• Title/Summary/Keyword: Electrostatic potential

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Process Evaluation for Current Ceramic Filters and Granular Bed Filters for High Temperature High Pressure Applications

  • Chung, Jin-Do
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.138-145
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    • 1996
  • The particulate collection at high temperature and high pressure (HTHP) is important on the advanced coal power generation system not only to improve the thermal efficiency of the system, but also to prevent the gas turbine from erosion and to meet the emission limits of the effluent gas. The specifications for particulate collection in those systems such as Integrated Coal Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) require the absolutely high collection efficiency and reliability. Advanced cyclone, granular bed filter, electrostatic precipitator, and ceramic filter have been developed for particulate collection on the advanced coal power generation system. However, rigid ceramic filters and granular bed filter among them show the best potential. The current technology of these collectors was evaluated in this paper. The experienced problems of these systems on performance, materials, and mechanical design were investigated. Ceramic candle filters has the best potential for IGCC at this moment because it has nearly the highest efficiency comparing with other filtering systems and has accumulated many reliable design data resulted from many field experiences.

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Novel route of enhancing the metal loading in highly active Pt/C electro-catalyst by polyol process (Polyol process를 통한 고비율 백금 담지 촉매 합성)

  • Oh, Hyung-Suk;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.560-563
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    • 2008
  • A modified polyol process is developed to enhance Pt loading during the preparation of Pt/C catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. However, this change does not affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behavior caused by the change in the solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All our experimental results reveal that this simple modification is a cost effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells.

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Nanoparticle patterning using nanoparticle focusing mask (나노입자 집속 마스크를 이용한 나노입자 패턴 형성)

  • You, Suk-Beom;Lee, Hee-Chul;Kim, Hyoung-Chul;Choi, Man-Soo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1713-1717
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    • 2008
  • We have developed a nanoparticle focusing mask which can generate particle arrays directly on the large area with high resolution. Using this mask, nanomaterials are precisely deposited onto desired positions on a substrate surface. We obtained various sizes of arrays ranging from 80 nm to 6 ${\mu}m$ with silver and copper nanoparticles that are generated by a spark discharge and an evaporation-condensation method. The feather size is much smaller than that of mask openings due to the focusing effects, like electrostatic lens, caused by charge or electric potential on insulator mask surface, which also prevent a mask clogging. The particle array size depends on the size of mask open patterns and focusing effects near the mask relate to ion flow rate and electric potential. We have demonstrated that diverse size of arrays with high resolution could be obtained repeatedly using the same sized mask in atmosphere.

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Numerical Analysis on Mixing in a Microchannel with Inhomogeneous Surface Charge (불균일 표면전하를 지닌 미소채널 내에서의 혼합에 관한 수치 해석적 연구)

  • Song, Kyung-Suk;Lee, Do-Hyung
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1004-1009
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    • 2003
  • Electroosmotic flow induced by an applied electrostatic potential field in microchannel is analyzed in this study. The electroosmotic flow is an alternative to pressure driven flow in microchannels, but the usage has been limited to the simple cases. In this study, We analyze electroosmotic flow driven by inhomogeneous surface charge on the channel wall. The surface charge varies along a direction perpendicular to the electric field in order to generate the electroosmotic flow. A numerical results substantiate the highly efficient mixing performance. It is highly the beneficial to fabrication process since only straight microchannel rather than complex geometry is enough to yield efficient mixing.

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A study on the effects of variously configured magnets on the characteristics of inductively coupled plasma (자장의 배열 및 형태가 유도결합형 플라즈마에 미치는 효과에 관한 연구)

  • 황순원;이영준;유지범;이재찬;염근영
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.513-520
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    • 1999
  • In this study, we investigated the effects of variously configured magnets on the characteristics of the plasmas to enhance plasma uniformity and density of an inductively coupled plasma source. As the magnets, Helmholtz type axial electromagnets and various multi-dipole magnets types around the chamber wall were used. To characterize the plasma as a function of the combination of the magnets and magnetic field strengths, ion density, electron temperature, and plasma potential were measured using an electrostatic probe along the chamber diameter for Ar plasmas. The measured maximum ion densities were $8$\times$10^{ 11}$$cm^{-3}$ with 600W inductive power and at 5mTorr of operational pressure and the uniformity of ion density was less than 5.9% at 2mTorr of operational pressure. The combination of an optimized multi-dipole magnet type and an axial electromagnet showed the lowest electron temperature (3eV) and plasma potential ($34V{p}$ )

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음이온형 수분산성 공중합 폴리에스테르의 합성 및 응용 연구(II)

  • 엄성일;고석원
    • Proceedings of the Korean Fiber Society Conference
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    • 1994.10a
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    • pp.137-138
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    • 1994
  • Anionic water dispersible copolyesters were synthesized and characterized. Viscosity of the copolyester is lower than that of routine acrylic water dispersible polymers. Adhesive force of the copolyester was much higher than that of water dispersible acrylic polymers. Particle size of the copolyesters in water decreased with the increase of DMS or DEG feed ratio. With the conclusive study of the data of particle size and potential, it was found that the dispersion stability of copolyesters in water increased with the increase of DMS or DEG feed ratio. Judging from the results of potential and particle size of copolyesters, there seems to be competition between two dispersion stability factors, i.e. electrostatic stabilization and steric stabilization and as a result, morphological change of particles occurrs. Tg decreased with the increase of DEG molar feed ratio or oil contents.

