• Title/Summary/Keyword: Elemental Distribution

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Developing Stochastic Long-Term Maintenance Cost Estimating Method for Apartment Housing (추계적 공동주택 장기수선충당금 산출 및 분석 방법론 개발)

  • Gwak, Han-Seong;Lee, Dong-Eun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.243-244
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    • 2015
  • This paper presents a Stochastic Long-Term Maintenance Costs Estimating Method for the Apartment Housing (SLCE). A simulation approach is used for generating the stochastic long-term maintenance cost, and it is based on the defined variability in repair cycle of the individual maintenance elemental within the process. SLCE provides the probability distribution of the budget required to maintain the apartment housing. A case study is presented to demonstrate and to validate the system.

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Electric Field distribution Analysis according to radius of curvature in needle electronode (침전극 곡률반경에 따른 XLPE의 전계분포 해석)

  • An, Byung-Chul;Lee, Hyeok-Jin;Kim, Tak-Yong;Byeon, Du-Gyun;Lee, Jong-Yong;Shin, Jong-Yeol;Lee, Su-Won;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.234-235
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    • 2005
  • 본 논문에서는 전력용 케이블에서 초고압으로 사용되고 있는 가교폴리에틸렌 내부(XLPE)에 침투된 침전극의 곡률반경변화에 따른 XLPE의 전계분포를 경계요소법에 의한 3차원 시뮬레이션 프로그램을 통하여 해석하여, 곡률반경이 작을수록 전계가 집중되는 현상을 확인하였다.

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Characterization of Humic Acids from Kuye San Soil

  • Hichung Moon;Me Hae Lee;Tae Hyun Yoon
    • Bulletin of the Korean Chemical Society
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    • v.12 no.2
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    • pp.153-156
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    • 1991
  • Three humic acids, two from uranium bearing coal shale and one from the neighbouring limey shale region, are extracted from soils by dissolution in 0.1 M NaOH followed by acid precipitation. After purification cycles, they are characterized for their elemental composition, contents of inorganic impurities, molecular size distribution and proton exchange capacities. The results are compared with the data of reference and aquatic humic acids characterized under the project MIRAGE Ⅱ at TUM and also with other literature data. The proton exchange capacity determined by direct titration, is found to be 3.60 and 2.01 meq/g for coal shale and limey shale humic acids, respectively.

Distribution of Nutrients in Dae-Cheong Reservoir Sediment

  • Hwang Jong Yeon;Han Eui Jung;Kim Tae Kehn;Kim Shin Jo;Yu Soon Ju;Yoon Young Sam;Jung Yong Soon;Park Pan Wook
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.169-179
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    • 1998
  • This paper was performed to estimate interrelations between humus level of sediments and nutrient release from sediments in Dae-cheong reservoir. For investigations, sediments were sampled in June and October, in 1997 at fish farms, embayment, and the main stream of Dae-cheong reservoir. Items for investigation are as follows; water content, weight loss on ignition(IG), porosities of sediments, contents of element such as hydrogen, nitrogen, carbon, and nutrient release rates. Water contents and porosities were measured to conjecture the physical trait and grain size trait. Weight loss on ignition was measured to determine the contents of organic substance. For determination of the humus level of sediments, carbon and nitrogen contents were measured by elemental analyzer. As a result of elemental analysis, C/N ratio was determined in the range of $3.0\~13.1$. From the elemental analysis, humus level of Dae-cheong reservoir sediment was estimated from mesohumic state to oligotrophic state. For the determination of nutrient release rate, $PO_4-P$ and $NH_4-N$ concentrations of interstitial water and overlying water were measured. By using the concentration difference between interstitial water and overlying water and using the Fick's diffusion law, the release rates of phosphorus and nitrogen from the sediment samples were calculated. Release rates of nutrients which directly influence to the water quality were $0.05\~8.63mgP/m^2day$ and $4.99\~36.56mgP/m^2day$. It was found that release rate was measured higher in the 1st sampling period than in the 2nd sampling period. For the determination of phosphorus content in sediment, TPs were measured in 807\~1542{\mu}g/g$ in the 1st samling period and $677\~5238{\mu}g/g$ in the End samling period. Phosphorus release rate and phosphorus content were not interrelated each other.

