• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1061-1066
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• 2009

Two fluoro-substituted 2-pyrazoline derivatives, 1-phenyl-3-(4-methoxyphenyl)-5-(4-fluorophenyl)-2-pyrazoline (1) and 1-phenyl-3-(4-methoxyphenyl)-5-(2-fluoro-phenyl)-2-pyrazoline (2) have been synthesized and characterized by elemental analysis, IR, UV-Vis and fluorescence spectra. The crystal structure of 1 has been determined by X-ray single crystal diffraction. For the two compounds, density functional theory (DFT) calculations of the structures and natural population atomic charge analysis (NPA) have been performed at B3LYP/6-311G** level of theory. By using TD-DFT method, electron spectra of 1 and 2 have been predicted, which are very approximate with the experimental ones. Comparative studies on 1 and 2 indicate that the location change of fluorine atom in 5-position phenyl ring of 2-pyrazoline does not make significant change of geometries and electronic transition bands, but it leads to evident change of atomic charge distributions and peak intensities of UV and fluorescence spectra.

• Structural Engineering and Mechanics
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• 제71권2호
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• pp.197-210
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• 2019

Probabilistic buckling behavior of sandwich panel considering random system parameters using a radial basis function (RBF) approach is presented in this paper. The random system properties result in an uncertain response of the sandwich structure. The buckling load of laminated sandwich panel is obtained by employing higher-order-zigzag theory (HOZT) coupled with RBF and probabilistic finite element (FE) model. The in-plane displacement variation of core as well as facesheet is considered to be cubic while transverse displacement is considered to be quadratic within the core and constant in the facesheets. Individual and combined stochasticity in all elemental input parameters (like facesheets thickness, ply-orientation angle, core thickness and properties of material) are considered to know the effect of different degree of stochasticity, ply- orientation angle, boundary conditions, core thickness, number of laminates, and material properties on global response of the structure. In order to achieve the computational efficiency, RBF model is employed as a surrogate to the original finite element model. The stiffness matrix of global response is stored in a single array using skyline technique and simultaneous iteration technique is used to solve the stochastic buckling equations.

• Structural Engineering and Mechanics
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• 제14권5호
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• pp.505-520
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• 2002

Based on the modal coordinates of the structure, a finite-element and CQC (complete quadratic combination) method for analyzing the coupled buffeting response of long-span bridges is presented. The formulation of nodal equivalent aerodynamic buffeting forces is derived based on a reasonable assumption. The power spectral density and variance of nodal displacements and elemental internal forces of the bridge structure are computed using the finite-element method and the random vibration theory. The method presented is very efficient and can consider the arbitrary spectrum and spatial coherence of natural winds and the multimode and intermode effects on the buffeting responses of bridge structures. A coupled buffeting analysis of the Jiangyin Yangtse River Suspension Bridge with 1385 in main span is performed as an example. The results analyzed show that the multimode and intermode effects on the buffeting response of the bridge deck are quite remarkable.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1993년도 추계학술대회 논문집
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• pp.218-223
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• 1993

An UBET(Upper Bound Elemental Technique) program has been developed to analyze forging load, die-cavity filling and effective strain distribution for flashless forging. To analyze the process easily, it is suggested that the deformation is divided into two different parts. Those are axisymmetric part in corner and plane-strain part in lateral. The total power consumption is minimized through combination of two deformation parts by building block method, from which the upper-bound forging load, the flow pattern, the grid pattern, the veocity distribution and the effective strain are determined. To show the merit of flashless forging, the result of flashless and flash forging processes are compared through theory and experiment. Experiments have been carried out with plasticine billets at room temperature. The theoretical predictions of the forging load and the flow pattern are in good agreement with the experimental results.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1999년도 추계학술대회논문집
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• pp.18-21
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• 1999

The wrinkling of thin sheet metal induced by compressive instability is one of major defects in sheet metal forming processes. compressive instability is influence by many factors such as mechanical properties of the sheet material geometry of the sheet contact conditions and plastic anisotropy. The analysis of compressive instability in a plastically deforming body is rather difficult because the effects of the above-mentioned factors are rather complex and the instability behavior may show swide variations even for small deviations of the factors. in this work the bifurcation theory is introduced for the finite elemental analysis of the instability behavior of a thin sheet with initially sound geometry and property. All the above-mentioned factors are conveniently considered by the finite element method. The instability limit is found by introducing a criterion scheme into the incremental analysis and the post-bifurcation behavior is analyzed by introducing the branching scheme. Wrinkling initiation and growth in the deep drawing process are analyzed.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2382-2388
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• 2007

