• Title/Summary/Keyword: Emission spectra

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Tomographic Interpretations of Visible Emissions from the Axisymmetric Partially Premixed Flames (단층진단법을 이용한 축대칭 부분예혼합 화염의 자발광 스펙트럼 해석에 관한 연구)

  • Ha, Kwang-Soon;Choi, Sang-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.6
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    • pp.769-776
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    • 2000
  • Visible spectral characteristics of cross-sectional emissions from a partially premixed methane/air and propane/air flames have been investigated. An optical train with a two-axis scanning mirror system was used to record line-of-sight emission spectra from 354nm to 618nm, and inversion technique was adapted to obtain cross-sectional emission spectra. By analyzing the reconstructed emission spectra, cross-sectional intensities of CH and $C_2$ radicals were separated from the background emissions. The blue flame edge and yellow flame edge were also obtained by image processing technique for edge detection with color photograph of flame. These edges were compared with radial distributions of CH, $C_2$ radicals and background emissions. The CH radicals were observed at blue flame edge. The background emissions were generated by soot precursor at upstream of flame and by soot at downstream of flame. The $C_2$ radicals in propane/air flame were observed more than those in methane/air flame.

Porphyrin-Cored Arylether Dendrimers with Vinyl Groups in the Periphery

  • Lim, So-Yeon;Choi, Dae-Ock;Shin, Eun-Ju
    • Bulletin of the Korean Chemical Society
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    • v.29 no.7
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    • pp.1353-1358
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    • 2008
  • Benzyl arylether dendrimers with zinc porphyrin core and terminal vinyl groups have been synthesized and their photophysical properties and the influence of dendritic environments were investigated. Free base porphyrin-cored benzyl arylether dendrimers 1a-1c and 3a-3c, and their zinc derivatives 2a-2c and 4a-4c have been prepared. Absorption spectra are similar for all porphyrin-cored benzyl arylether dendrimers, except that absorption intensity at 280 nm increases in the higher generation of dendrimer. Fluorescence spectra are similar with two bands for all free base porphyrin dendrimers 1a-1c and 3a-3c, although fluorescence intensity ratio of shorter wavelength emission band to longer wavelength band varies with the generation of dendrimer. Emission efficiencies of 1a-1c and 3a-3c are lower than that of TTP. Emission efficiencies of 2a-2c and 4a-4c are higher than that of ZnTTP. Absorption and emission properties of 1a-1c, 2a-2c, 3a-3c, and 4a-4c were affected negligibly with dendritic environments.

Gas Temperature Measurement in Supersonic Flows by N2+ Emission Spectroscopy (질소 이온 발광 분광법을 이용한 초음속 유동의 기체 온도 측정)

  • Shin, Ji-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.245-250
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    • 2010
  • The procedure for estimating the gas (rotational) temperature of an air discharge in supersonic flows is presented in detail. Since direct measurement of the temperature in a supersonic flow is difficult, a nonintrusive measurement was performed by optical emission spectroscopy based on the emission spectra of nitrogen molecular ions. A detailed explanation, including the equations for emission line intensity, is presented in order to understand the structure of the emission spectra of nitrogen molecular ions. Using the obtained representation for emission spectrum, a synthetic spectrum of the first negative system of $N_2^+$ is obtained, and it is compared with the experimentally measured spectrum. Within a relative error of approximately 6.8% for the overall band spectra, the synthetic and measured spectra agree well. In the case of a 25-mA DC air discharge in a supersonic (Mach 3) flow, the gas temperature profile shows an approximately linear variation and a peak temperature of approximately 350 K.

Modeling Polarized Dust Emission from Aligned Grains by Radiative Torques

  • Lee, Hyeseung;Lazarian, A.;Chepurnov, A.
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.58.1-58.1
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    • 2014
  • We model the polarized dust emission from aligned grains by radiative torques in molecular clouds. We consider various models of molecular clouds and calculate the polarization spectrum from aligned grains by both internal and external radiation fields. We show that some polarization spectrum exhibits the bump at wavelengths ${\lambda}$ < $100{\mu}m$, which can be explained due to the polarized emission from a population of small grains aligned by internal radiation fields. Our polarization spectra can explain the anomalous spectra observed by Hildebrand et al, with the rising polarization toward short wavelengths

