• Title/Summary/Keyword: Emission enhancement

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Status and Response Strategies of Carbon Labeling in Landscape Architecture (조경분야 탄소성적표지제도 적용실태 및 대응전략)

  • Kim, Jeong-Ho;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.24 no.6
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    • pp.709-720
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    • 2015
  • After analyzing the actual acquisition status of carbon labeling by year and by product for the past four years, as well as its certification in the construction-related sectors of greenhouse gas emission, this study attempted to present the problems and coping strategies upon issuing the carbon labeling certification in the landscape architecture. During the period of this analysis, the carbon labelings were acquired by 134 enterprises, 267 workplaces, and 735 products, while the percentage of acquisition was highest in the regular non-durable goods(49%), followed by energy-consuming durable goods(26%), regular production goods (19%), regular durable goods(3%), and service(3%). Furthermore, the acquisition certifications in construction sectors, were highest in the various pipes/panel(8 cases), followed by concrete(6 cases), gypsum board(4 cases), and landscape architecture materials(2 cases). The landscape architecture only had two cases in the acquisition certification for the first time in 2012, which accounted for 0.27% of the entire certification products, due to the uncertainty in the process, the lack of professionalism, and the lack of comprehension. However, the study conducted on the coping strategies for carbon labeling in the landscape architecture revealed the following: (1) regular reporting system management through the division of labor in the head office and factories, (2) the building of objective DB through the adoption of data management programs such as SAP, (3) continuous promotion and vitalization of the incentive system, (4) the adoption of mandatory or preferential application system in landscaping projects, management, and bidding, (5) enhancement of elasticity in deliberation of certification by recruiting experts in the landscape architecture sectors, and (6) provision of incentives for the cooperative firms acquiring the certification and support for their participation.

Orange Phosphorescent Organic Light-emitting Diodes Using a Spirobenzofluorene-type Phospine Oxides as Host Materials

  • Jeon, Young-Min;Lee, In-Ho;Lee, Chil-Won;Lee, Jun-Yeob;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2955-2960
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    • 2010
  • Spiro-type orange phosphorescent host materials, 9-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-1P) and 5-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-2P) were successfully prepared by a lithiation reaction followed by a phosphination reaction with diphenylphosphinic chloride. The EL characteristics of OPH-1P and OPH-2P as orange host materials doped with iridium(III) bis(2-phenylquinoline)acetylacetonate ($Ir(pq)_2acac$) were evaluated. The electroluminescence spectra of the ITO (150 nm)/DNTPD (60 nm)/NPB (30 nm)/OPH-1P or OPH-2P: $Ir(pq)_2acac$ (30 nm)/BCP (5 nm)/$Alq_3$ (20 nm)/LiF (1 nm)/Al (200 nm) devices show a narrow emission band with a full width at half maximum of 75 nm and $\lambda_{max}$ = 596 nm. The device obtained from OPH-1P doped with 3% $Ir(pq)_2acac$ showed an orange color purity of (0.580, 0.385) and an efficiency of (14 cd/A at 7.0 V). The ability of the OPH-P series to combine a high triple energy with a low operating voltage is attributed to the inductive effect of the P=O moieties and subsequent energy lowering of the LUMO, resulting in the enhancement of both the electron injection and transport in the device. The overall result is a device with an EQE > 8% at high brightness, but operating voltage of less than 6.4 V, as compared to the literature voltages of ~10 V.

Preparation and Bonding Properties of Natural Garlic Adhesives for Wallpaper (벽지용 천연마늘접착제의 제조 및 접착성능)

  • Roh, Jeongkwan;Lee, Jinwha
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.125-132
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    • 2011
  • As the enhancement of indoor air quality is increasingly compelling the use of natural materials without any emission, this study reports the preparation and performance of natural garlic adhesives for wallpaper. The natural garlic adhesives were successfully prepared by the extraction of the clove of raw garlic with water to isolate carbohydrates and proteins. Properties of the prepared garlic adhesives such as the non volatile solids content, viscosity, density, and pH were 62%, 2,789 mPa.s, $1.3g/cm^3$, and 6.6, respectively. The non-volatile solids content has a great impact on the adhesion performance of the prepared garlic adhesives, which was adequate about 60%. Bonding strength of prepared garlic adhesives was greater than the requirement of a Korean standard for wallpaper. In addition, the garlic adhesives showed antibacterial activity inheriting from the garlic. It is expected that the prepared garlic adhesives could be used as safe and natural adhesives without emitting any volatile organic compounds and formaldehyde gas.

