• Title/Summary/Keyword: Elemental ratio

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An Analysis of Aerosol Mass Concentrations and Elemental Constituents Measured at Cheongwon depending on the Backward Trajectories of Air Parcel in East Asia in 2011 (2011년 동아시아에서 기류의 이동 경로에 따른 청원에서 측정한 에어로졸 질량 농도 및 원소 성분 분석)

  • Kim, Hak-Sung;Byun, Kwang-Tae;Chung, Yong-Seung;Choi, Hyun-Jung;Kim, Min-Jung
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.855-863
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    • 2012
  • This study analyzed mass concentrations of TSP, PM10 and PM2.5 and elemental constituents according to the isentropic backward trajectories of air parcel from Cheongwonin East Asia during the period January - October, 2011. Mass concentrations of the continental polluted airflow (CP) showed levels of TSP and PM10 mass concentrations higher than the continental background airflow (CB). Also, PM2.5 mass concentrations of anthropogenic fine particles ran higher in CP than in CB. The elemental constituents and elemental constituent ratio ended up varying depending on the origin of atmospheric aerosols generated. The average absolute content of elemental constituents reached its height in CB, the ratio of anthropogenically originating elements (PE) among the all elements (AE) analyzed marked a high in CP, and Mg+Na/AE reached its height in the oceanic airflow (OA). At the same time, TSP, PM10 and PM2.5 mass concentrations, the ratio of PM2.5/TSP and PE/AE element ratio ran higher in CP than CB. Episodes of large-scale transport of atmospheric pollutants as observed at Cheongwon were 8 cases and 22 days. The ratios of PM10, PM2.5 among TSP mass concentrations showed different results and the ratios of PM2.5 showed an increasing trend in the episodes of anthropogenic air pollution transport. Overall, dustfall episodes show a level of elemental constituents higher than those of anthropogenic air pollution.Dustfall episodes were observed to contain more of Fe, Al and Ca originating from continental soils and those of air pollution were observed to contain more of Zn, Mn, Cu and Pb. By difference in contents of absolute elemental constituents, episodes of anthropogenic air pollution showed a high PE/AE rate, and dustfall episodes a high SE/AE rate.

Compression of Elemental Images Using Block Division in 3D Integral Imaging (3D 집적 영상에서 영역 분할을 이용한 요소 영상의 압축 기법)

  • Kang, Ho-Hyun;Shin, Dong-Hak;Kim, Eun-Soo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.34 no.3C
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    • pp.297-303
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    • 2009
  • Integral imaging is a well-known 3D image recording and display technique. The huge size of integral imaging data requires a compression scheme to store and transmit 3D scenes. In the conventional compression scheme, the data amount of elemental images depends on the various recording condition such as the positional location of a 3D object, the illumination and specification of the lenslet array even if an identical pickup system is used. In this paper, to reduce the dependence of the image characteristics of elemental images on the pickup conditions, a compression scheme using block division on the elemental image of integral imaging is proposed. The proposed scheme provides an improved compression ratio by considering the local similarity of elemental images picked up from three-dimensional objects according to a positional location. To test the proposed scheme, various elemental images are picked up and a compression process is then carried out u sing a standard MPEG-4. Based on compression ratio results, the proposed compression scheme is improved by approximately 9% compared with the conventional compression method.

Depth Extraction of Integral Imaging Using Correlation (상관관계를 활용한 집적 영상의 깊이 추출 방법)

  • Kim, Youngjun;Cho, Ki-Ok;Kim, Cheolsu;Cho, Myungjin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.7
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    • pp.1369-1375
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    • 2016
  • In this paper, we present a depth extraction method of integral imaging using correlation between elemental images with phase only filter. Integral imaging is a passive three-dimensional (3D) imaging system records ray information of 3D objects through lenslet array by 2D image sensor, and displays 3D images by using the similar lenslet array. 2D images by lenslet array have different perspectives. These images are referred to as elemental images. Since the correlation can be calculated between elemental images, the depth information of 3D objects can be extracted. To obtain high correaltion between elemental images effectively, in this paper, we use phase only filter. Using this high correlation, the corresponding pixels between elemental images can be found so that depth information can be extracted by computational reconstruction technique. In this paper, to prove our method, we carry out optical experiment and calculate Peak Sidelobe Ratio (PSR) as a correlation metric.