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Electrostatic Discharge Analysis of n-MOSFET (n-MOSFET 정전기 방전 분석)

  • 차영호;권태하;최혁환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.8
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    • pp.587-595
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    • 1998
  • Transient thermal analysis simulations are carried out using a modeling program to understand the human body model HBM ESD. The devices were simulated a one-dimensional device subjected to ESD stress by solving Poison's equation, the continuity equation, and heat flow equation. A ramp rise with peak ESD voltage during rise time is applied to the device under test and then discharged exponentially through the device. LDD and NMOS structures were studied to evaluate ESD performance, snap back voltages, device heating. Junction heating results in the necessity for increased electron concentration in the space charge region to carry the current by the ESD HBM circuit. The doping profile adihacent to junction determines the amount of charge density and magnitude of the electric field, potential drop, and device heating. Shallow slopes of LDD tend to collect the negative charge and higher potential drops and device heating.

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Analysis of the Surface Degradation in UV-irradiated High-Temperature Vulcanized Silicone Rubber (자외선 조사된 HTV 실리콘 고무의 표면열화 분석)

  • 연복희;이태호;허창수;이종한
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.411-419
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    • 2000
  • In this paper we have investigated the surface degradation by ultraviolet-irradiation in high-temperature vulcanized silicone rubber. Through the measurement of surface potential decay by corona-charging and of contact angle it is found that the change of surface electrostatic properties and the decrease of contact angle under UV-radiation. For the changes in micro-morphological and chemical structure of the UV-treated silicone rubber we utilized several analytical techniques such as SEM, ATR-FTIR,XPS. From this study it is shown that the chemical reactions(scissoring of side chain(S-$CH_3$) cross-linking and branching) occur on the surface of silicone rubber during the UV-irradiation. Also we obtained the results of the loss of low molecular weight chain by cross-linking and oxidation reaction.

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Mechanism of Escherichia Coli Removal by Hydroxyapatite

  • Su-Chak Ryu;Dong-Hun Lee;Jae-Hoon Jeong;Sung-Kwang Jo
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.261-266
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    • 2024
  • Although most strains of escherichia coli (E. coli) are harmless, some serotypes can cause serious food poisoning in humans. It is very difficult to eliminate E. coli from our lives. Here we show that E. coli can be eliminated by hydroxyapatite (HAp). Because HAp has a positive charge, the material and E. coli are attracted through electrostatic interactions. Additionally, because the surface of HAp is porous, it enters the pores of the HAp surface removing them from the environment. The amount of adsorption was observed to increase over time, and the zeta potential value of the material tended to be similar to that of E. coli. This phenomenon is thought to have zeta potential similar to that of E. coli as it is adsorbed onto the HAp surface over time. E. coli stained with crystal violet was spread on a glass slide and HAp porous sol powder was dropped to remove the E. coli. We expect that this analysis will open a new direction for antibacterial materials.

Investigation on Flocculi-floc Interaction and Flocculation in Extracellular Polymeric Substances, Ionic Species and Clay-containing Suspension (생체고분자물질 농도와 이온강도에 따른 점토입자 현탁액의 응집핵-응집체 이군집 응집 특성 연구)

  • Kim, Jae In;Lee, Byung Joon
    • Journal of Korean Society on Water Environment
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    • v.36 no.3
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    • pp.185-193
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    • 2020
  • Bimodal flocculation describes the aggregation and breakage processes of the flocculi (or primary particles) and the flocs in the water environment. Bimodal flocculation causes bimodal size distribution with the two separate peaks of the flocculi and the flocs. Extracellular polymeric substances and ionic species common in the water environment increase the occurrence of bimodal flocculation and flocculi-floc size distribution, under the flocculation mechanisms of electrostatic attraction and polymeric bridging. This study investigated bimodal flocculation and flocculi-floc size distribution, with respect to the extracellular polymeric substance concentration and ionic strength in the kaolinite-containing suspension. The batch flocculation tests comprising 0.12 g/L of kaolinite showed that the highest flocculation potential occurred at the lowest xanthan gum (as extracellular polymeric substances) concentration, under all the ionic strengths of 0.001, 0.01, and 0.1 M NaCl. Also, it was important to note that the higher ionic strength resulted in the higher flocculation potential, at all the xanthan gum concentrations. The bimodal flocculation and flocculi-floc size distribution became apparent in the experimental conditions, which had low and intermediate flocculation potential. Besides the polymeric bridging flocculation, steric stabilization increased the flocculi mass fraction against the floc mass fraction, thereby developing the bimodal size distribution.