10 nm in thickness) in the MQW structure are strained complementary to accommodate the lattice misfit strain. Because of this complementary strain of GaN QBs, the strain gradient and also (piezoelectric) polarization gradient across the MQW changes more steeply than expected, resulting in more polarization charge density at the MQW interfaces than the typically expected value from the spontaneous polarization mismatch alone. By quantitative and comparative analysis of the total charge density map with the polarization charge map, we can clarify what extent of the polarization charges are compensated by the electrons supplied from the n-doped GaN QBs. Comparison with the simulated energy band diagrams with various screening parameters show that only 60% of the net polarization charges are compensated by the electrons from the GaN QBs, which results in the internal field of ~2.0 MV cm-1 across each pair of GaN/InGaN of the MQW structure. In the second part of my talk, I will present in-situ observations of the polarization switching process of a planar Ni/PZT/SrRuO3 capacitor using TEM. We observed the preferential, but asymmetric, nucleation and forward growth of switched c-domains at the PZT/electrode interfaces arising from the built-in electric field beneath each interface. The subsequent sideways growth was inhibited by the depolarization field due to the imperfect charge compensation at the counter electrode and preexisting a-domain walls, leading to asymmetric switching. It was found that the preexisting a-domains split into fine a- and c-domains constituting a $90^{\circ}$ stripe domain pattern during the $180^{\circ}$ polarization switching process, revealing that these domains also actively participated in the out-of-plane polarization switching. The real-time observations uncovered the origin of the switching asymmetry and further clarified the importance of charged domain walls and the interfaces with electrodes in the ferroelectric switching processes.

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Comparison of the Characteristics of Seed Germination and the First Stage of Growth in Cynanchum wilfordii (Maxim.) by Different Light Conditions (광조건별 백수오의 종자 발아 특성 및 초기생육 비교)

  • Yoo, Ji Hye;Seong, Eun Soo;Lee, Jae Geun;Kim, Chul Joong;Choi, Jae Hoo;Lee, Gi Hye;Hwang, In Seong;Hwang, Eun Bee;Lim, Jung Dae;Ahn, Young Sup;Park, Chung Berm;Yu, Chang Yeon
    • Korean Journal of Medicinal Crop Science
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    • v.21 no.5
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    • pp.329-333
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    • 2013
  • This study was carried out to compare the characteristics of seed germination and the first stage of growth in Cynanchum wilfordii (Maxim.) by different light conditions such ass fluorescent light, dark and light emitting diode (LED). There was not much difference from the germination rate of C. wilfordii (Maxim.) in different light conditions for 10 days. The highest of germination rate occurred over 91.11 percentage by LED red condition at $26^{\circ}C$. Also mean germination velocity and promptness index were represented the highest results of 2.3 ea/day and 52.67 under red light, respectively. But mean germination time under both LED red and blue light was represented low data that it takes over three days for germinating of seed. Even though handling both LED red and blue lights, the germination uniformity was not constant. These results may help our understanding of variations in germination characteristics for C. wilfordii (Maxim.) seeds treated under different light conditions.

Characteristics of Halophosphate Phosphor for Long-wavelength UV Prepared by Spray Pyrolysis (분무열분해법에 의해 합성된 장파장 자외선용 할로포스페이트계 형광체의 특성)

