• Membrane Journal
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• v.13 no.1
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• pp.29-36
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• 2003

A characterization of the permeation and separation using single salt solution was carried out with charged composite membranes. Various charged composite membranes were fabricated by blending an ionic polymer with a nonionic polymer in different ratios. In this study, sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic, cationic and nonionic polymers, respectively. The permeation and separation behaviors of the aqueous salt solutions have been investigated through the charged composite membranes with various charge densities. As the content of the ionic polymer increased in the membrane, the hydrophilicity of the membrane increased, and pure water flux and the solution flux increased correspondingly, indicating that the permeation performance through the membrane is determined mainly by its hydrophilicity. Electrostatic interaction between the charged membrane and ionic solute molecules, that is, Donnan exclusion, was observed to be attributed to salt rejection to a greater extent, and molecular sieve mechanism was effective for the separation of salts under a similar electrostatic circumstance of solutes.

• Membrane Journal
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• v.11 no.1
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• pp.22-28
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• 2001

Various charged homogeneous membranes were fabricated by blending of ionic polymer with a non-ionic polymer with different ratios. In this study. sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic. cationic and non-ionic polymers, respectively. The permcation and separation behaviors of aquCOll::; salt solutions have been investigated through the charged membranes. As the content of ionic polymer increases in the membrane, the hydrophilicity of the membrane increases and pure water flux as well as solution flux increases correspondingly, indicating that the permeation performance through the membrane is cletemunecl mainly by its hydrophilicity-, Electrostatic interaction between the charged membrane and ionic solute molecules, that is. Donnan exclusion was observed to be attributed to salt rejection to a great deal of extent, and molecular sieve mechanism was effective [or the separation of the salt solution under a similar electrostatic circumstance of solutes.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.193-197
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• 2001

This study was carried out to recover gold, silver and other valuable metals from the printed circuit boards (PCB) of waste computers. PCB samples were crushed to under 1mm by a shredder and initially separated into 30% conducting and 70% non-conducting materials by an electrostatic separator. The conducting materials, which contained the valuable metals, were then used as the feed material for magnetic separation where it was found that 42% was magnetic and 58% non- magnetic. The non-magnetic materials contained 0.227mg/g Au and 0.697mg/g Ag. Further leaching of the non-magnetic component using 2.0M sulfuric acid and 0.2M hydrogen peroxide at 85$^{\circ}C$ extracted more than 95% copper, iron, zinc, nickel and aluminium. Au and Ag were not extracted in this solution, however, more than 95% of Au and 100% of Ag were selectively leached with a mixed solvent (0.2M ammonium thiosulfate, 0.02M copper sulfate, 0.4M ammonium hydroxide). Finally, the residues were reacted with a NaCl solution to leach out Pb while sulfuric acid was used to leach out Sn. Recoveries reached 95% and 98% in solution, respectively.

• Resources Recycling
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• v.23 no.6
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• pp.30-39
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• 2014

The trajectories of PCB(Printed Circuit Board) particles in the corona discharge electrostatic separation was simulated. The PCB particles are prepared by crushing bare board, which disassembled from electronic components, consist mostly of copper and FR-4(Flame Retardant Level-4) Firstly, a model was established for calculating of detachment points of PCB particles from the rotating electrode in separator. The model of detachment points was derived from equilibrium of force such as gravity force, centrifugal force, electrostatic force. The trajectories of particles after detachment was calculated by acceleration derived from time-integrating method of motion equation. In this simulation, particle size, supplied voltage, rotation speed of rotating roll electrode and angle of induction electrode were adopted as variables. While the trajectories of FR-4 particles were affected by all variables, rotation speed of rotating roll electrode was dominant variables affecting trajectories of copper particles.

• Resources Recycling
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• v.14 no.5 s.67
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• pp.54-61
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• 2005

In 2006, the coal usage that is used as energy source of power plant will meet 16,000 MW which is 30% of the whole energy usage. A Coal deposits among the fossil fuels is very plentiful in natural resources and has high economical efficiency but application technique is very inconvenient. Also when burned for utilization, it generate various toxic and untoxic air pollution materials; fly ash, bottom ash, sulfurous acid gas etc. In this study, we could establish a preparation of clean coal by triboelectrostatic separation. In this study, we made a bench-scale's triboelectrostatic separation equipment using electrostatic technology, and got an optimum conditions of various factors for increasing recovery rate and purification in separation. A test result, we got a clean coal that recovery rate is 68.10%, rejection rate of ash and sulfur content is 31.23% and 28.33%.

