• Title/Summary/Keyword: Emission Spectrum

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Effects of Eu3+ Concentration on the Photoluminescence Properties of Y1-xPO4:Eux3+ Red Phosphor (Eu3+ 함량비가 Y1-xPO4:Eux3+ 적색 형광체의 발광 특성에 미치는 영향)

  • Cho, Seon-Woog;Cho, Shin-Ho
    • Journal of the Korean Vacuum Society
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    • v.20 no.6
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    • pp.430-435
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    • 2011
  • $Y_{1-x}PO_4:{Eu_x}^{3+}$ red phosphors were synthesized with changing the concentration of $Eu^{3+}$ ion by using a solid-state reaction method. The crystal structures of all the red phosphors were found to be a tetragonal system composed of (200) diffraction peak centered at $25.88^{\circ}$, and the morphology of grains approached the spherical form with homeogenous size distribution as the concentration of $Eu^{3+}$ ion increased. As for the photoluminescence properties, all of the ceramic phosphors, irrespective of $Eu^{3+}$ ion concentration, showed the red-orange and the red emission peaked at 593.0 and 619.2 nm respectively. As the concentration of $Eu^{3+}$ ion increased, the excitation spectrum moved into a longer wavelength with the increase of emission intensity. The maximum excitation and the emission spectrum were observed at 0.15 mol of $Eu^{3+}$ ion.

In-Situ Application Study on the Power Plant Valve Leak Diagnosis Using Acoustic Emission Technology (음향방출을 이용한 발전용 밸브 누설 진단 현장 적용 연구)

  • Lee, Sang-Guk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.4
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    • pp.315-322
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    • 2008
  • Valves in power plants are leaking internally by various damages including insertion of foreign objects on seat, seat crack, defects and fatigue crack of stem packing or welds etc. due to severe operating conditions such as high temperature and high pressure for extended period time. Acoustic emission(AE) technology should be applied in order to diagnose precisely and evaluate these valve internal leak. In this paper, results of studies which have accomplished in actual power plant are presented. We have analyzed background noise, AE signal level and frequency spectrum through laboratory tests on the basis of various actual conditions in power plant, and also have considered evaluation methods on the background noise, AE properties and the detectable minimum leak rate according to valve leak conditions through comparing with results of field tests in power plant. As a result of these studies, we conformed that evaluation of internal leak conditions including discrimination of leak or not, and the detectable minimum leak rate is possible, and also it is expected to contribute to safe operation and prevention of energy loss in power plants.

Cracks evolution and multifractal of acoustic emission energy during coal loading

  • Kong, Xiangguo;Wang, Enyuan;He, Xueqiu;Liu, Xiaofei;Li, Dexing;Liu, Quanlin
    • Geomechanics and Engineering
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    • v.14 no.2
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    • pp.107-113
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    • 2018
  • Coal samples with different joints morphology were subjected to uniaxial compression experiments, cracks evolution was recorded by Nikon D5300 and acoustic emission (AE) energy signals were collected by AEwin Test for Express-8.0. During loading process, coal samples deformed elastically with no obvious cracks changes, then they expanded gradually along the trace of the original cracks, accompanied by the formation of secondary cracks, and eventually produced a large-scale fracture. It was more interesting that the failure mode of samples were all shear shape, whatever the original cracks morphology was. With cracks and damage evolution, AE energy radiated regularly. At the early loading stage, micro damage and small scale fracture events only induced a few AE events with less energy, while large scale fracture leaded to a number of AE events with more energy at the later stage. Based on the multifractal theory, the multifractal spectrum could explain AE energy signals frequency responses and the causes of AE events with load. Multifractal spectrum width (${\Delta}{\alpha}$), could reflect the differences between the large and small AE energy signals. And another parameter (${\Delta}f$) could reflect the relationship between the frequency of the least and greatest signals in the AE energy time series. This research is helpful for us to understand cracks evolution and AE energy signals causes.

