• 분석과학
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• 제8권4호
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• pp.411-418
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• 1995

A method for the direct determination of elemental content in each of aerosol particles by inductively coupled plasma atomic emission (ICP-AES) or mass spectrometry (ICP-MS) is described. This method is based upon the introduction of diluted aerosol into an ICP and the measurement of either the flash emission intensities of an atomic spectral line or ion intensities. A pulse-height analyzer is used for the measurement of the distribution of the elemental content. In order to calibrate the measuring system, monodisperse aerosols are used. The potentials of the method are shown by demonstrating the copper emission signals from the aerosols generated at a small electric switch, a study of the relation between the decreasing rate of particle number density and particle size, and measurements of calcium contents in the individual biological cells.

• Bulletin of the Korean Chemical Society
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• 제22권2호
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• pp.159-163
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• 2001

Si3N4 powder has been analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES). The sample was dissolved by high-pressure acid digestion with HF, H2SO4 (1+1), and HNO3 mix ture. This technique is well suited for the impurity analysis of Si3N4 because the matrix interference is eliminated. A round-robin samples trace elements, such as Ca, W, Co, Al, Fe, Mg, and Na, were determined. For the direct analysis, slurry nebulization of 0.96 mm Si3N4 powder also has been studied by ICP-AES. Emission intensities of Fe were measured as ICP operational conditions were changed. Significant signal difference between slurry particles and aqueous solution was observed in the present experiment. Analytical results of slurry injection and high-pressure acid digestion were compared. For the use of aqueous standard solution for calibration, k-factor was determined to be 1.71 for further application.

• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.525-527
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• 2002

• 분석과학
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• 제6권3호
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• pp.297-305
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• 1993

글로우 방전 방출원을 다색화장치에 연결시켜 개발된 글로우방전/방출분광법으로 탄소의 농도가 수 퍼센트에 이르러 스파크방출분광법으로서는 분석이 곤란한 주철시료를 분석하고 정확성을 검토하고자 하였다. 알곤가스 압력, 전압, 방전시간 등 glow discharge lamp(GDL)의 방전조건을 최적화시키고 이 조건에서 두 종류의 주철 표준시료(BAS, LECO)에 대해 원소별 방출 복사선의 세기와 농도의 상관관계를 조사하였다. Mn, Si, P, S 등 대부분 원소의 검정곡선이 양호한 직선성을 보여 주었고 탄소의 경우에는 표준시료의 종류에 따라 절편과 기울기값이 미소하게 계통적인 차이를 나타내었다.

• 대한화학회지
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• 제39권5호
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• pp.399-407
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• 1995

회토류와 악티늄족 원소의 현장분석을 목적으로 휴대용 극미량 분석용 원자 분광계인 Electrothermal-Hollow Cathode Glow Discharge Spectrometry(Et-HCGDS)가 제작되었다.본 분광계의 기본 구조는 전기열과 글로우 방전에 기초를 두고 있으며 본 분광계가 미량의 원소분석에도 유용함을 실험적으로 살펴보았다. 본 연구는 새로이 제작된 Et-HCGDS라는 글로우방전 시스템을 사용하여 공기의 저온 플라스마를 만들고 여기서 얻은 공기의 방출 스펙스럼에 관하여 연구하였다. 본 연구를 통하여 Et-HCGDS를 사용할시에 공기가 흐름가스로 유용하며 이 경우 대기의 분석도 쉽게 이루어질 수 있음을 알았다. 글로우 방전을 이용하여 관찰한 공기의 방출 스펙트럼의 분석을 통하여 볼 때 거의 질소에 의한 방출이 전 자외선과 가시광선 영역에서 골고루 나타남을 살펴보았다. 공기를 흐름가스로 사용할 시에도 여러파장 영역에서 미량 분석이 가능함을 알았다. 이 결과는 앞으로 Et-HCGDS를 사용하여 현장에서 공기만을 사용하여 분석을 수행할 경우에 필요한 기초 자료로 활용될 수 있으리라 본다. 본 연구에서 수행한 공기 방출 스펙트럼의 분석은 대기 분석 및 물질 분석에도 중요한 기초자료로 쓰이게 되리라 기대하며 이와 더불어 방출을 이용한 분광분석에서 공기로 인한 간섭 스펙트럼등을 이해하는 경우에도 중요한 참고자료로 활용되리라 본다.

