• 제목/요약/키워드: Emission Control

검색결과 1,564건 처리시간 0.029초

전자빔 조사에 의한 탄소상 탐침의 성장 (Carbon tip growth by electron beam deposition)

  • 김성현;최영진
    • 한국진공학회지
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    • 제12권2호
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    • pp.144-149
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    • 2003
  • 주사전자현미경을 이용한 전자빔의 직접조사에 의해 실리콘 캔틸레버 위에 탄소상 탐침을 성장하였다. 오일확산 펌프의 잔류가스 분위기에서 실리콘 캔틸레버와 전자빔을 수직으로 정렬한 다음 전자현미경의 스폿 모드를 통해 전자빔을 일정시간 동안 조사시켜 탄소상 탐침을 성장시켰다. 주사전자현미경의 제어변수인 조사시간, 가속전압, 방출 전류, 전자빔 프로브 전류 등을 변화시킴으로써 다양한 종횡비를 가지는 탐침을 성장시킬 수 있었으며, 성장 위치의 표면 형상과 무관하게 탐침을 성장시킬 수 있었다. 그 결과 유효길이 0.5 $\mu\textrm{m}$, 바닥직경 90 nm,콘의 반각 $3.5^{\circ}$인 탐침을 성장시켰다. 탐침이 없는 캔틸레버에 고종횡비 탄소상 탐침을 성장시킬 수 있는 기술은 PZT 박막구동기가 집적화된 AFM 캔틸레버의 탐침 형성 과정에서 발생하는 제작과정의 번거로움을 극복하는데 적용될 수 있다.

저온 증착 Nano-Crystalline TCO

  • 홍문표
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.6-6
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    • 2010
  • Indium Tin Oxide (ITO)를 포함한 Transparent Conduction Oxide (TCO)는 LCD, OLED와 같은 Display, 그리고 Solar Cell 등 광신호와 전기신호간 변환이 필요한 모든 Device에 반드시 필요한 핵심 물질로, 특히 고특성 Display의 투명전극에서 요청되는 95% 이상의 투과도와 $15\;{\Omega}/{\square}$ 이하의 면저항 특성을 동시에 만족할 수 있는 기술은 현재까지 Plasma Sputtering 공정으로 $160^{\circ}C$ 이상에서 증착된 ITO 박막이 유일하다. 그러나, 최근 차세대 기술로서 Plastic Film을 기반으로 하는 Flexible Display 및 Flexible Solar Cell 구현에 대한 요구가 급증하면서, Plastic Film 기판위에 Plasma Damage이 없이 상온에 가까운 저온 ($100^{\circ}C$ 이하)에서 특성이 우수한 ITO 투명전극을 형성 할 수 있는 기술의 확보가 중요한 현안이 되고 있다. 지난 10년 동안 $100^{\circ}C$이하 저온에서 고특성의 ITO 또는 TCO 박막을 얻기위한 다양한 연구와 구체적인 공정이 활발히 연구되어 왔으나, ITO의 결정화 온도 (통상 $150{\sim}180^{\circ}C$)이하에서 증착된 ITO박막은 비정질 상태의 물성적 특성을 보여 원하는 전기적, 광학적 특성확보가 어려웠다. 본 논문에선 기본적으로 절연체 특성을 가져야 하는 산화물인 TCO가 반도체 또는 도체의 물리적 특성을 보여주는 기본원리의 고찰을 토대로, 재료학적 특성상 Crystalline 구조를 보여야 하는 ITO (Complex Cubic Bixbyte Structure)가 Plasma Sputtering 공정으로 저온에서 증착될 때 비정질 구조를 갖게 되는 원인을 규명하고, 이를 바탕으로 저온에서 증착된 ITO가 Crystalline 구조를 유지 할 수 있게 하고, Stress Control에 유리한 Nano-Crystalline 박막을 형성하면서 Crystallinity를 임의로 조절 할 수 있는 새로운 기술인 Magnetic Field Shielding Sputtering (MFSS) 공정과 최근 성과를 소개한다. 한편, 또 다른 새로운 저온 TCO 박막형성 기술로서, 유기반도체와 같은 Process Damage에 매우 취약한 유기물 위에 Plasma Damage 없이 TCO 박막을 직접 형성할 수 있는 Neutral Beam Assisted Sputtering (NBAS) 기술의 원리를 설명하고, 본 공정을 적용한 Top Emission OLED 소자의 결과를 소개한다. 또한, 고온공정이 수반되는 Solar Cell용 투명전극의 경우, 통상의 TCO박막이 고온공정을 거치면서 전기적 특성이 열화되는 원인을 규명하고, 이에 대한 근본적 해결 방법으로 ITO 박막의 Dopant인 Tin (Sn) 원자의 활성화를 증가시킨 Inductively Coupled Plasma Assisted DC Magnetron Sputtering (ICPDMS)의 원리와 박막의 물성적 특성과 내열 특성을 소개한다.