Study on the Comparison of Piezoelectric Property of Acoustic Sensor for Valve Leak Diagnosis (밸브누설 진단용 PZT 및 Pb-Free 음향센서의 압전특성 비교 연구)

  • Lee, Sang-Guk;Park, Sung-Keun
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3383-3388
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    • 2007
  • To compare the sensor performance of AE leak diagnosis system which can measure valve leak conditions, AE activities such as RMS voltage level, AE signal trend, leak rate degree according to AE database, FFT spectrum were measured on valve of the simulated test system for power plant. AE activities were recorded and analyzed from various operating conditions including different temperature, pressure difference, valve size and fluid using both piezoelectric acoustic emission sensor and Pb-Free acoustic emission sensor. The results of this study are utilized to select the type of sensors, the frequency band for filtering and thereby to improve the signal-to-noise ratio for diagnosis or monitoring of valves in operation. As the final result of application study above, portable type leak diagnosis system by AE was developed. The outcome of the study can be definitely applied as a means of the diagnosis or monitoring system for energy saving and prevention of accident for power plant valve.

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AKARI OBSERVATIONS OF THE INTERSTELLAR MEDIUM

  • Onaka, Takashi
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.187-193
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    • 2012
  • AKARI has 4 imaging bands in the far-infrared (FIR) and 9 imaging bands that cover the near-infrared (NIR) to mid-infrared (MIR) contiguously. The FIR bands probe the thermal emission from sub-micron dust grains, while the MIR bands observe emission from stochastically-heated very small grains and the unidentified infrared (UIR) band emissions from carbonaceous materials that contain aromatic and aliphatic bonds. The multi-band characteristics of the AKARI instruments are quite efficient to study the spectral energy distribution of the interstellar medium, which always shows multi-component nature, as well as its variations in the various environments. AKARI also has spectroscopic capabilities. In particular, one of the onboard instruments, Infrared Camera (IRC), can obtain a continuous spectrum from 2.5 to $13{\mu}m$ with the same slit. This allows us to make a comparative study of the UIR bands in the diffuse emission from the 3.3 to $11.3{\mu}m$ for the first time. The IRC explores high-sensitivity spectroscopy in the NIR, which enables the study of interstellar ices and the UIR band emission at $3.3-3.5{\mu}m$ in various objects. Particularly, the UIR bands in this spectral range contain unique information on the aromatic and aliphatic bonds in the band carriers. This presentation reviews the results of AKARI observations of the interstellar medium with an emphasis on the observations of the NIR spectroscopy.

Organic-layer and reflectivity of transparent electrode dependent, microcavity effect of top-emission organic light-eitting diodes (TE-OLED의 유기물층과 반투명 음전극의 반사도에 따른 마이크로 캐비티 특성)

  • An, Hui-Chul;Na, Su-Hwan;Joo, Hyun-Woo;Mok, Rang-Kyun;Jung, Kyung-Seo;Chio, Seong-Jea;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.299-300
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    • 2009
  • We have studied an organic layer and semitransparent Al cathode thickness dependent optical properties for top-emission organic light-emitting diodes. Device structure is ITO(170nm)/TPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(100nm) and Al(100nm)/TPD(xnm)/$Alq_3$(ynm)/LiF(0.5nm)/Al(25nm). While a thickness of total, organic layer was varied from 85nm to 165nm, a ratio of those two layers was kept to be about 2:3. Then it was compared with that of bottom devices. And a thickness of semitransparent Al cathode was varied from 20nm to 30nm for the device with an organic layer thickness of 140nm. We were able to control the emission spectra from the top-emission organic light-emitting diodes.

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A Study on Fabrication of $ZnSe_{1-x}:Te_x$ Thin Films and Their OPtical Properties ($ZnSe_{1-x}:Te_x$ 박막의 제작과 광학적 특성에 관한 연구)

  • Lee Hong-Chan
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.176-181
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    • 2006
  • In this study, systematical investigations were carried out on crystal qualifies and optical properties of $ZnSe_{1-x}:Te_x$ (x=0.002-0.04) thin films frown by molecular beam epitaxy (MBE). The crystal qualifies and optical properties have been investigated by X-ray diffraction (XRD) and Photoluminescence (PL) measurements, respectively. From the XRD measurements, the crystallographic characteristics showed mediocre crystal quality with increasing the Te composition. From the PL measurements, emission in the visible spectrum region from blue to green was obtained by varying the Te content of the ZnSe:Te epilayers. The efficient blue and green emission were attributed to the recombination of excitons trapped at isoelectronic isolated a single Te atom and $Te_n(n{\geq}2)$ clusters. respectively. The blue emission become dominant in Te tightly doped $ZnSe_{1-x}:Te_x$ $(Te=0.2\%)$ epilayers with increasing temperature. For the Te heavily doping condition $(Te=4.0\%)$, the dominant green emission could be observed at around 160K.