  • Sohn, Jong-Rak;Kang, Yun-Chan;Park, Hee-Dong;Yoon, Soon-Gil
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.555-559
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    • 2002
  • Blue-emitting $Sr_{10}$($PO$)$_{6}$ $Cl_2$:$Eu^{2+}$ and $_{(Sr,Mg) }$ 10/($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles for application of long-wavelength UV LED were prepared by ultrasonic spray pyrolysis. The luminescence characteristics under long- wave-length ultraviolet of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ and (Sr,Mg)$_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$^Eu{2+}$ phosphor particles prepared by the spray pyrolysis were compared with that of the commercial product. The PL intensity of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles prepared by the spray pyrolysis was lower than that of the commercial $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles because prepared $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles had porous structure and hollow morphology. However, the PL intensity of the (Sr,Mg)$_{10}$($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles prepared by the spray pyrolysis was 8% higher than that of the commercial one. The high brightness of $(Sr,Mg)_{10}$ ($PO_4$)$_{6}$ $Cl_2$:Eu$^{2+}$ phosphor particles prepared by spray pyrolysis is due to the dense structure and high crystallinity of particles. The TEX>$(Sr,Mg)<_{10}$ ($PO_4$)$_{6}$ /$Cl_2$:$Eu^{ 2+}$ phosphor particles had main emission peak t 448 nm under long- wavelength ultraviolet.

Improvement of Canopy Light Distribution, Photosynthesis, and Growth of Lettuce (Lactuca Sativa L.) in Plant Factory Conditions by Using Filters to Diffuse Light from LEDs (LED 식물공장에서 산란 유리 이용에 의한 상추(Lactuca Sativa L.)의 군락 광분포, 광합성 및 생장 향상)

  • Kang, Woo Hyun;Zhang, Fan;Lee, June Woo;Son, Jung Eek
    • Horticultural Science & Technology
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    • v.34 no.1
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    • pp.84-93
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    • 2016
  • Plant factories with artificial lights require a large amount of electrical energy for lighting; therefore, enhancement of light use efficiency will decrease the cost of plant production. The objective of this study was to enhance the light use efficiency by using filters to diffuse the light from LED sources in plant factory conditions. The two treatments used diffuse glasses with haze factors of 40% and 80%, and a control without the filter. For each treatment, canopy light distribution was evaluated by a 3-D ray tracing method and canopy photosynthesis was measured with a sealed acrylic chamber. Sixteen lettuces for each treatment were cultivated hydroponically in a plant factory for 28 days after transplanting and their growth was compared. Simulation results showed that the light absorption was concentrated on the upper part of the lettuce canopy in treatments and control. The control showed particularly poor canopy light distribution with hotspots of light intensity; thus the light use efficiency decreased compared to the treatments. Total light absorption was the highest in the control; however, the amount of effective light absorption was higher in treatments than the control, and was highest in treatment using filters with a haze factor of 80%. Canopy photosynthesis and plant growth were significantly higher in all the treatments. In conclusion, application of the diffuse glass filters enhanced the canopy light distribution, photosynthesis, and growth of the plants under LED lighting, resulting in enhanced the light use efficiency in plant factory conditions.

A Indoor Management System using Raspberry Pi (라즈베리 파이를 이용한 실내관리 시스템)

  • Jeong, Soo;Lee, Jong Jin;Jung, Won Ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.745-752
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    • 2016
  • In the era of the Internet of Things, where all physical objects are connected to the Internet, we suggest a remote control system using a Raspberry Pi single-board computer with ZigBee, which can turn an indoor light-emitting diode (LED) and a multiple-tap on and off, and with a smart phone can control the brightness of the LED as well as an electronic door lock. By connecting an infrared (IR) transmitter module to the Raspberry Pi, we can control home appliances, such as an air conditioner, and we can also monitor indoor images, indoor temperatures, and illumination by using a smart phone app. We developed a method of finding out IR transmission codes required for remote-controllable appliances with an AVR micro-controller. We suggest a method to remotely open and shut an office door by novating the door lock. The brightness level of an LED (between 0 and 10) can be controlled through a PWM signal generated by an ATmega88 microcontroller. A mutiple-tap is controlled using an ATmega32, a photo-coupler, and a TRIAC. The signals for measured temperature and illumination are converted from analog to digital by using the ATtiny44A microcontroller transmitting to a Raspberry Pi through SPI communication. Then, we connect a camera to the CSI head of the Raspberry Pi. We can turn on the smart multiple-tap for a certain period of time, or we can schedule the multi-tap to turn on at a specific time. To reduce standby power, people usually pull out a power code from multiple-taps or turn off a switch. Our method helps people do the same thing with a smart phone, if they are away from home.