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강변여과에서의 은나노입자의 영향 : 실험실규모 컬럼 실험 (Effect of silver nanoparticles on the performance of riverbank filtration: Column study)

  • 이동현;노진형;김현철;최재원;최일환;맹승규
    • 상하수도학회지
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    • 제29권1호
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    • pp.77-88
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    • 2015
  • Soil column experiments were evaluated effects of silver nanoparticles (i.e., 0, 2.5, 5, and 10 mg/L) on the microbial viability which is strongly associated with the degradation of organic matter, pharmaceutically active compounds(PhACs) and biological oxidation of nitrogenous compounds during river bank filtration. The addition of silver nanoparticles resulted in almost no change in the aqueous matrix. However, the intact cell concentration decreased with addition of silver nanoparticles from 2.5 to 10 mg/L, which accounted for 76% to 82% reduction compared to that of control (silver nanoparticles free surface water). The decrease in adenosine triphosphate was more pronounced; thus, the number and active cells in aqueous phase were concurrently decreased with added silver nanoparticles. Based on the florescence excitation-emission matrix and liquid chromatograph - organic carbon detection analyses, it shows that the removal of protein-like substances was relatively higher than that of humic-like substances, and polysaccharide was substantially reduced. But the extent of those substances removed during soil passage was decreased with the increasing concentration of silver nanoparticles. The attenuation of ionic PhACs ranged from 55% to 80%, depending on the concentration of silver nanoparticles. The attenuation of neutral PhACs ranged between 72% and 77%, which was relatively lower than that observed for the ionic PhACs. The microbial viability was affected by silver nanoparticles, which also resulted in inhibition of nitrifiers.

수질오염총량관리 대상물질 확대를 위한 한강수계 하천수질 경향 및 수질특성 분석 (Analysis of Water Qulity changes & Characterization at the Watershed in Han River Basin for Target indicator in TMDLs)

  • 최옥연;김홍태;서희승;한인섭
    • 한국물환경학회지
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    • 제33권1호
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    • pp.15-33
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    • 2017
  • Based on the existing pollutant emissin standards which are armed at the pollutant concentration of each pollution source, government formulated and implemented new management system of total water pollutant emission. By virtue of this new management system, pollution loading amount of individual watershed could be controlled, which achieved the requirement of water quality management such as TP and BOD. In initiate stage of it's implement, BOD was selected as object of water quality management, While it's necessary to consider the continuity of water quality data and established pollutant management laws and policy. During the ongoing management, TP management was added into the system while simply BOD management was not enough. However, the frequency of algae bloom in Han-river showed a trend of same, even though TP was treated as additional control target. Therefore, this paper will analyze different water quality parameters and characteristic of water quality, so that this study can be provide as reference for watershed management of water quality, by which the applicable management period and target pollutant can be selected in the future.

