• Title/Summary/Keyword: Elevated temperatures

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MAGNETIC PROPERTIES OF NANOCRYSTALLIZED METALLIC GLASSES AT ELEVATED TEMPERATURES

  • Lachowicz, Henryk K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.589-596
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    • 1995
  • In the present paper some of the magnetic properties of the nanocrystalline Fe-based magnets produced by an appropriate annealing of their metallic glass precursors are reviewed. These properties are discussed on the grounds of their characteristics measured at the elevated temperatures. It is shown that the effective magnetostriction these magnets display, results from the competition among two contributions of the opposite sign originating from the individual magnetic phases, crystalline phase and the residual glassy matrix in which the nanocrystallites are embedded. It is also shown that at certain conditions the magnets considered expose superparamagnetic behavior and that their isothermal magnetization characteristics can successfully be used to calculate the distribution of the particle volumes. Application of the recently invented new genetic algorithm method, a powerful tool to calculate these distributions is, finally, presented.

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Covalent Adaptable Liquid Crystal Elastomers Comprising Thiourea Bonds: Reprocessing, Reprogramming and Actuation

  • Lee, Jin-Hyeong;Park, Sungmin;Kim, Yong Seok;Kim, Dong-Gyun;Ahn, Suk-kyun
    • Elastomers and Composites
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    • v.57 no.2
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    • pp.55-61
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    • 2022
  • In this work, we report a highly deformable covalent adaptable-liquid crystal elastomer (CA-LCE) comprising dynamic thiourea bonds that enable macromolecular network rearrangement at elevated temperatures. The exchange of chain network is verified through stress-relaxation analyses and follows Arrhenius-type behavior. The unique capability of rearranging the chain network in the CA-LCE provides useful properties, such as welding, melt reprocessing, and shape reprogramming, that cannot be achieved by the conventional LCE comprising permanent crosslinks. Reversible actuation is further demonstrated by reprogramming the polydomain CA-LCE into a monodomain via mechanical stretching at elevated temperatures.

Ratcheting assessment of austenitic steel samples at room and elevated temperatures through use of Ahmadzadeh-Varvani Hardening rule

  • Xiaohui Chen;Lang Lang;Hongru Liu
    • Structural Engineering and Mechanics
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    • v.87 no.6
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    • pp.601-614
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    • 2023
  • In this study, the uniaxial ratcheting effect of Z2CND18.12N austenitic stainless steel at room and elevated temperatures is firstly simulated based on the Ahmadzadeh-Varvani hardening rule (A-V model), which is embedded into the finite element software ABAQUS by writing the user material subroutine UMAT. The results show that the predicted results of A-V model are lower than the experimental data, and the A-V model is difficult to control ratcheting strain rate. In order to improve the predictive ability of the A-V model, the parameter γ2 of the A-V model is modified using the isotropic hardening criterion, and the extended A-V model is proposed. Comparing the predicted results of the above two models with the experimental data, it is shown that the prediction results of the extended A-V model are in good agreement with the experimental data.

Analytical model for CFRP strengthened circular RC column under elevated temperature

  • Rashid, Raizal S.M.;Aboutaha, Riyad S.
    • Computers and Concrete
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    • v.13 no.4
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    • pp.517-529
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    • 2014
  • In order to increase the load carrying capacity and/or increase the service life of existing circular reinforced concrete bridge columns, Carbon Fiber Reinforced Polymer (CFRP) composites could be utilized. Transverse wrapping of circular concrete columns with CFRP sheets increases its axial and shear strengths. In addition, it provides good confinement to the concrete column core, which enhances the bending and compressive strength, as well as, ductility. Several experimental and analytical studies have been conducted on CFRP strengthened concrete cylinders/columns. However, there seem to be lack of thorough investigation of the effect of elevated temperatures on the response of CFRP strengthened circular concrete columns. A concrete confinement model that reflects the effects of elevated temperature on the mechanical properties of CFRP composites, and the efficiency of CFRP in strengthened concrete columns is presented. Tensile strength and modulus of CFRP under hot conditions and their effects on the concrete confinement are the primary parameters that were investigated. A modified concrete confinement model is developed and presented.

Influence of Tool Coating on Frictional Behavior of AZ31B Mg Alloy at Elevated Temperature (금형 표면 처리가 AZ31B 마그네슘 합금의 온간 마찰 특성에 미치는 영향에 관한 연구)

  • Han, S.S.
    • Transactions of Materials Processing
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    • v.30 no.1
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    • pp.43-48
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    • 2021
  • The success of warm forming of Mg alloy sheet is greatly influenced by friction at elevated temperature, depending on the surface treatment of the tool. The tool coating affected the frictional characteristics of AZ31B Mg alloy sheet at elevated and room temperatures. The frictional behavior of the Mg alloy sheet at room temperature was not significantly affected by surface treatment conditions of the tool, but was significantly affected at elevated temperature. When the contact pressure is high, a few surface-treated tools exhibit a higher coefficient of friction than those without surface treatment. It is important to select the surface treatment conditions of the tool in order to ensure appropriate friction during warm forming of Mg alloy sheet.