Effects of photoperiod and light intensity on milk production and milk composition of dairy cows in automatic milking system

  • Lim, Dong-Hyun;Kim, Tae-Il;Park, Sung-Min;Ki, Kwang-Seok;Kim, Younghoon
    • Journal of Animal Science and Technology
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    • v.63 no.3
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    • pp.626-639
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    • 2021
  • The purpose of this study was to determine the effects of photoperiod and light intensity on milk production, milk composition, hormones levels and blood metabolites indices of Korean Holstein dairy cows in automatic milking system (AMS). A total of 24 Holstein dairy cows were selected and used to four subsequent treatments for the experimental periods of 60 days. The light programs consisted of (1) Control: the natural photoperiod with 14.2 h of the light period and 9.4 h of the dark period (below 10 Lux); (2) T1: 16 h of the long day photoperiod (LDPP) with 50 Lux of light; (3) T2: 16 h of LDPP with 100 Lux of light; and (4) T3: 16 h of LDPP with 200 Lux of light, respectively. Importantly, there was a significant difference in the thurl activity of dairy cows between the different light intensity programs (p < 0.05). Milk yield was higher in T1 and T2 (40.80 ± 1.71 and 39.90 ± 2.02 kg/d, respectively) than those of Control and T3 (32.18 ± 1.51 and 35.76 ± 2.80 kg/d, respectively) (p < 0.05), but DMI was lower in T1, T2, and T3 compared to Control (p < 0.05). Also, milk fat percentage, the contents of milk fat and total solids were higher in T2 than those in the others (p < 0.05). The average daily melatonin level in milk was high to T3 (28.20 ± 0.43 pg/mL), T2 (24.62 ± 0.32 pg/mL), T1 (19.78 ± 0.35 pg/mL), and Control (19.36 ± 0.45 pg/mL) in order (p < 0.05). Also, the cortisol levels in milk and blood were lower in treatment groups than in Control (p < 0.05). The results of this study showed that it will be effective to improve the milk yield and milk composition, and to reduce the stress of dairy cows when the light conditions regulate to extend the photoperiod to 16 h at a light emitting diode (LED) intensity of 100 Lux under the AMS in dairy farm.

A Study on the Effect of De-NOx Device on GHG Emissions (De-NOx 저감장치가 온실가스 배출량에 미치는 영향 연구)

  • Kim, Sungwoo;Kim, Jeonghwan;Kim, Kiho;Oh, Sang-Ki
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.212-220
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    • 2018
  • As increase the number of vehicles, the issue of greenhouse gas that was emitted by them became important. As a result, greenhouse gas (GHG) regulations are being strengthened and efforts are being actively made to reduce greenhouse gas emissions in the automotive industry. In the other hand, regulations for harmful emission of vehicles have been reinforced by step. Especially, the lastly applied step, so called Euro 6, not only decreased NOx limit down to half of Euro 5 but also introduced real driving emission limit for NOx and PN. It is a challenge for manufacturers to meet the recent GHG regulation as well as the latest emission regulation. To overcome these regulations a De-NOx after-treatment system is being applied to diesel vehicles that are known emitting the lowest GHG among conventional internal combustion engines. At the time of the introduction of Euro 6 emission standard in Korea, in the domestic fuel economy certification test, some diesel vehicles emitted more $CH_4$ than Euro 5 vehicles. As a result, it was confirmed that LNT-equipped vehicles emitted a high level $CH_4$ and the level exceeded the US emission standard. In order to determine the reason, various prior literature was investigated. However, it was difficult to find a detailed study on the methane increase with LNT. In this paper, to determine whether the characteristics of vehicles equipped with LNT the affects the above issue and other greenhouse gases, 6 passenger cars were tested on several emission test modes and ambient temperatures with a environment chamber chassis dynamometer. 2 cars of these were equipped with LNT only, other 2 cars had SCR only, and LNT + SCR were applied to remaining 2 cars. The test result shown that the vehicles equipped with LNT emitted more $CH_4$ than the vehicles with SCR only. Also, $CH_4$ tended to increase as the higher acceleration of the test mode. However, as the test temperature decreases, $CH_4$ tended to decreased. $CO_2$ was not affected by kinds of De-NOx device but characteristic of the test modes.