Ti-6Al-4V 합금에 2nd ATO 처리 후 플라즈마 전해 산화법에 의한 생체활성표면형성 (Formation of Bioactive Surface by PEO-treatment after 2nd ATO Technique of Ti-6Al-4V Alloy)

  • Lim, Sang-Gyu;Cho, Han-Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.74-74
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    • 2018
  • Ti-6Al-4V alloys have been widely used as orthopedic materials because of their excellent corrosion resistance and mechanical properties. However, it does not bind directly to the bone, so it requires a surface modification. This problem can be solved by nanotube and micropore formation. Plasma electrolytic oxidation (PEO) treatment for micropore, which combines high-voltage spark and electrochemical oxidation, is a new way of forming a ceramic coating on light metals such as titanium and its alloys. This method has excellent reproducibility and can easily control the shape and size of the Ti alloy. In this study, formation of bioactive surface by PEO-treatment after $2^{nd}$ ATO technique of Ti-6Al-4V alloy was invesgated by various instrument. Nanotube oxide surface structure was formed on the surface by anodic oxidation treatment in 0.8 wt.% NaF and 1M $H_3PO_4$ electrolytes. After nanotube formation, nanotube layer was removed by ultrasonic cleaning. PEO-treatment was carried out at 280V for 3 minutes in the electrolytic solution containing the bioactive substance (Mg, Zn, Mn, Sr, and Si). The surface of Ti-6Al-4V alloy was observed by field emission scanning electron microscopy (FE-SEM, S-4800 Hitachi, Japan). An energy dispersive X-ray spectrometer (EDS, Inca program, Oxford, UK) was used to analyze the spectra of physiologically active Si, Mn, Mg, Zn, and Sr ions. The PEO film formed on the Ti-6Al-4V alloy surface was characterized using an X-ray diffractometer (TF-XRD, X'pert Philips, Netherlands). It is confirmed that bioactive ions play an essential role in the normal bone growth and metabolism of the human skeletal tissues.

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커먼레일 엔진에서 노킹 진단 알고리즘 구현 및 OBD-II 진단기 S/W 설계 방안 (Implement of Knocking diagnostic algorithm and design of OBD-II Diagnostic system S/W on common-rail engine)

  • 김화선;장성진;남재현;장종욱
    • 한국정보통신학회논문지
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    • 제16권11호
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    • pp.2446-2452
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    • 2012
  • 국내외의 배출가스 규제 강화에 부합하기위하여, 사용자 의도에 따른 연료 분사시기와 분사량 조절이 가능한 커먼레일 ECU를 제어할 수 있는 알고리즘 개발의 필요에 따라서 본 논문에서는 커먼레일 엔진 전용 ECU에 적용할 수 있는 노킹 판별 및 엔진 밸런스 보정이 가능한 노킹 진단 알고리즘을 구현하여 시뮬레이터로 개발하였다. 또한 운전자가 직접 차량을 진단하는 운전자 중심의 진단 서비스를 제공하고자 시뮬레이터의 결과를 OBD-II 표준에 의거하는 차량 위주의 진단기로 개발하고자 한다. 이를 위해 자동차 고장진단 신호 및 센서 출력 신호를 송수신하는 유선 시스템과 무선 시스템인 블루투스 모듈을 이용하여 실시간 통신이 제공될 수 있는 OBD-II 진단기 S/W 설계방안을 제안함으로써 차량의 연비향상 및 유해가스 저감을 통한 엔진의 효율성 향상을 실현하도록 한다.

천연가스 개조 승용차에 대한 실험적 연구(2) - 분사 시스템 평가 (Experimental Study on Natural Gas Conversion Vehicle(2) - Evaluation of Injection System)

  • 김형구;권순태;엄인용
    • 한국자동차공학회논문집
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    • 제23권4호
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    • pp.444-453
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    • 2015
  • In the previous study, several problems were observed in a NG conversion vehicle, which were fail of air-fuel ratio closed loop control, aggravated fuel economy, increased harmful emission and declined roadability. It was provisionally supposed that the mismatch of injection system with the engine caused these performance deterioration. In this context, the characteristics of fuel injection system of commercial conversion kit for NG were investigated experimentally varying the engine speed, fuel rail pressure and volume. The results are as follows; The injection quantity decreases as the engine speed increases due to the extremely small rail volume of the presenting system and flow rate of No. 2 injector are always lower than that of the other ones regardless of the speed under the dynamic operation condition. Furthermore the existing system does not meet the required fuel quantity for the normal engine operation over 3000 RPM. On the other hands, the large rail volume systems ease and/or eliminate the difference of injection quantity between the injectors according to the speed variation, however, these systems decrease injection flow rate and still cannot supply sufficient fuel. Finally, suitable combination of the higher rail pressure and the larger rail volume might be a solution about these problems.