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Development of Calorific Values and Carbon Emission Factors for Petroleum Energy in Korea from 2012 to 2013 (2012~2013년 국내 석유계 에너지원의 열량 및 탄소배출계수 개발)

  • Lim, Wan-Gyu;Doe, Jin-Woo;Kang, Hyung-Kyu;Ha, Jong-Han;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.301-310
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    • 2014
  • Country-specific data for net calorific values and carbon emission factors requires for a higher tier estimate of greenhouse gas emissions in the energy sector. The objective of this study is to develop country-specific net calorific values and carbon emission factors for petroleum energy produced in Korea. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and carbon emission factors were determined based on the measurement results. The net calorific values and carbon emission factors determined for the petroleum produced in Korea 2012 and 2013 were compared to those in the 2006 IPCC Guidelines. Most of the values were different compared with the default values of the 2006 IPCC Guidelines although those were placed within their upper and lower limits. Time series analysis results showed inconsistent seasonal variation for the net calorific values and carbon emission factors.

CO2 Emission Characteristics of Bunker C Fuel Oil by Sulfur Contents (C 중유의 황 함유량에 따른 CO2 배출 특성)

  • Lim, Wan-Gyu;Doe, Jin-Woo;Hwang, In-Ha;Ha, Jong-Han;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.368-377
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    • 2015
  • Bunker C fuel oil is a high-viscosity oil obtained from petroleum distillation as a residue. The sulfur content of bunker C fuel oil is limited to 4.0% or even lower to protect the environment. Because bunker C fuel oil is burned in a furnace or boiler for the generation of heat or used in an engine for the generation of power, carbon dioxide is emitted as a result of combustion. The objective of this study is to investigate $CO_2$ emission characteristics of bunker C fuel oil by sulfur contents. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and $CO_2$ emission factors were determined. The results showed that hydrogen content increases and carbon content decreases by reducing sulfur contents for bunker C fuel oil with sulfur contents less than 1.0%. For sulfur contents between 1.0% and 4.0%, carbon content increases as sulfur content decreases but there is no evident variation in hydrogen content. Net calorific value increases by reducing sulfur contents. $CO_2$ emission factor, which is calculated by dividing carbon content by net calorific value, decreases as sulfur content decreases for bunker C fuel oil with sulfur contents less than 1.0% but it showed relatively constant values for sulfur contents between 1.0% and 4.0%.

Characterization of Size Distribution and Water Solubility of 15 Elements in Atmospheric Aerosols

  • Park, Jeong-Ho;Sun, Jeong-Min;Park, Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E1
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    • pp.1-7
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    • 2001
  • The elemental characteristics of atmospheric aerosols were investigated as a function of particle size and water solubility. The aerosol particles were samples at 12 individual size ranges between 0.01 and 30㎛. Collected aerosol particles were separated into both soluble and insoluble components. The concentrations of 15 elements in both components were determined by a PIXE analysis using a 2.0 MeV-proton beam. In general, the mass size distribution of particulate matter was represented as a bimodal distribution. The maximum rations of S in July and December were 5.5 and 3.8 %, and they appeared in the size range of 0.47∼1.17㎛(stage No. 6 or 7) . The ratios of a S at non-separated size were 3.1 and 2.2 % in July and December, respectively, On the other hand, the maximum rations of Si in July and December were 7.0 and 5.4% and they appeared in the size range of 5.1∼30㎛(stage No. 0∼2). The ratios of Si at the non-separated size were 2.1 and 1.8% in July and December, respectively, The mass diameter of 12 elements ranged between 0.59㎛ of S and 3.20 of Fe. More than 90% of atmospheric aerosols consisted of the light elements such as C, N, O, H and Al. The soluble component was dominant in the smaller size range and the insoluble component in the larger size range. Large portions of Si. Ti and Fe existed in insoluble state. By contrast, S, Cl, Ca, Zn and Br were dissolved in water.