• Bulletin of the Korean Chemical Society
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• 제19권7호
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• pp.766-770
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• 1998

On-line preconcentration by direct precipitation with hydroxide has been developed and applied for the analysis of Cd in Inductively Coupled Plasma Atomic Emission Spectrometry. Cadmium is continuously precipitated with hydroxide and dissolved by nitric acid in on-line mode. Currently, the enrichment factor is more than 90 times for 20.0 mL of sample and could be further increased very easily. For a large sample throughput, 1.0 mL of sample loop is used and the enrichment factor is 4.5 with the sampling speed of 15/hr. The method has been applied to the analysis of NIST reference sample and has yielded good results with the certified value.

• 한국응용과학기술학회지
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• 제30권4호
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• pp.586-591
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• 2013

본 연구에서는 가속된 이온이 전기장이 걸려있는 freestanding 단결정 실리콘 나노 박막에 충돌했을 때 발생하는 열-전계 전자 방출 특성을 여러 전계 및 열적 조건 아래 체계적으로 분석하였다. 이온 충돌에 의한 열-전계 전자 방출은 쇼트키 효과 (schottky effect)의 선형영역의 특성에 의해 예측된 바와 같이 전계의 세기가 증가할수록 선형적으로 증가했으며, 이온 충돌에 의해 발생하는 열에너지의 제곱에 비례하는 특성을 보여주었다. 이러한 특성들은 실리콘 나노 박막의 질량 분석기용 이온 검출기로의 사용 가능성을 보여준다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제22권6호
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• pp.22-28
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• 2017

The accuracy of analytical results in response to the use of different additives ($NH_4Cl$, KCl, $LaCl_3$) and oxidant gases was evaluated and compared by using Atomic Absorption Spectrometry (AAS). Identification of spectroscopic interferences and possible improvements in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) analysis were also discussed. The average accuracies of total chromium using Certified Reference Materials (CRMs) were found to be 72.1~94.2% in air/acetylene flame condition by AAS, and they were improved to 100.5~110.5% when the oxidants was changed to nitrous oxide rather than adding the additives. The field samples showed similar trends to CRMs, but chromium concentrations were highly variable depending on analytical conditions. The average accuracies using CRMs were estimated to be 89.3~166.1% by ICP-AES, and improved to below 121.7% after eliminating iron interference. Field samples with low chromium and high iron concentration were measured to be > 30% lower in total chromium concentrations by ICP-AES than AAS in nitrous oxide/acetylene flame. Total chromium concentrations in soil could be analyzed with better accuracy under nitrous oxide/acetylene flame by AAS because it was more effective to increase the temperature of the flame than to eliminate the chemical interference for maximizing atomization of chromium. When using ICP-AES, interference substances, total chromium levels, and analytical conditions should be also considered.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1967-1971
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• 2012

A hexavalent chromium (Cr (VI)) is one of the hazardous substances regulated by the RoHS. The determination of Cr (VI) in various polymers and printed circuit board (PCB) has been very important. In this study, the three different analytical methods were investigated for the determination of a hexavalent chromium in Acrylonitrile Butadiene Styrene copolymer (ABS) and PCB. The results by three analytical methods were obtained and compared. An analytical method by UV-Visible spectrometer has been generally used for the determination of Cr (VI) in a sample, but a hexavalent chromium should complex with diphenylcarbazide for the detection in the method. The complexation did make an adverse effect on the quantitative analysis of Cr (VI) in ABS. The analytical method using diphenylcarbazide was also not applicable to printed circuit board (PCB) because PCB contained lots of irons. The irons interfered with the analysis of hexavalent chromium because those also could complex with diphenylcarbazide. In this study, hexavalent chromiums in PCB have been separated by ion chromatography (IC), then directly and selectively detected by inductively coupled plasma atomic emission spectrometry (ICP-AES). The quantity of Cr (VI) in PCB was 0.1 mg/kg.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2018년도 추계학술논문요약집
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• pp.608-609
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• 2018