• Title/Summary/Keyword: Element technique

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Organic Precipitate Flotation of Trace Metallic Elements with Ammonium Pyrrolidinedithiocarbamate(Ⅰ). Determination of Bismuth, Cadmium, Cobalt and Lead in Water Samples by Coprecipitation-Flotation with Cu-pyrrolidinedithiocarbamate (Ammonium Pyrrolidinedithiocarbamate에 의한 극미량 금속원소의 유기침전 부선에 관한 연구(제1보) Cu-pyrrolidinedithiocarbamate 공침부선에 의한 물시료중 비스무트, 카드뮴, 코발트 및 납의 정량)

  • Jung, Yong June;Choi, Jong Moon;Choi, Hee Seon;Kim, Young Sang
    • Journal of the Korean Chemical Society
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    • v.40 no.12
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    • pp.724-732
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    • 1996
  • The organic precipitate flotation using Cu(II)-pyrrolidinedithiocarbamate complex as a coprecipitant was studied for the preconcentration and determination of trace Cd, Pb, Bi and Co in several water samples. Experimental conditions such as pH of solution, amounts of Cu(II) and ammonium pyrrolidinedithiocarbamate(APDC), stirring time, the type and amount of surfactant, etc. were optimized for the effective flotation of analytes. After 3.0 mL of 1,000 ${\mu}g/mL$ Cu(II) solution was added to 1.00 L water sample, the pH of the solution was adjusted to 2.5 with HNO3 solution. Trace amounts of analytes were coprecipitated by adding 2.0% APDC solution. And the precipitates were flotated onto the surface of solution with the aid of nitrogen gas and sodium lauryl sulfate. The floats were collected from mother liquor, and filtered through the micropore glass filter by suction. The precipitates were dissolved with 4 mL conc. HNO3, and then diluted to 25.00 mL with deionized water. The analytes were determined by graphite furnace atomic absorption spectrophotometry. This flotation technique was applied to the analysis of some water samples, and the 90 to 120% of recoveries were obtained from the spiked samples, this procedure could be concluded to be simple and applicable for the trace element analysis in various kinds of water.

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Reliability Prediction of Failure Modes due to Pressure in Solid Rocket Case (고체로켓 케이스 내압파열 고장모드의 신뢰도예측)

  • Kim, Dong-Seong;Yoo, Min-Young;Kim, Hee-Seong;Choi, Joo-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.6
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    • pp.635-642
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    • 2014
  • In this paper, an efficient technique is developed to predict failure probability of three failure modes(case rupture, fracture and bolt breakage) related to solid rocket motor case due to the inner pressure during the mission flight. The overall procedure consists of the steps: 1) design parameters affecting the case failure are identified and their uncertainties are modelled by probability distribution, 2) combustion analysis in the interior of the case is carried out to obtain maximum expected operating pressure(MEOP), 3) stress and other structural performances are evaluated by finite element analysis(FEA), and 4) failure probabilities are calculated for the above mentioned failure modes. Axi-symmetric assumption for FEA is employed for simplification while contact between bolted joint is accounted for. Efficient procedure is developed to evaluate failure probability which consists of finding first an Most Probable Failure Point(MPP) using First-Order Reliability Method(FORM), next making a response surface model around the MPP using Latin Hypercube Sampling(LHS), and finally calculating failure probability by employing Importance Sampling.

Study on the effect of tail void grouting on the short- and long-term surface settlement in the shield TBM Tunneling using numerical analysis (쉴드TBM터널에서 뒤채움 주입이 지반의 단기·장기 침하에 미치는 영향에 대한 수치해석적 연구)

  • Oh, Ju-Young;Park, Hyunku;Kim, Dohyoung;Chang, Seokbue;Lee, Seungbok;Choi, Hangseok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.265-281
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    • 2017
  • For shallow tunnel constructions, settlement of the ground surface is a main issue. Recent technical developments in shield TBM tunneling technique have enabled a decrease in such settlements based on tunneling with ground deformation controls. For this objective, the tail void grouting is a common practice. Generally surface settlements in a soil of low permeability occur during a tunnel construction but also during a long period after completion of the tunnel. The long-term settlements occur mainly due to consolidation around the tunnel. The consolidation process is caused and determined by the tail void grouting which leads to an excess pore water pressure in the vicinity of the tunnel. Because of this, the grouting pressure has a strong effect on the long-term settlements in the shield tunneling. In order to investigate this effect, a series of coupled hydro-mechanical 3D finite element simulations have been performed. The results show that an increase in grouting pressure reduces the short-term settlements, but in many cases, it doesn't lead to a reduction of the final settlements after the completion of consolidation. Thereby, the existence of a critical grouting pressure is identified, at which the minimal settlements are expected.