• Resources Recycling
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• v.18 no.2
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• pp.30-38
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• 2009

In this research, we studied the scale-up triboelectrostatic process for separation of PVC from higher gravity fraction of plastic wastes produced from wet gravity separation process. High density polyethylene (HDPE) was found to be the most effective materials for a tribo-charger in the separation of plastic tailings. In a commercial scale triboelelctrostatic separator unit, using the HDPE pipe-line charger, a grade of 99.1% with PET, PS and others and a recovery of 86% was obtained under optimum conditions at over 250 kV/m electric field, a splitter position of -8 cm from the center, and less than 40% relative humidity. The developed unit can process the plastic wastes at a 300 kg/h, and the product can be utilized as RPF or RDF of over grade 2.

• Resources Recycling
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• v.16 no.4
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• pp.47-60
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• 2007

Plastic supply and recycling are increasingly becoming matters of social concern. In our country, Extended Producer Responsibility(EPR) system has been adopted in 2003 to expand recycle and reuse of waste resources at producer side, and due to expansion of the EPR system, amount of the mixed plastic waste generation has been drastically increased. Plastic-plastic separation is most fundamental technique to achieve effective plastic recycling. This paper reviews recent developments in plastic-plastic separation techniques and describe future tasks. The mechanisms of each separation which contain gravity separation, electrostatic separation, flotation, and separation of automotive shredder residue are described, and commercial scale and lab-scale results are introduced.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.97-105
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• 1998

The goal of this study is to investigate the potential application of triboelectrostatic separation process for removing unburned carbon from fly ash. The process utilizes the difference in electrical charging characteristics between the organic material (carbon) and the mineral matter (fly ash). In the present work, dry separation tests have been conducted on Samchunpo fly ash samples using a bench - scale analytic separator. The test variables studied include air rate, feed rate, electric field strength, particle size, charger material and length, etc. The best separation results were obtained at the air rate 501/min, feed rate 15 g/min and voltage 15 ㎸. The fly ash with carbon content below 1 % was obtained with over 65% recovery.

• Journal of Mechanical Science and Technology
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• v.16 no.10
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• pp.1336-1345
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• 2002

A triboelectrostatic separation system using a fluidized bed tribocharger for the removal of PVC material in the mixture of PVC/PS plastics is designed and evaluated as a function of electric field strength, air flow rate, and the mixing ratio of two-component mixed plastics. It consists of a fluidized-bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PS particles can be imparted negative and positive surface charges, respectively, due to the difference in the work function values of plastics suspended in the fluidized-bed tribocharger, and can be separated by passing them through an external electric field. Experimental results show that separation efficiency is strongly dependent on the electric Deld strength and particle mixing ratio. In the optimum conditions of 150 Ipm air flow rate and 2.6 kV/cm electric field strength a highly concentrated PVC (99.1%) can be recovered with a yield of more than 99.2% from the mixture of PVC and PS materials for a single stage of processing.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.155-160
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• 2004

Permeation experiments of a commercial nanofiltration membrane (nominated as ESNA 1) were carried out with aqueous solutions of various single salts, that is, five chlorides (NH$_4$Cl, NaCl, KCl, MgCl$_2$ and $CaCl_2$), three nitrates $(NaNo_3,\;Mg(No_3)_2\;and\;Ca(NO_3)_2)\;and\;three\;sulfates\;((NH_4)_2SO_4,\;Na_2SO_4\;and\;MgSO_4)$. The experimental results showed that (1) the permeate volume flux of the ESNA 1 membrane increased and decreased with the growth of the applied pressure and the feed concentration of salts, respectively. The real rejection of ESNA 1 membrane to most single salts increased with the growth of the permeate volume flux. (2) The reflection coefficients of ESNA 1 membrane to chlorides, nitrates and sulfates are 0.97, 0.96 and 0.99, respectively. The solute permeability of most salts except for magnesium and calcium salts increased with the growth of feed concentration. (3) The sequence of the rejections of ESNA 1 membrane to anions is $R({SO_4}^{2-})>R(CI)>R(NO_3)$ at the same feed concentration. While the sequence of the rejections to cations is cataloged into two cases: $R(Na^+)>R(K^+)>R(Mg^{2+})>R(Ca^{2+})$ at the concentration of 10 mol/$m^3$ and $R(Mg^{2+})>R(Ca^{2+})>R(Na^+)>R(K^+)$ at the concentration of 100 mol/$m^3$. The separation capability of a NF membrane is usually affected by the electrostatic effect and the steric-hindrance effect. In this case, the electrostatic effect is the major factor at low concentration and the steric-hindrance effect is the major factor at high concentration. Both the specific sorption and the hydration also reasonably influenced the separation performance of NF membrane to salts.