Crystal structure of the pretense domain of an ATP-independent heat shock protease HtrA

  • Kim, Dong-Young;Kim, Dong-Ryoung;Ha, Sung-Chul;Neratur K.Lokanath;Hwang, Hye-Yeon;Kim, Kyeong-Kyu
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.24-24
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    • 2002
  • HtrA (high temperature requirement A), a periplasmic heat shock protein, is known to have molecular chaperone function at low temperatures and proteolytic activity at elevated temperatures. To investigate the mechanism of functional switch to pretense, we have determined the crystal structure of the N-terminal protease domain (PD) of HtrA from Thermotoga maritima. HtrA PD shares the same fold with chymotrypsin-like serine professes. However, crystal structure suggests that HtrA PD is not an active pretense at current state since its active site is not formed properly and blocked by an additional helical lid. On the surface of the lid, HtrA PD has hydrophobic patches that could be potential substrate binding sites for molecular chaperone activity. Present structure suggests that the activation of the proteolytic function of HtrA PD at elevated temperatures might occur by the conformational change.

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Deformation of Amorphous GeSe2 Film under Uniaxial Pressure Applied at Elevated Temperatures

  • Jin, Byeong Kyou;Lee, Jun Ho;Yi, Jeong Han;Lee, Woo Hyung;Shin, Sang Yeol;Choi, Yong Gyu
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.108-113
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    • 2015
  • In an effort to evaluate the practicability of an imprinting technique for amorphous chalcogenide film in Ge-based compositions, we investigate the deformation behavior of the surface of amorphous $GeSe_2$ film deposited via a thermal evaporation route according to varying static loads applied at elevated temperatures. We observe that, under these static loading conditions, crystallization tends to occur on its surface relatively more easily than in As-based $As_2Se_3$ films. As for the present $GeSe_2$ film, higher processing temperatures are required in order to make its surface reflect the given stamp patterns well; however, in this case, its surface becomes partially crystallized in the monoclinic $GeSe_2$ phase. The increased vulnerability of this amorphous $GeSe_2$ film toward surface crystallization under static loading, when compared with the $As_2Se_3$ counterpart, is explained in terms of the topological aspects of its amorphous structure.

Behavior of Plasma-doped Graphene upon High Temperature Vacuum Annealing

  • Lee, Byeong-Joo;Jo, Sung-Il;Jeong, Goo-Hwan
    • Applied Science and Convergence Technology
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    • v.27 no.5
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    • pp.100-104
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    • 2018
  • Herein, we present the behavior of plasma-doped graphene upon high-temperature vacuum annealing. An ammonia plasma-treated graphene sample underwent vacuum annealing for 1 h at temperatures ranging from 100 to $500^{\circ}C$. According to Raman analysis, the structural healing of the plasma-treated sample is more pronounced at elevated annealing temperatures. The crystallite size of the plasma-treated sample increases from 13.87 to 29.15 nm after vacuum annealing. In addition, the doping level by plasma treatment reaches $2.2{\times}10^{12}cm^{-2}$ and maintains a value of $1.6{\times}10^{12}cm^{-2}$, even after annealing at $500^{\circ}C$, indicating high doping stability. A relatively large decrease in the pyrrolic bonding components is observed by X-ray photoelectron spectroscopy as compared to other configurations, such as pyridinic and amino bindings, after the annealing. This study indicates that high-vacuum annealing at elevated temperatures provides a method for the structural reorganization of plasma-treated graphene without a subsequent decrease in doping level.

Size effect on strength of Fiber-Reinforced Self-Compacting Concrete (SCC) after exposure to high temperatures

  • Gulsan, M. Eren;Abdulhaleem, Khamees N.;Kurtoglu, Ahmet E.;Cevik, Abdulkadir
    • Computers and Concrete
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    • v.21 no.6
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    • pp.681-695
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    • 2018
  • This pioneer study investigates the size effect on the compressive and tensile strengths of fiber-reinforced self-compacting concrete (FR-SCC) with different specimens, before and after exposure to elevated temperatures. 432 self-compacting concrete (SCC) specimens with two concrete grades (50 and 80MPa) and three steel fiber ratios (0%, 0.5% and 1%) were prepared and tested. Moreover, based on the experimental results, new formulations were proposed to predict the residual strengths for different specimens. A parametric study was also carried out to investigate the accuracy of proposed formulations. Residual strength results showed that the cylinder specimen with dimensions of $100{\times}200mm$ was the most affected, while the cube with a size of 100 mm maintained a constant difference with the standard cylinder ($150{\times}300mm$). Temperature effect on the cube specimen (150 mm) was the least in comparison to other specimen sizes and types. In general, provision of steel fibers in SCC mixtures resulted in a reduction in temperature effect on the variance of a conversion factor. Parametric study results confirm that the proposed numerical models are safe to be used for all types of SCC specimens.