초호열성 고세균 Thermococcus sp. DT1331의 유황 화합물 이화 특성

  • 곽이성;김영배
    • Microbiology and Biotechnology Letters
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    • v.25 no.4
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    • pp.354-358
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    • 1997
  • Some sulfur coompounds dissimilation characteristcs of Thermococcus sp. DT1331 were studied. DT1331 had ether-like lipid compounds in addition to esters in the cell membrane. The specific growth rates of DT1331 decreased with increasing head spaces of the cultures. However, when the ratio of head space volume to medium volume was 5.60, the strain showed no growth. DT1331 showed vigo- rous growth with 1% or more elemental sulfur addition. Cystine could substitute elemental sulfur and DT1331 showed moderate growth with 0.1% or more cystine concentration. The specific growth rate and maximum cell concentration of Thermococcus sp. DT1331 in the presence of elemental sulfur were 0.80 hr$^{-1}$ and 2.0 x 10$^{8}$ cells/ml, respectively, while they were 0.67 hr$^{-1}$ and 1.1 x 10$^{8}$ cells/ml, respectively in the presence of cystine.

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Evaluation of elemental concentrations of uranium, thorium and potassium in top soils from Kuwait

  • Bajoga, A.D.;Al-Dabbous, A.N.;Abdullahi, A.S.;Alazemi, N.A.;Bachama, Y.D.;Alaswad, S.O.
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1638-1649
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    • 2019
  • Top soil samples across the state of Kuwait numering ninety were collected and analysed using gamma-ray spectrometry, to evaluate the elemental concentration of $^{238}U$, $^{232}Th$ and $^{40}K$ and their depletion/enrichment. Results of elemental concentration ranges from 0.48 to 2.61 mg/kg, 0.87-5.23 mg/kg, and 0.24-2.23%, with a mean values of 1.39 mg/kg, 3.47 mg/kg, and 1.18%, for the $^{238}U$, $^{232}Th$ and $^{40}K$, respectively. Further analysis was conducted amongst the five identified soil types, i.e. Aquisalids (S1), Calcigypsids (S2), Petrocalcids (S3), Petrogypsids (S4), and torripsamment (S5). The highest radioactivity concentrations from both uranium and thorium were recorded in the S2 (Calcigypsids) soil, with a value of 1.71 (mg/kg) and 4.45 (mg/kg), respectively. Minimum and maximum values of $^{40}K$ are 1.1(%) and 1.27(%) and is prevalent in Aquisalids (S1) and Petrocalcids (S3) soil types, respectively. Ratios of elemental concentration for $^{232}Th/^{238}U$, $^{40}K/^{238}U$, $^{40}K/^{232}Th$ across the soil types are 2.53, 0.09 and 0.03, with a correlation coefficient of 0.92, 0.34, and 0.38, respectively. A progressively higher $^{232}Th/^{238}U$ ratio is observed moving south-wards, indicating lower $^{238}U$ content in soils from the south relative to the northern part. Overall results indicate Kuwait to be relatively an area with low level of natural radioactivity.

Synthesis of Isopropyldichlorosilane by Direct Process

  • Lim, Weon-Cheol;Cho, Joo-Hyun;Han, Joon-Soo;Yoo, Bok-Ryul
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1661-1664
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    • 2007
  • Direct reaction of elemental silicon with a gaseous mixture of isopropyl chloride (1) and hydrogen chloride in the presence of copper catalyst using a stirred bed reactor equipped with a spiral band agitator gave isopropyldichlorosilane having a Si-H bond (2a) as a major product and isopropyltrichlorosilane (2b) along with chlorosilanes, trichlorosilane and tetrachlorosilane. A process for production of 2a was maximized using the 1:0.5 mole ratio of 1 to HCl and smaller size of elemental silicon at a reaction temperature of 220 °C. When a reaction was carried out by feeding a gaseous mixture of 1 [12.9 g/h (0.164 mol/h)] and HCl [2.98 g/h (0.082 mol/h)] to a contact mixture of elemental silicon (360 g) and copper (40 g) under the optimum condition for 45 h, 2a among volatile products kept up about 82 mol % until 35 h and then slowly decreased down 68 mol % in 45 h reaction. Finally 2a was obtained in 38% isolated yield (based on 1 used) with an 85% consumption of elemental silicon in a 45 h reaction. In addition to 2a, 2b was obtained as minor product along with chlorosilanes, trichlorosilane, and tetrachlorosilane. The decomposition of 1 was suppressed and the production of 2a improved by adding HCl to 1.