A series of dimethine cyanine dyes were synthesized in a fast, efficient and high yield by the condensation of quaternary salts with 1H-indole-3-carbaldehyde in the presence of piperidine under solvent-free microwave irradiation. The products were identified by 1H NMR, IR, UV-Vis spectra and elemental analysis. The absorption and fluorescence properties of these dyes were investigated both experimentally and theoretically. Calculations performed at a combination of time-dependent density functional theory (TD-DFT) and the polarizable continuum model (PCM) reproduced the π-π* type absorption bands of the dyes. Regression analysis was used for studying theoretical results of the absorption maxima in different solvents. Compared with experimental counterparts, estimated overall uncertainties in the absorption maxima were about ±2%.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.1033-1038
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• 2003

A wind turbine obtains its power input by converting the force of the wind into a torque (turning force) acting on the rotor blades. The amount of energy which the wind transfers to the rotor depends on the density of the air, the rotor area, and the wind speed. Because it has long term operating life and very complex load condition, the fatigue strength of each component must be considered. In this paper, we calculated the load condition by wind using a combined blade elemental theory and a FEM based analytical approach was use to evaluate the fatigue strength of a Hub of wind turbine. The effect of tensile mean stress was taken into account by the modified Goodman diagram. Using this approaches, we evaluated the fatigue strength of hub and main shaft and improved the design.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1994년도 추계학술대회 논문집
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• pp.223-228
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• 1994

A new velocity formulation technique, which contains the advantage of UBET and the shape function of FEM, is proposed. In the proposed technique, a shape function is used to improve the unreasonableness of elemental partition and to solve the difficulty of velocity-field determination. In order to verify the effectiveness of this rechnique, T-shaped forging processes are simulated. The results are compared with these obtained by experimental measurements in T-shaped forging. In T-shaped forging, good agreements between theory and experiment are also confined.

• 한국항해학회지
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• 제22권3호
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• pp.17-25
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• 1998

This paper describes elemental technologies for the creation of three-dimensional(3-D) sound-field to implement the next-generation Ship Handling Simulator with human -computer interaction, known as Virtual Reality. In the virtual reality system, Head-Related Transfer Functions(HRTF's) are used to generate 3-D sound environmental context. Where, the HRTF's are impulse response characterizing the acoustical transformation in a space. This work is divided into two parts, the part Ⅰis mainly for the model constructions of the HRTF's, the part Ⅱis for the control of 3-D sound-field by using the HRTF's . In this paper, as first part, we search for the theory to formulate models of the HRTF's which reduce the dimensionalityof the formulation without loss of any directional information . Using model HRTF's we report results from psychophysical tests used to asses the validity of the proposed modleing method.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2889-2894
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• 2013

A new complex [$Ni(phen)(C_9H_8Br_2NO_3)_2{\cdot}2CH_3OH{\cdot}2H_2O$] [phen: 1,10-phenanthroline $C_9H_8Br_2NO_3$: 3,5-dibromo-L-tyrosine] was synthesized and characterized by IR, elemental analysis and single crystal X-ray diffraction. X-ray crystallography shows that Ni(II) ion is six-coordinated. The Ni(II) ion coordinates with four nitrogen atoms and two oxygen atoms from three ligands, forming a mononuclear Ni(II) complex. The crystal crystallizes in the Orthorhombic system, space group $P2_12_12$ with a = 12.9546 ${\AA}$, b = 14.9822 ${\AA}$, c = 9.9705 ${\AA}$, V = 1935.2 ${\AA}$, Z = 1, F(000) = 1008, S = 0.969, ${\rho}_{calcd}=1.742g{\cdot}cm^{-3}$, ${\mu}=4.688mm^{-1}$, $R_1$ = 0.0529 and $wR_2$ = 0.0738 for 3424 observed reflections (I > $2{\sigma}(I)$). Theoretical study of the title complex was carried out by density functional theory (DFT) method and the B3LYP method employing the $6-3l+G^*$ basis set. The energy gap between HOMO and LUMO indicates that this complex is prone to interact with DNA. CCDC: 908041.