Analysis of Acoustic Emission Signals from Fluid Leakage (유체 누출에서의 음향방출 신호분석)

  • 김용민;윤용구;김호철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.413-421
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    • 1990
  • Acoustic emission signals due to leak from circular holes of 0.4, 1, 2 and 4mm diameter and rectangular slits of different geometry having the same cross section as 4mm diameter hole was studied both analytically and experimentally. Acoustic emission signals from a wide-band type transducer were transformed to digital signals through a digital oscilloscope, and $V_{rms}$ and frequency spectrum were obtained by processing digital signals. Relationships between acoustic parameters and fluid mechanical parameters were derived analytically. A quadrapole aerodynamic model was applied in the analysis of leak from the circular holes and $V_{rms}$ was found to be proportional to the root square of leak rate through the circular hole. A modified model based on dipole source mechanism and laminar equivalent diameter was applied in the analysis of leak signals from the rectangular slits. In the case of constant pressure, $V_{rms}$ increased as the laminar equivalent diameter of slit decreased. In the case of constant laminar equivalent diameter, however the result was similar to that for leak from the circular hole. The frequency spectra of leak signals shows the same frequency characteristics irrespective of the pressure difference.rence.

Growth and Properties of GaN by Vapor Transport Epitaxy (Vapor Transport Epitaxy에 의한 GaN의 성장과 특성)

  • Lee, Jae-Bum;Kim, Seon-Tai
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.479-484
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    • 2006
  • Highly c-axis oriented poly-crystalline GaN with a dimension of $1{\sim}3\;{\mu}m$ was deposited on $c-Al_2O_3$ substrate by vapor transport epitaxy (VTE) method at the temperature range of $900{\sim}1150^{\circ}C$. XRD intensities from (00'2) plane of grown GaNs were increased with reaction conditions which indicate the improvement of the crystal quality. In the PL spectra measured at 10 K, the spectrum composed with the neutral-donor bound exciton-related emission at 3.47 eV, crystal defect-related emission band at 3.42 eV and with its phonon replicas. The fact that intensity of $I_2$ were increased and FWHM were decreased with growth conditions means that the quality of GaN crystals were improved. With this simple VTE technology, we confirm that the GaNs were simply deposited on sapphire substrate and crystal quality related to optical properties of GaN grown by VTE were relatively good. PL emission without deep level emission in spite of polycrystalline structure can be applicable to the fabrication of large area and low cost optical devices using poly-GaN grown by VTE.

Cathodoluminescence of $Mg_2$$SnO_4$:Mn,:Mn Green Phosphor under Low-Voltage Electron Excitation ($Mg_2$$SnO_4$:Mn 녹색 형광체의 저전압 음극선 발광 특성)

  • Kim, Gyeong-Nam;Jeong, Ha-Gyun;Park, Hui-Dong;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.759-762
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    • 2001
  • Mg$_2$SnO$_4$having an inverse spinel structure was selected as a new host material of $Mn^{2+}$ activator. The luminescence of the $Mg_2$SnO$_4$:Mn phosphor prepared by the solid-state reaction were investigated under ultraviolet and low-voltage electron excitation. The Mn-doped magnesium tin oxide exhibited strong green emission with the spectrum centered at 500nm wavelength. It was explained that the green emission in $Mg_2$SnO$_4$:Mn phosphor is due to energy transfer from $^4T_1to ^6A_1\;of\; Mn^{2+}$ ion at tetrahedral site in the spinel structure. The optimum concentration of $Mn^{2+}$/ion exhibiting maximum emission intensity by the low-voltage electron excitation was 0.6mol%. ?

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