A Study on Thermal Characteristic Carbon and other Elements in Suspended Particulates (대기 입자상물질중 탄소(C)등의 열적특성에 관한 조사연구)

  • 황경철
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.31-39
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    • 1990
  • An analytical method for particulate carbon and other elements by using elemental analyzer was investigated. Carbon, hydrogen, and nitrogen was determined as CO$_{2}$, H$_{2}$, and N$_{2}$, respectively. Organic was determined after scparation from elemental carbon(Cae) by volatilization and thermal decomposition in a heated helium flow. With organic materials examined in this reprot, more than 90% of carbon was detected as above 600$^{\circ}$C. But it is considered that a few percents of some compounds were charred above 550$^{\circ}$C. A small amount of Cae was oxidized in the inert atmosphere above 850$^{\circ}$C, but the reason was not explained clearly. Based on the thermal chracteristics of Cao it was found that the optimum temperature of heating in the helium flow of an elemental analyzer for Cao analysis is 630$^{\circ}$C. Carbon in a sample after removing Cao was assumed as Cae and the gramatom ratio of hydrogen to carbon in the sample was 0.4 and less. Rescovery of nitrogen derived from some ammonium salts and nitrates was 100% by two-step measurement with elemental analyzer. By the analytical method investigated in this report, carbon and other elements in suspended particulates(S.P) collected at an urban area in Seoul were measured. There was a good correlation between total nitrogen in SP measured by elemental analyzer and nitrogen estimated form ammonium ions and nitrate ions in SP. The nitrogen from these ions accounts for 80% of the total nitrogen. It is further suggested that the residue(20%) of the total nitrogen is attributed to the other nitrogeneous compounds.

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Elemental Analysis of Road Aerosols using by a PIXE Method (PIXE 분석법에 의한 도로변 분진의 원소분석)

  • 최금찬;임경택;조정구;김태형
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.5
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    • pp.523-528
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    • 1996
  • Aerosol Particles were collected in a heaby traffic region in pusan. Samples were collected in two size fractions with a two-stage sampler during the day and the night. Elemental concentrations of these aerosol particles were determined by a PIXE(Proton Induced X-ray Emission) analysis method. The results suggest that the elements originating mainly from natural sources such as Si, Ca, Fe, Cl, and K are dominent in the coarse fraction, but the elements such as S, Pb, Br, and Zn are dominent in the fine fraction. Br/Pb ratio are evaluated in both coarse and fine size fraction, and which are mainly emitted automobile sources. The study further also discussed other Br/Pb ratio related works described elsewhere. Sulfur in the fine fraction was continuously increased during the sampling period without time variation.

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Ratio of Elemental Carbon Concentrations for Respective Measurement Locations according to the Sampler (샘플러에 따른 측정 위치별 원소탄소의 농도 비율)

  • Cha, Won-Seok;Kim, Eun-Young;Choi, Sung-Won;Choi, Soo-Yeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.31 no.4
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    • pp.461-472
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    • 2021
  • Objectives: This study was conducted to determine the differences in EC concentrations according to the type of sampler by measuring and analyzing EC. Methods: Elemental carbon was measured in diesel engine vehicles and at the roadside. Using NIOSH method 5040, a cassette was coupled to 37 mm and 27 mm quartz filters and measurements were performed 21 times. There were 14 types of measurement methods, and polystyrene, polypropylene, and metal samplers were evenly placed inside the movable chamber. Results: The results measured using the 37 mm conductive cassette (closed/open) and the IOM sampler made of conductive materials showed a higher ratio than the other results. When the 37 mm conductive cassette was measured with the lid open, it showed a statistically significantly higher ratio than with other measurement methods (p<0.05). Conclusions: Checking the EC concentration a total of 21 times at each ratio based on the concentration of the 3-stage polystyrene cassette, it was statistically significantly higher when the 37 mm conductive cassette was open. This same cassette also showed a slightly higher EC concentration when closed. It was ascertained that some DEE was collected on the cassette wall surface due to the electrical conductivity of the polystyrene cassette, resulting in sample loss. Since EC is composed of fine particles, it is thought that electrical conductivity may affect its concentration.

Seasonal characteristics of Elemental and Orgainc Carbon (미세입자 ($PM_{2.5}$) 에 포함된 탄소농도계절 특성)

  • 강병욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.2
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    • pp.103-112
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    • 2000
  • Elemental carbon(EC) and organic carbon(OC) in fine particles (PM2.5) were collected from October 1995 through August 1996 in the Chongju area. The annual mean concentrations of EC and OC were 4.44 and 4.99 $\mu\textrm{g}$/m3 respectively. EC showed seasonal variation (p<0.01) The magnitude of the seasonal mean EC concen-tration progresses in the following manner : fall>winter>spring>summer. However OC was not statistically seasonal difference(p=0.20) The annual average OC/EC ratio was 1.12 suggesting that organic carbon measured may by emitted directly in particulate form(primary aerosol) The contribution of EC to PM2.5 mass follows a general pattern in which fall(14.6%) > winter (9.8%) >spring(7.8%) =summer(7.8%) and the contribution of OC to the PM2.5 mass varies in order fall(13.8%) >winter(11.3%) >spring(10.5%) >summer (9.4%) Total carbona-ceous particles(EC and OC) accounted for 17-28% of the PM2.5 mass.

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