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Organic-layer thickness dependent optical properties of top emission organic light-eitting diodes (전면 유기 발광 소자의 유기물층 두께 변화에 따른 광학적 특성)

  • An, Hui-Chul;Joo, Hyun-Woo;Na, Su-Hwan;Kim, Tae-Wan;Hong, Jin-Woong;Oh, Yong-Cheul;Song, Min-Joung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.413-414
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    • 2008
  • We have studied an organic layer thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top emission device, structure is Al(100nm)ITPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(23nm). While a thickness of hole-transport layer of TPD was varied from 35 to 65nm, an emissive layer thickness of $Alq_3$ was varied from 50 to 100nm for two devices. A ratio of those two layers was kept to about 2:3. Variation of the layer thickness changes a traverse time of injected carriers across the organic layer, so that it may affect on the chance of probability of exciton formation. View-angle dependent emission spectra were measured for the optical measurements. Top-emission devices show that the emission peak wavelength shifts to longer wavelength as the organic layer thickness increases. For instance, it shifts from 490 to 555nm in the thickness range that we used. View-angle dependent emission spectra show that the emission intensity decreases as the view-angle increases. The organic layer thickness-dependent emission spectra show that the full width at half maximum decreases as the organic layer thickness increases. Top emission devices show that the full width at half maximum changes from 90 to 35nm as the organic layer thickness increases. In top-emission device, the microcavity effect is more vivid as the organic layer thickness increases.

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THE X-RAY EMISSION FROM EARLY TYPE GALAXIES

  • Kim, Dong-Woo
    • Publications of The Korean Astronomical Society
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    • v.7 no.1
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    • pp.63-69
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    • 1992
  • We have systematically investigated the X-ray spectra of normal galaxies, by using the Imaging Proportional Counter (IPC) data in the Einstein data base. We employed the X-ray color-color plot as well as the standard model fitting method which requires higher signal to noise ratio. We discuss X-ray emission mechanisms in terms of their spectral properties and the signature of cooling flows which are most likely present in X-ray bright early type galaxies. On the average, fits to absorbed thermal spectra show that the X-ray emission temperature of spirals is higher than that of ellipticals. This is consistent with our understanding that accreting binaries are a major X-ray source in spirals, while extended gaseous halos are present in ellipticals. The emission temperature becomes lower with increasing X-ray to optical luminosity ratio in E and S0 galaxies. This result is what we would expect if the emission of X-ray faint early type galaxies consists of a large evolved stellar component, while the gaseous emission becomes dominant in X-ray brighter galaxies. We also find a cool, self-absorbed core in some early type galaxies, which directly indicates the presence of cooling flows in such galaxies.

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Photoluminescence of CaS:Pb Phosphors Grown by Atomic Layer Deposition

  • Kang, Jung-Sook;Kim, Yong-Shin;KoPark, Sang-Hee;Yun, Sun-Jin;Sohn, Sang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.29-30
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    • 2000
  • CaS:Pb thin film used as phosphor layer in electroluminescent devices were deposited by an atomic layer deposition (ALD). The photoluminescence emission and excitation spectra were measured at 5 and 300K for the $CaS:Pb^{2+}$ phosphors with different Pb concentration from 0.001 at.% to 0.648 at.%. The emission spectra of these samples were characterized as UV emission and blue emission with the center of peak around 360 and 425nm, respectively. The UV emission was dominant at the low $Pb^{2+}$ concentration of 0.001 at%, whereas with increase of Pb concentration, the blue emission became a major component and to longer wavelength.

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OBJECTIVE-PRISM SEARCH OF EMISSION-LINE GALAXIES INSIDE THE HYDRA VOID

  • KIM CHULHEE
    • Journal of The Korean Astronomical Society
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    • v.33 no.2
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    • pp.75-80
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    • 2000
  • In order to identify the candidates of emission-line galaxies inside the southern Hydra Void, photo-graphic objective-prism observations with the UK Schmidt Telescope were carried out using the Tech-Pan films for five fields. All observed prism plates were scanned with the APM Facility and the scanned data was processed to determine the APM plate parameters and to draw spectra. For all galaxy spectra, the emission features, the distance between emission features of H$\beta$4861, [OIII]${\lambda}{\lambda}$ 4959, 5007 and the overlapping by nearby objects were investigated by eyeballing. A total of 7 candidates of emission-line galaxies inside the Hydra Void were identified.