Thermochemical Sulfate Reduction Simulation Experiments on the Formation and Distribution of Organic Sulfur Compounds in the Tuha Crude Oil

  • Yue, Changtao;Li, Shuyuan;Song, He
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2057-2064
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    • 2014
  • Thermochemical sulfate reduction (TSR) was conducted in autoclave on the system of crude oil and $MgSO_4$ at different temperatures. Gas chromatography pulsed flame photometric detector (GC-PFPD) was used to detected the composition of organic sulfur compounds in oil phase products. The results of the analysis indicate that with increased temperature, the contents of organic sulfur compounds with high molecular weight and thermal stability, such as benzothiophenes and dibenzothiophenes, gradually became dominated. In order to gain greater insight into the formation and distribution of organic sulphur compounds from TSR, positive ion electrospray Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used in detecting the detailed elemental composition and distribution of them. The mass spectra showed that the mass range of sulfur compounds was 200-550 Da. Four sulfur class species, $S_1$, $N_1S_1$, $O_1S_1$ and $O_2S_1$, were assigned in the positive-ion spectrum. Among the identified sulfur compounds, the $S_1$ class species was dominant. The most abundant $S_1$ class species increase associated with the DBE value and carbon number increasing which also indicates the evolution of organic sulfur compounds in TSR is from the labile series to the stable one. In pure blank pyrolysis experiments with crude oil cracking without TSR, different composition and distribution of organic sulfur compounds in oil phase products were seen from mass spectra in order to evaluate their pyrolysis behaviors without $MgSO_4$. FT-IR and XRD were used in analyzing the products of solid phases. Two distinct crystallographic phases MgO and $MgSO_4$ are found to coexist in the products which demonstrated the transformation of inorganic sulfur compounds into organosulfur compounds exist in TSR.

A Study on the Application of Cost Risk Exposure methods by the Probabilistic Evaluation on the Construction Projects (확률적 평가에 의한 건설공사 비용 위험도 측정의 적용성에 관한 연구)

  • Cho Jea-Ho;Chun Jae-Youl
    • Korean Journal of Construction Engineering and Management
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    • v.1 no.1 s.1
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    • pp.63-71
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    • 2000
  • The paper considers two non-deterministic methods of analysing the risk exposure in a cost estimate The fist method(referred to as the 'conventional statistical' method) analyses cost data directly, to describe a probability distribution for total cost. The second method(referred to as the 'Monte Carlo simulation' method) interprets cost data directly, to generate a probability distribution for total costs from the descriptions of elemental cost distribution. The common practice of allowing for risk through an all-embracing contingency sum or percentage addition is challenged. Rather than excluding conventional, non-deterministic methods, they are here presented as possibly the only of effective foundation on which to risk management in cost estimating.

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Investigation on Microstructure and Flowability of Gas Atomized Heat-resistant KHR45A Alloy Powders for Additive Manufacturing

  • Geonwoo Baek;Mohsen Saboktakin Rizi;Yeeun Lee;SungJae Jo;Joo-Hyun Choi;Soon-Jik Hong
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.13-21
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    • 2023
  • In additive manufacturing, the flowability of feedstock particles determines the quality of the parts that are affected by different parameters, including the chemistry and morphology of the powders and particle size distribution. In this study, the microstructures and flowabilities of gas-atomized heat-resistant alloys for additive manufacturing applications are investigated. A KHR45A alloy powder with a composition of Fe-30Cr-40Mn-1.8Nb (wt.%) is fabricated using gas atomization process. The microstructure and effect of powder chemistry and morphology on the flow behavior are investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and revolution powder analysis. The results reveal the formation of spherical particles composed of single-phase FCC dendritic structures after gas atomization. SEM observations show variations in the microstructures of the powder particles with different size distributions. Elemental distribution maps, line scans, and high-resolution XPS results indicate the presence of a Si-rich oxide accompanied by Fe, Cr, and Nb metal oxides in the outer layer of the powders. The flowability behavior is found to be induced by the particle size distribution, which can be attributed to the interparticle interactions and friction of particles with different sizes.