• Title/Summary/Keyword: Emission

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Study on the Measurement of Emission Spectrum and Reaction Mechanism of OH Radical in the Nitrogen Corona Discharge System for Removal of $NO_x$ in Flue Gas (배연가스의 $NO_x$제거용 코로나 방전장치에서 OH 발광 스펙트럼 측정 및 관련 반응 연구)

  • Park, Chul-Woung;Hahn, Jae-Won;Shin, Dong-Nam
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.27-38
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    • 1999
  • We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

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Estimation Technique of Volatile Hazardous Air Pollutants(HAPs) Emitted from Petroleum Industrial Process/Equipment (석유정제산업 공정과 공정장비에 기인한 휘발성 유해 대기오염물질(HAPs)의 배출량 산정기법)

  • Jo, Wan Geun;Gwon, Gi Dong;Dong, Jong In;Gang, Gyeong Hui
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.703-710
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    • 2004
  • Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.

Feasibility Study on Robust Calibration by DoE to Minimize the Exhaust Emission Deviations from Injector Flow Rate Scatters (DoE를 이용한 인젝터 유량 편차에 의한 배출가스 편차에 대한 강건 엔진 매핑 가능성의 검토)

  • Chang, Jin-Seok;Cheong, Jae-Hoon;Jo, Chung-Hoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.134-143
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    • 2008
  • The hardware scatters as well as the engine parameters calibration have strong influences on exhaust emissions in recent diesel engines. In this research DoE(Design of Experiments) optimizations were done to study the possibility of minimizing the emission deviations caused by flow rate scatters of the injectors. It has been shown that the optimization of engine calibration, which minimizes the emission deviations, is feasible by establishing a target function representing the emission deviations for test results of maximum, mean and minimum flow rate injectors. It has also been shown that optimization of both emission deviations and emission level is possible by sequential DoE optimizations of the target functions representing the emission level and the emission deviations respectively with the appropriate boundary limits.

Effect of Heat Loss on CO and NOx Emission Characteristics in the Postflame Region of Premixed Flames (예혼합 화염후류에서 열전달이 CO 및 NOx 생성 특성에 미치는 영향)

  • Kim, Jong-Min;Kim, Tae-Hyun;Kum, Sung-Min;Kim,, Se-Won;Jang, Gi-Hyun;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.13 no.4
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    • pp.1-7
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    • 2008
  • Strict pollutant regulations of NOx emission and increasing awareness of the environmental damage stimulated interest in research to obtain useful information regarding CO and NOx reductions at the same time. In this study, $CH_4$/air premixed flame was examined numerically to reduce CO and NOx emission level simultaneously in the post-flame region by the heat loss models in which radiative and combined conductive and convective heat losses were included. To reduce the NOx emission, first heat exchanger location was decided near the flame. After first heat exchanger was decided for the optimal NOx emission(about 30 ppm), in order to decide the optimal CO emission(about 30ppm), seocond heat exchanger location was tested and decided for several cases. Finally, the optimal location of heat exchanger for minimal CO and NOx emission simultaneously were determined and suggested.

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A Study on CO2 Emission Factor for Earth-Work Equipment Using C-FVM (C-FVM을 이용한 토공장비의 CO2 배출계수에 관한 연구)

  • Kim, Byung-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.3
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    • pp.999-1006
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    • 2014
  • $CO_2$ emission factor for earthwork equipment was made based on fuel consumption quantity using IPCC carbon emission factor. This is presented through the carbon emission estimating guideline each facilities by the Ministry of Land, Infrastructure and Transportation in 2011. However, this method has the defect which don't apply the various condition of site. Therefor it needs the new emission factor supplemented these defects. This study will tries to estimate $CO_2$ emission with the direct measurement method using concentration flow velocity measurement (C-FVM) for earth work equipment and present the new $CO_2$ emission factor for earth work equipment after compare with emission factor of the Ministry of Land, Infrastructure and Transportation.

Development of NH3 Emission Factors using a Dynamic Flux Chamber in a Sewage Treatment Plant (부유형 챔버를 이용한 하수처리장에서의 암모니아 배출 특성 연구)

  • Jeon, Eui-Chan;Sa, Jae-Hwan;Park, Jong-Ho
    • Journal of Environmental Impact Assessment
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    • v.14 no.5
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    • pp.263-273
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    • 2005
  • In this study, the major emission procedures and emission characteristics were identified at the site of sewage treatment plant which is one of the major sources of ammonia. At the same time the emission factors and emission rates were estimated. In order to calculate the emission flux, we used a Dynamic Flux Chamber(DFC), which is found to be a proper sampling devise for area sources such as sewage treatment plant. It was found that the most stable sampling condition was when the stirrer's speed of DFC was 120RPM, and it would be the best time to take a sample 60 minutes later after setting the chamber. The relatively higher flux was shown in Autumn compared to summer and winter. Annual ammonia emission rates procedures were calculated as $906.32{\mu}g/activity-ton$, $1,114.72{\mu}g/activity-ton$ and $437.53{\mu}g/activity-ton$ each at the primary settling basin, aeration basin and the final settling basin, respectively. The ammonia emission rate the highest at in the aeration basin according to this test. This results was due to that the surface of aeration basin or the final settling basin is relatively wider than the primary settling basin.