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Thickness and Angle Dependent Microcavity Properties in Top-Emission Organic Light-Emitting Diodes (상부 발광 유기 발광 소자에서 두께와 시야각에 따른 마이크로 캐비티 특성)

  • Lee, Won-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.1
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    • pp.32-35
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    • 2011
  • Top-emission device has a merit of high aperture ratio and narrow emission spectrum compared to that of bottom-emission one. Emission spectra of top-emission organic light-emitting diodes depending on a layer thickness and view angle were analyzed using a theory of microcavity. Device structure was manufactured to be Al (100 nm)/TPD/$Alq_3$/LiF (0.5 nm)/Al (2 nm)/Ag (30 nm). N,N'-diphenyl-N,N'- di (m-tolyl)-benzidine (TPD) and tris (8-hydroxyquinoline) aluminium (Alq3) were used as a hole-transport layer and emission layer, respectively. And a thickness of TPD and Alq3 layer was varied in a range of 40 nm~70 nm and 60 nm~110 nm, respectively. Angle-dependent emission spectrum out of the device was measured with a device fixed on a rotating plate. Since the top-emission device has a property of microcavity, it was observed that the emission spectrum shift to a longer wavelength region as the organic layer thickness increases, and to a shorter wavelength region as the view angle increases. Layer thickness and view-angle dependent emission spectra of the device were analyzed in terms of microcavity theory. A reflectivity of semitransparent cathode and optical path length were deduced.

Spectra Responsibility of Quantum Dot Doped Organic Liquid Scintillation Dosimeter for Radiation Therapy

  • Kim, Sung-woo;Cho, Byungchul;Cho, Sangeun;Im, Hyunsik;Hwang, Ui-jung;Lim, Young Kyoung;Cha, SeungNam;Jeong, Chiyoung;Song, Si Yeol;Lee, Sang-wook;Kwak, Jungwon
    • Progress in Medical Physics
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    • v.28 no.4
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    • pp.226-231
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    • 2017
  • The aim is to investigate the spectra responsibilities of QD (Quantum Dot) for the innovation of new dosimetry application for therapeutic Megavoltage X-ray range. The unique electrical and optical properties of QD are expected to make it a good sensing material for dosimeter. This study shows the spectra responsibility of toluene based ZnCd QD and PPO (2.5-diphenyloxazol) mixed liquid scintillator. The QDs of 4 sizes corresponding to an emission wavelength (ZnCdSe/ZnS:$440{\pm}5nm$, ZnCdSeS:470, 500, $570{\pm}5nm$) were utilized. A liquid scintillator for control sample was made of toluene, PPO. The Composition of QD loaded scintillators are about 99 wt% Toluene as solvent, 1 wt% of PPO as primary scintillator and 0.05, 0.1, 0.2 and 0.4 wt% of QDs as solute. For the spectra responsibility of QD scintillation, they were irradiated for 30 second with 6 MV beam from a LINAC ($Infinity^{TM}$, Elekta). With the guidance of 1.0 mm core diameter optical fiber, scintillation spectrums were measured by a compact CCD spectrometer which could measure 200~1,000 nm wavelength range (CCS200, Thorlabs). We measured the spectra responsibilities of QD loaded organic liquid scintillators in two scintillation mechanisms. First was the direct transfer and second was using wave shifter. The emission peaks from the direct transfer were measured to be much smaller luminescent intensity than based on the wavelength shift from the PPO to QDs. The emission peak was shifted from PPO emission wavelength 380 nm to each emission wavelength of loaded QD. In both mechanisms, 500 nm QD loaded samples were observed to radiate in the highest luminescence intensity. We observed the spectra responsibility of QD doped toluene based liquid scintillator in order to innovate QD dosimetry applicator. The liquid scintillator loading 0.2 wt% of 500 nm emission wavelength QD has most superior responsibility at 6 MV photon beam. In this study we observed the spectra responsibilities for therapeutic X-ray range. It would be the first step of innovating new radiation dosimetric methods for radiation treatment.