The Co-luminescence Groups of Sm-La-pyridyl Carboxylic Acids and the Binding Characteristics between the Selected Doped Complex and Bovine Serum Albumin

  • Yang, Zhengfa;Tang, Ruiren;Tang, Chunhua
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1303-1309
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    • 2012
  • A novel ligand N,N'-(2,6-pyridinedicarbonyl)bis[N-(carboxymethyl)] (L1) was designed and synthesized. Four co-luminescence groups of Sm-La-pyridyl carboxylic acids systems were researched, which are $K_4Sm_{(1-x)}-La_x(L_1)Cl_3{\cdot}y_1H_2O$, $K_4Sm_{(1-x)}La_x(L_2)Cl_3{\cdot}y_2H_2O$, $K_6Sm_{2(1-x)}La_{2x}(L_3)Cl_6{\cdot}y_3H_2O$, $K_4Sm_{(1-x)}La_x(L_4)Cl_3{\cdot}y_4H_2O$. The results indicated the addition of La(III) could sensitize the luminescence of Sm(III) obviously in a certain range, enhancing emission intensity of Sm-pyridyl carboxylic acids relative to the undoped ones. The optimal mole percentages of La(III) in the mixed ions for $L_1$, $L_2$, $L_3$, $L_4$ were confirmed to be 0.6, 0.5, 0.3, 0.6, respectively. The mechanism of the fluorescence enhancement effect was discussed in detail. Furthermore, the binding interaction of $K_4Sm_{0.4}La_{0.6}(L_4)Cl_3{\cdot}5H_2O$ with bovine serum albumin (BSA) have been investigated due to its potential biological activity. The binding site number n was equal to 1.0 and binding constant $K_a$ was about $2.5{\times}10^5\;L{\cdot}mol^{-1}$.

TEMPORAL VARIATIONS OF IO'S MAGNETIC FOOTPRINT BRIGHTNESS

  • WANNAWICHIAN, SUWICHA;PROMFU, TATPHICHA
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.61-64
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    • 2015
  • The brightness of Io's magnetic footprint, an indicator of electromagnetic interaction at the satellite, appears to be strongly connected to the satellite's distance from the plasma equator. As a result, the brightest footprints were detected when Io is near the interception location between the satellite's orbital plane and the plasma equator. However, volcanic activities on Io show strong correlation with the equatorward shift of Jupiter's main auroral oval, consequently causing the disappearance of Io's footprint. The same conclusion was suggested via the observation of Jupiter's hectometric radio emission, called HOM, which closely corresponds to Jupiter's auroral activity. The plasma environment near the Jovian satellites was found to vary significantly at different observational epochs. The electron density increased by approximately a factor of three from the Voyager epoch (1979) to the Galileo epoch (1995), while the electron density was found to be significantly higher (~ 5 times) in the Cassini epoch (2001). In this current study, the magnetic footprints were clearly brighter ten years ago (from peak brightness in 1998-2001) than the footprints detected in 2007. For volcanic activities on Io in 2007, there are two clear activities in February and late May. The magnetic footprint appeared to be dimmer in March 2007, expected to be the result of volcano activities in Feb 2007. However, the magnetic footprint brightness in June appeared to be slightly brighter than the footprints observed in May. The reason could be the time delay between the brightening of the sodium nebula on approximately May 31st and, a while later, the enhancement of flux tube content peaking on approximately June 5th. On the other hand, Io's magnetic footprints were observed during June 1st - 10th when they may not yet have been affected by the increase in mass outflow due to the increase of plasma density.

Fabrication of Ru Nanoparticles Decorated Porous Carbon Nanofibers for Electrochemical Capacitors (Electrochemical capacitor를 위한 Ru 나노입자가 담지 된 다공성 탄소 나노섬유의 제조)

  • Lee, Yu-Jin;An, Geon-Hyoung;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.37-42
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    • 2014
  • Well-distributed ruthenium (Ru) nanoparticles decorated on porous carbon nanofibers (CNFs) were synthesized using an electrospinning method and a reduction method for use in high-performance elctrochemical capacitors. The formation mechanisms including structural, morphological, and chemical bonding properties are demonstrated by means of field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). To investigate the optimum amount of the Ru nanoparticles decorated on the porous CNFs, we controlled three different weight ratios (0 wt%, 20 wt%, and 40 wt%) of the Ru nanoparticles on the porous CNFs. For the case of 20 wt% Ru nanoparticles decorated on the porous CNFs, TEM results indicate that the Ru nanoparticles with ~2-4 nm size are uniformly distributed on the porous CNFs. In addition, 40 wt% Ru nanoparticles decorated on the porous CNFs exhibit agglomerated Ru nanoparticles, which causes low performance of electrodes in electrochemical capacitors. Thus, proper distribution of 20 wt% Ru nanoparticles decorated on the porous CNFs presents superior specific capacitance (~280.5 F/g at 10 mV/s) as compared to the 40 wt% Ru nanoparticles decorated on the porous CNFs and the only porous CNFs. This enhancement can be attributed to the synergistic effects of well-distributed Ru nanoparticles and porous CNF supports having high surface area.