Emission Characteristics of Dual-Side Emission OLED with Al Cathode Thickness Variation (Al 음극 두께 변화에 따른 양면 발광 OLED의 발광 특성)

  • Kim, Ji-Hyun;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.48 no.4
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    • pp.174-178
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    • 2015
  • We studied emission characteristics for blue fluorescent dual-side emission OLED with Al cathode thickness variation. In the bottom emission OLED of Al cathode with 10, 15, 20, 25, 30, and 150 nm thickness, maximum luminance showed 36.1, 8,130, 9,300, 12,000, 13,000, and $12,890cd/m^2$, and maximum current efficiency showed 2, 8.8, 10, 10.5, 10.8, and 11.4 cd/A, respectively. The emission characteristics of the bottom emission seemed to be improved according to decrease of resistance as the thickness of Al cathode increase. In the top emission OLED of Al cathode with 10, 15, 20, 25, and 30 nm thickness, maximum luminance showed 4.3, 351, 131, 88.6, and $33.2cd/m^2$, and maximum current efficiency showed 0.23, 0.38, 0.21, 0.16, and 0.09 cd/A, respectively. It yielded the highest maximum luminance and maximum current efficiency in Al cathode thickness 15 nm. It showed a tendency to decrease as the thickness of Al cathode increase. The reason for this is due to decrease of transmittance with increasing of Al cathode thickness. The electroluminescent spectra of bottom and top emission OLED were not change.

A Comparison Study on Isoprene Emission Rates from White Oak (갈참나무로부터 발생되는 이소프렌의 배출속도 비교 연구)

  • Son, Youn-Suk;Kim, Jo-Chun;Kim, Ki-Joon;Lim, Yong-Jae;SunWoo, Young;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.791-798
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    • 2006
  • In order to investigate the NVOC (Natural Volatile Organic Compound) emissions from White Oak, the emission rates of isoprene were measured according to season, weather conditions, and the age of the tree. The analysis of seasonal emission rates showed that the emission rates were the highest during summer followed by spring and fall. The emission rates during summer were found to be nearly 8 times greater than those during fall. In addition, it was observed that the emission rates of isoprene depends on PAR and temperature. Moreover, the effect of age on the emission rates was studied, and the White Oak in the age range of $21{\sim}30$ had higher emission rates than that in the range of $41{\sim}50$. Accordingly, the current result indicates that the isoprene emissions are affected by both meteorological parameter and the age of a tree.

Effect of Shell Structure of Artificial Lightweight Aggregates on the Emission Rate of Absorbed Water (인공경량골재의 표피층 구조가 흡수된 물의 방출속도에 미치는 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.750-754
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    • 2008
  • The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

Field emission properties of the silicon field emission arrays coated with diamond-like carbon film prepared by filtered cathodic vacuum arc technique (진공아크방전으로 제작된 다이아몬드상 탄소 박막이 코팅된 실리콘 전계 방출 소자의 전계 방출 특성)

  • 황한욱;김용상
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.326-331
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    • 2000
  • We have fabricated the field emitter arrays coated with diamond-like carbon (DLC) films that improved the field emission characteristics. The nitrogen doped DLC films are prepared by the filtered cathodic vacuum are (FCVA) tehnique. The activation energy of the nitrogen doped DLC films are derived from electrical conductivity measurements. The silicon field emission arrays (FEAs) were prepared by the VLSI technique. The turn-on field was rapidly decreasing and the emission current was remarkably increasing the DLC-coated FEAs than the non-coated silicon FEAs. In the nitrogen doped FEAs, the turn-on field decreased and the emission current increased with increasing the nitrogen found out the field emission current and the work function of the DLC-coated FEAs was remarkably decreased than that of the non-coated silicon FEAs. As nitrogen doping concentrations are increased the work function of FEAs is decreased and the field emission properties are improved in nitrogen doped DLC-coated FEAs. This phenomenon in due the fact that the Fermi energy level moves to the conduction band by increasing nitrogen doping concentration.

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