합성가스(Reforming gas)를 이용한 멀티채널 CDPF의 재생 특성 연구 (Studies on Reforming Gas Assisted Regeneration of Multi-channel Catalyzed DPF)

  • 최광춘;정진화;송순호;전광민
    • 한국자동차공학회논문집
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    • 제19권3호
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    • pp.138-145
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    • 2011
  • Diesel particulate filter (DPF) systems are being used to reduce the particulate matter emission of diesel vehicles. The DPF should be regenerated after certain driving hours or distance to eliminate soot in the filter. The most widely used method is active regeneration with oxygen at $550{\sim}650^{\circ}C$. Syngas (synthetic gas) can be used to lower the regeneration temperature of Catalyzed DPF (CDPF). The syngas is formed by fuel reforming process of CPOx (Catalytic Partial Oxidation) at specific engine condition (1500rpm, 2bar) using 1wt.% $Rh/CeO_2-ZrO_2$ catalyst. The oxidation characteristics of PM with syngas supplied to filter were studied using partial flow system that can control temperature and flow rate independently. The filter is coated with washcoat loading of $25g/ft^3$ $Pt/Al_2O_3-CeO_2$, and multi-channel CDPF (MC-CDPF) was used. The filter regeneration experiments were performed to investigate the effect of syngas exothermic reaction on soot oxidation in the filter. For this purpose, before oxidation experiment, PM was collected about 8g/L to the filter at engine condition of 1500rpm, bmep 8bar and flow temperature of $200^{\circ}C$ Various conditions of temperature and concentration of syngas were used for the tests. Regeneration of filter started at 2% $H_2$ and CO concentration respectively and inlet temperature of $260^{\circ}C$. Filter Regeneration occurs more actively as the syngas concentration becomes higher.

18F 동위원소 피폭에 의한 금붕어 장관 평활근의 수축활성 (Contractile Activity of Goldfish Intestine Exposed to 18F Isotope)

  • 문경희;옥치일;조승일;이종규;길상형;서원찬;이병우;손희영;고혜진;박남규
    • 한국수산과학회지
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    • 제41권2호
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    • pp.89-93
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    • 2008
  • Goldfish were exposed to radioactive isotope $^{18}F$, which is used for positron emission tomography (PET). $^{18}F$ is created when the oxygen in water combines with hydrogen on exposure to positrons accelerated by a cyclotron. The temporal change in intestine contractility was measured by physiograph after the exposure to $^{18}F$. The distance between the goldfish and 580 mCi of $^{18}F$ was approximately 4 cm and the exposure was for 4 hrs. The absorption level calculated from the distance, exposure time, and half-life of $^{18}F$ was approximately 2 Gy. The contractile activity of goldfish intestine was lowest on the first day and increased gradually to 100% of the control level by a period of between 5 and 36 days.

Development of Light Transmission Fluctuation for Particle Measurement in Solid-Gas Two Phase Flows

  • YANG, Bin;WANG, Zhan-ping;HE, Yuan;CAI, Xiao-Shu
    • 한국입자에어로졸학회지
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    • 제12권1호
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    • pp.21-26
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    • 2016
  • In order to realize In-line and convenient measurement for solid-gas two phase flows, Light Transmission Fluctuation (LTF) based on the random variation of transmitted light intensity, light scattering theory and cross-correlation method was presented for online measurement of particle size, concentration and velocity. The statistical relationship among transmitted light intensity, particle size and particle number in measurement zone was described by Beer-Lambert Law. Accordingly, the particle size and concentration were determined from the fluctuation signal of transmitted light intensity. Simultaneously, the particle velocity was calculated by cross-correlation analysis of two neighboring light beams. By considering the influence of concentration variation in industrial applications, the improved algorithm based on spectral analysis of transmitted light intensity was proposed to improve measurement accuracy and stability. Therefore, the online measurement system based on LTF was developed and applied to measure pulverized coal in power station and raw material in cement plant. The particle size, concentration and velocity of powder were monitored in real-time. It can provide important references for optimal control, energy saving and emission reduction of energy-intensive industries.