Establishment of a Strategy for the Promotion of an Active Participation in the IAEA Program related to Applications of Radioisotopes and Ionizing Radiation (방사선동위원소.방사선 응용을 위한 IAEA 프로그램의 참여 제고 방안)

  • Kim, Kyeong-Pyo;Lee, Jun-S.;Jung, Sung-Hee
    • Journal of radiological science and technology
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    • v.28 no.2
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    • pp.79-89
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    • 2005
  • This paper presents the overall attributes of the current IAEA programs and their future prospects in the arena of applications of radioisotopes and ionizing radiation, thus dealing with the demand to achieve a condensed understanding of the Agency's programs for an effective and efficient deployment of the respective national R&D projects in Korea. The considerable and beneficial advantages of a participation in the IAEA programs have been reviewed and their immediate relevance has been emphasized. A strategic approach for the enhancement of an active participation in the program and its efficient implementation has also been established. It is anticipated that the proposed recommendations such as the long term strategy and the applicable guidelines will be useful in formulating a nuclear policy for the further development of the international cooperative projects in the future.

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Tungsten oxide interlayer for hole injection in inverted organic light-emitting devices

  • Kim, Yun-Hak;Park, Sun-Mi;Gwon, Sun-Nam;Kim, Jeong-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.380-380
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    • 2010
  • Currently, organic light-emitting diodes (OLEDs) have been proven of their readiness for commercialization in terms of lifetime and efficiency. In accordance with emerging new technologies, enhancement of light efficiency and extension of application fields are required. Particularly inverted structures, in which electron injection occurs at bottom and hole injection on top, show crucial advantages due to their easy integration with Si-based driving circuits for active matrix OLED as well as large open area for brighter illumination. In order to get better performance and process reliability, usually a proper buffer layer for carrier injection is needed. In inverted top emission OLED, the buffer layer should protect underlying organic materials against destructive particles during the electrode deposition, in addition to increasing their efficiency by reducing carrier injection barrier. For hole injection layers, there are several requirements for the buffer layer, such as high transparency, high work function, and reasonable electrical conductivity. As a buffer material, a few kinds of transition metal oxides for inverted OLED applications have been successfully utilized aiming at efficient hole injection properties. Among them, we chose 2 nm of $WO_3$ between NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] and Au (or Al) films. The interfacial energy-level alignment and chemical reaction as a function of film coverage have been measured by using in-situ ultraviolet and X-ray photoelectron spectroscopy. It turned out that the $WO_3$ interlayer substantially reduces the hole injection barrier irrespective of the kind of electrode metals. It also avoids direct chemical interaction between NPB and metal atoms. This observation clearly validates the use of $WO_3$ interlayer as hole injection for inverted OLED applications.

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Unifocal Langerhans Cell Histiocytosis of Frontal Bone in a Child (소아 전두골에 발생한 랑게르한스세포 조직구증)

  • Hong, Seong Jae;Cho, Sang Hun;Eo, Su Rak
    • Archives of Craniofacial Surgery
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    • v.14 no.1
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    • pp.69-72
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    • 2013
  • Lateral eyebrow mass with primary skull lesion are rare in pediatric population. Although epidermoid cyst and dermoid cyst are the most commonly encountered skull lesions in pediatric population, Langerhans cell histiocytosis (LCH) is rarely reported. We report a case of LCH arising from the lateral eyebrow with osteolytic lesion involving the frontal bone. A 5-year-old boy was presented with a hard, fixed mass in his lateral eyebrow. Contrast magnetic resonance imaging revealed inhomogeneous enhancement of the mass with direct invasion of the frontal bone and adjacent dura mater. Under general anesthesia, linear incision at the lateral eyebrow region was made. Intraoperative evaluation revealed hard, fixed and well-defined soft tissue mass. The final extirpated mass was $2.5{\times}2.4cm$ in size, and was accompanied by a $1{\times}1cm$ sized defect on the frontal bone with intact dura mater. The surgical wound was closed primarily by a layer-by-layer fashion. Histologic examination was later performed for definite diagnosis. The histologic examination revealed abnormal proliferation of Langerhans cell with granuloma formation. Radionuclide bone scan and positron emission tomography was taken and revealed free of multi-organ involvement. At 3 months after surgery, natural looking contour at the lateral eyebrow region was observed with no tumor recurrence. Differential diagnosis of the hard and fixed mass at the lateral eyebrow region affecting the primary skull lesion from pediatric population includes epidermoid cyst, dermoid cyst and LCH. Generally, brief physical examination with plain X-ray view can be performed for clinical evaluation, but for a definite diagnosis, contrast MRI may be helpful.

A Review of Roundabout Capacity Model (회전교차로 용량분석 방법에 대한 고찰)

  • An, Hong Ki;Kim, Dong Sun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.2
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    • pp.143-150
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    • 2021
  • Roundabouts have been spreading out all over the world quickly with their attractions including capacity enhancement, safety increase and pollutant emission decrease. The history of Korean roundabout has already been 10 years. However, due to the accumulation of unclear right of way and insufficient data, the advantages of the roundabout are not fully utilized so far. Moreover, there are some differences in the capacity model of roundabouts compared to overseas capacity models. In addition, most research tend to concentrate in evaluation of roundabout performance using computer software. This paper, therefore, investigated overseas typical roundabout capacity models; empirical model and gap acceptance model, and then KHCM 2013 was compared to SIDRA model and USHCM 2010 model. It is expected that this paper will assist and guide practitioners in analyzing and estimating roundabout capacity more precise.