Simulation of Circulation and Water Qualities on a Partly Opened Estuarine Lake Through Sluice Gate (배수갑문을 통해 부분 개방된 하구호에서의 순환과 수질모의)

  • 서승원;김정훈;유시흥
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.2
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    • pp.136-150
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    • 2002
  • To improve the water quality of the recently constructed Siwhaho, sluice gates were operated to allow free exchange of water with the sea. This estuarine lake connected to the outer sea through narrow gates is affected mainly by flushing by gate operation and river flows and wind forcing sometimes. As a predicting tool far the water qualities, a three-dimensional finite volume model CE-QUAL-ICM is incorporated into a finite element hydrodynamic model, TIDE3D. In coupling these two different modules, a new error minimization technique is applied by considering conservation of mass. Model tests for one year after calibration and validation using field observation show that eutrophication and other biological changes reach quasi-steady state after initial 60 days of simulation, thus it would be necessary to consider moderate ramp up option to remove initial uncertainties due to cold start option. Sediment-water interaction might not be a concern in the long-term simulation, since its effect is negligible. Simulated results show the newly applied scheme can be applied with satisfaction not only fur lessening of eutrophic processes in an estuarine lake but also looking for some active circulation to improve water quality.

A Mechanical Information Model of Line Heating Process using Artificial Neural Network (인공신경망을 이용한 선상가열 공정의 역학정보모델)

  • Park, Sung-Gun;Kim, Won-Don;Shin, Jong-Gye
    • Journal of the Society of Naval Architects of Korea
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    • v.34 no.1
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    • pp.122-129
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    • 1997
  • Thermo-elastic-plastic analyses used in solving plate forming process are often computationally expensive. To obtain an optimal process of line heating typically requires numerous iterations between the simulation and a finite element analysis. This process often becomes prohibitive due to the amount of computer time required for numerical simulation of line heating process. Therefore, a new techniques that could significantly reduce the computer time required to solve a complex analysis problem would be beneficial. In this paper, we considered factors that influence the bending effect by line heating and developed inference engine by using the concept of artificial neural network. To verify the validity of the neural network, we used results obtained from numerical analysis. We trained the neural network with the data made from numerical analysis and experiments varying the structure of neural network, in other words varying the number of hidden layers and the number of neurons in each hidden layers. From that we concluded that if the number of neurons in each hidden layers is large enough neural network having two hidden layers can be trained easily and errors between exact value and results obtained from trained network are not so large. Consequently, if there are enough number of training pairs, artificial neural network can infer similar results. Based on the numerical results, we applied the artificial neural network technique to deal with mechanical behavior of line heating at simulation stage effectively.

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Combustion of Diesel Particulate Matters under Mixed Catalyst System of Fuel-Borne Catalyst and Perovskite: Influence of Composition of Perovskite (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn) on Combustion Activity (Fuel-Borne Catalyst와 Perovskite로 구성된 복합촉매 시스템에 의한 디젤 탄소입자상 물질의 연소반응: 반응성능과 Perovskite 촉매조성 (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn)의 상관관계)

  • Lee, Dae-Won;Sung, Ju Young;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.281-290
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    • 2018
  • As the internal combustion engine vehicles of high fuel efficiency and low emission are demanded, it becomes important to procure technologies for improving low-temperature performance of automotive catalyst systems. In this study, we showed that the combustion rate of diesel particulate matter is greatly enhanced at low temperature by applying fuel-borne catalyst and perovskite catalyst concurrently. It was tried to examine the correlation between elemental composition of perovskite catalyst and combustion activity of mixed catalyst system. To achieve this goal, we applied temperature-programmed oxidation technique in testing the combustion behavior of perovskite-mixed particulate matter bed which contained the element of fuel-borne catalyst or not. We tried to explain the synergetic action of two catalyst components by comparing the trends of concentrations of carbon dioxide and nitrogen oxide in temperature-programmed oxidation results.

Analysis of Influence Factors for Remediation of Contaminated Soils Using Prefabricated Vertical Drains (연직배수재를 이용한 오염지반 복원의 영향인자 분석)

  • Park, Jeongjun;Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.2
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    • pp.39-46
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    • 2008
  • Due to the growth in industrialization, potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. There are a number of approaches to in-situ remediation that are used in contaminated sites for removing contaminants. These include soil flushing, dual phase extraction, and soil vapor extraction. Among these techniques, soil flushing was the focus of the investigation in this paper. Incorporated technique with PVDs has been used for dewatering from fine-grained soils for the purpose of ground improvement by means of prefabricated vertical drain systems. The laboratory model tests were performed by using the flushing tracer solutions for silty soils and recorded the tracer concentration changes with the elapsed time and flow rates. The modeling was intended to predict the effectiveness and time dependence of the remediation process. Modeling has been performed on the extraction, considering tracer concentration and laboratory model test characteristics. The computer model used herein are SEEP/W and CTRAN/W, this 2-D finite element program allows for modeling to determine hydraulic head and pore water pressure distribution, efficiency of remediation for the subsurface environment. It is concluded that the coefficient of permeability of contaminated soil is related with vertical velocity and extracted flow rate. The vertical velocity and extracted flow rate have an effect on dispersivity and finally are played an important role in-situ soil remediation.