Effects of Production of Ever-bearing Strawberries Using Cool Air from Mushroom Cultivation House (버섯재배시설의 냉공기 이용이 사계성딸기 생산성에 미치는 영향)

  • Jeoung, Yun-Kyeoung;Park, Ju-Hyen;Ha, Tae Moon;Lee, Young-Suk;Seo, Myeong-Hoon;Kim, In-Chul
    • Journal of Bio-Environment Control
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    • v.28 no.1
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    • pp.28-37
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    • 2019
  • We designed a system that can automatically collect, convey, and control cool air of $15^{\circ}C-20^{\circ}C$ containing carbon dioxide from a mushroom cultivation house to a strawberry plastic house. We recorded the temperature at various positions from July to August 2017. The average temperature of the green house during day and at night was maintained at $33^{\circ}C$ and $26^{\circ}C$, respectively. In the moveable three-tier cylindrical bed, the average temperature around root was maintained at $26^{\circ}C$ and $21^{\circ}C$ during day and at night, respectively. On the high-bench in the green house, the temperature was maintained at $32^{\circ}C$ and $30^{\circ}C$ during day and at night, respectively. The carbon dioxide concentration was maintained around 800-1,600 ppm in the mushroom cultivation system and 400-800 ppm in the strawberry plastic house. The growth characteristics of the strawberry treated with moveable three-tier cylindrical bed were significantly different from those of the untreated high-bench bed. In addition, during the summer season, moveable three-tier cylindrical bed showed more tendency to increase in normal fruit number (NFN) and to decrease in defective fruit number (DFN) compare to the high-bench bed. Therefore, the moveable three-tier cylindrical bed showed a tendency to be more than 2 times higher yields than that of the high-bench bed. It was confirmed that ever-bearing strawberry cultivars could be cultivated in green house due to the cool air supply from the mushroom cultivation system in the summer season.

Application of LEAP Model to Reduce GHG Emissions from Residential Sector (LEAP 모형을 이용한 가정 부문 온실가스 저감효과 분석)

  • Jo, Mi-hyun;Park, Nyun-Bae;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.4 no.3
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    • pp.211-219
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    • 2013
  • This study uses the LEAP model that is a long-term energy analysis model to analyze reduction potential on S city residential sector energy usage for greenhouse gas emission. Energy consumption of S-si in 2009 is consumed most in residential and commerce sector by 39.1%. Also, energy and greenhouse gas emission of residential sector is expected to increase due to increase of households. Therefore, greenhouse gas reduction measures are desperately required in residential sector. For this study recognizes energy consumption of S-si residential sector and has established reduction measure of S-si residential sector greenhouse gas through literature search on domestic and foreign climate change correspondence policies. Also, construction of greenhouse gas reduction potential by reduction measures through LEAP model. There were a total of 5 reduction measures scenarios is Reference Scenario, LED Lighting, Energy Alternative, Green Life Practice, and Total Reduction Measure. As a result, greenhouse gas emission of Light Emitting Diode Lightings by 2020 was $1,181.0thousand\;tonCO_2eq$, decrease of 6.1% compared to the Reference Scenario and Greenhouse gas emission of Energy Alternative by 2020 was $1,171.6thousand\;tonCO_2eq$, decrease of 6.8% compared to the Reference Scenario. Greenhouse gas emission of Green Life Practice by 2020 was $1,128.7thousand\;tonCO_2eq$, decrease of 10.2% compared to the Reference Scenario. For Total Reduction Measures by 2020 emission was $966.9thousand\;tonCO_2eq$, decrease 23.1% compared to Reference Scenario.