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A Development of Active Monitoring and Approach Alarm System for Marine Buoy Protection and Ship Accident Prevention based on Trail Cameras and AIS (해상 부이 보호 및 선박 사고 예방을 위한 트레일 카메라-AIS 연계형 능동감시 및 접근경보 시스템 개발)

  • Hwang, Hun-Gyu;Kim, Bae-Sung;Kim, Hyen-Woo;Gang, Yong-Soo;Kim, Dae-Han
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.22 no.7
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    • pp.1021-1029
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    • 2018
  • The marine buoys are operated in various domains, which are navigation route and danger maker, weather and environment monitoring, military strategical element, etc. If the marine buoy is damaged, there consumes many cost and time for recovery or replacement, because of severe environmental condition, and causes a risk possibility of secondary accident. In this paper, we developed an active monitoring and approach alarm providing system using trail cameras and AIS for protection for the marine buoys. To do this, we analyzed existing researches and similar systems, extracted requirements for enhancement, and designed the system architecture that applied the enhanced elements. The main considerations of system enhancement are: integration of AIS and trail cameras, adopting of phased alarm technique by approaching ships, applying of selective communication module, conducting the image processing of ships for providing alarm, and applying thermal cameras. After that, we developed the system using designed architecture and verified effectiveness of the system based on laboratory or field-level tests.

Lightweight Design of an Outer Tie Rod Using Meta-Model Based Optimization Technique (메타모델기반최적화를 이용한 아우터타이로드의 경량화 설계)

  • Kim, Young-Jun;Park, Soon-Hyeong;Lee, Kwon-Hee;Park, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7754-7760
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    • 2015
  • The outer tie rod is one of the part of steering system, the optimization process was executed to find the lightweight design. The inner tie rod was considered in the optimum design of an outer tie rod. it could be closer to the test condition than in the case of considering outer tie rod only. The aluminum forging material was considered as a weight reduction proposal. The target of optimization was the shape of the minimum weight to resist at the load of buckling. RSM and Kriging interpolation method were applied as a optimization method to consider the nonlinear shape optimization problem. Then, 16.3%, 16.6% of weight reduction was obtained from the result comparing with that of the initial model. The results of meta model optimization was compared with that of finite element method. The error values of buckling load estimation were 2.6%, 2.04%. and those of weight estimation were 0.17%, 0.13%. Therefore, it seemed that the result of Kriging model could be obtained closer to optimum value than that of RSM model.

A theoretic study about western traditional wallpaper hanging (서양의 전통도배에 관한 이론적 고찰)

  • Lim, Sun-Yang
    • Archives of design research
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    • v.19 no.2 s.64
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    • pp.207-216
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    • 2006
  • Even though the notion exists that wall paper has got a short durability for interior decoration in terms of paper's nature, it can be the most important element among the modern dosing wall papering because of the variation of the walls visual effect. Wall paper hasn't been preserved well according to the paper's character and official records haven't been done well. So, by studying a case in which a room is maintained well, seeing various commercial samples which were used for an advertisement and reading several booklets it is possible to study historical evidence. In regard to wall paper and Papering. data, the commercial historic nature of the traditional wall papering has been recognized again in order to study the root of the technical and commercial background. In theory, the historic background research of traditional wall paper in the past is said to have established its theoretical system and the development of modern wall papering in the middle of Britain in 18th century. Through the theoretical study of wall papering, the following things have been researched: handling don the method of the traditional wall papering and lining paper, stylization of pattern by using the method of continual linking, subdivision of commercial cost and specialization of wallpaper, handing down the past traditional adhesion method, the origin of string wallpaper, utility of traditional wallpaper and its various abilities, the change from the face to face linking to duplicated linking, the development of DIY products by women's wallpaper selections. Put against other materials, wallpaper remains the most popular and preferable product for managing a wall and provides a decorative, wall dosing technique. This study can estimate the source of wallpapering history in order to create a systemic approach towards the future's wallpaper industry. This is very important data in order to establish a theoretical system of traditional wallpapering according to its historical research about wallpapering skills and its commercial aspect.

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