• Korea-Australia Rheology Journal
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• v.19 no.4
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• pp.221-225
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• 2007

Electrorheological characteristics of a dispersed system of phosphorylated potato starch particles in silicone oil investigated via a rotational rheometer equipped with a high voltage generator is being reanalysized. Flow curves of these ER fluids both under several applied electric field strengths and with different degrees of phosphate substitution were mainly examined via three different rheological constitutive equations of Bingham model, De Kee-Turcotte model and our previously proposed CCJ model. Among these, the CCJ equation was found to fit the data of phosphorylated potato starch well.

• Tribology and Lubricants
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• v.15 no.3
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• pp.240-247
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• 1999

The electrorheological (ER) behavior of suspensions in silicone oil of phosphoric ester cellulose particles (average particle size : 18$\pm$1${\mu}{\textrm}{m}$) coated with octadecylamine ( $C_{18}$ $H_{37}$ N $H_2$) as surfactant was investigated at room temperature. For development of anhydrous ER suspension using at real application, it should be researched how can reduce deposition of ER particles in ER suspension. Anhydrous ER suspensions mixing with phosphoric ester cellulose particles coated with octadecylamine were measured. As increasing the coating concentration of octadecylamine, not only analysis of electrical properties such as dielectric constant, current density and electrical conductivity but also rheological properties of ER suspensions were studied. From the experimental results, coating concentration of surfactant had large influence to ER properties of anhydrous ER suspension. Current density, conductivity and electrorheological effect ($\tau$/$\tau$$_{0}$) of ER suspension were linearly reduced with increasing the coating concentration of octadecylamine. But ER suspensions dispersed the phosphoric ester cellulose particles coated with octadecylamine showed reducing deposition of ER particles and could be redispersed easily.

• The Korean Journal of Rheology
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• v.11 no.2
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• pp.91-96
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• 1999

Semiconductive polyaniline and its derivatives such as poly(aniline-co-sodium diphenylamine sulfonate), poly (aniline-co-o-ethoxyaniline), poly (o-methylaniline), and poly (o-methoxyaniline) were synthesized, and then adopted as suspending particles of the electrorheological (ER) fluids. All suspensions of these polyaniline derivatives showed typical ER properties under high applied electric fields. However, flow behaviors are observed to be quite different depending on the polyaniline derivatives, especially in the stress plateau regions obtained at low shear rates. Using a scaling law, we also obtained universal cures of ER fluids from the flow curves at each applied electric field based on the relationship between the dynamic yield stress with the applied electric field and flow curve changes according to the electric fields.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.12
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• pp.1684-1691
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• 2001

Electrorheological fluids(ERFs) show a rapid and reversible increase in apparent viscosity by applied electric field. It is called the electrorheological effect (ER effect). The reason for ER effect is the induction of an electric dipole in each particle, leading to the formation of clusters in the direction of the field, which resist fluid flow. Generally, the behavior of ER fluids has been modeled on those of Bingham fluids. But there are some differences between Bingham fluids and ER fluids. The visualization of ER fliuds are presented and ER effects by the forming, growing and breaking of clusters are discussed. In the low shear rate area, the pressure drop is measured by a pressure sensor and the formation of ER particles is visualized by video camera. The reason for the nonlinear behavior of ER fluids at low shear rate is explained through results of visualization. As result, the behavior of ER fluids is nonlinear at low shear rate with overshoot area because it is different to from the clusters according to the strength of electric field. The gap of electrodes becomes narrow because of the cluster layer occurrence near to electrodes in any conditions.

• Applied Chemistry for Engineering
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• v.16 no.1
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• pp.1-8
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• 2005

Electrorheological (ER) fluids, typically composed of particles having higher dielectric constant or electric conductivity than that of suspending fluids with a low viscosity, undergo dramatic, reversible changes when exposed to an external electric field. Among various electroactive materials, we put our efforts on inorganic materials including zeolite, MCM-41, MCM-41/polyaniline composite and SBA-15/polyaniline composites. Their preparation and ER characteristics are introduced.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.613-619
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• 2022

The extended Maxwell-Wagner polarization model is employed to describe the ER(Electrorheological) behavior of bi-dispersed ER suspensions, and solutions to the equation of motion are obtained by dynamic simulation. Under the same particle volume fraction, it is found that the dynamic yield stresses of uniform size suspensions do not depend on the particle size. Compared with uniform size suspensions, the dynamic yield stress is reduced for ER fluids consisting of two kinds of particles with different sizes. Compared with the dynamic yield stress behavior, for ${\dot{\gamma}}^*$≧0.01 the shear stress shows different behaviors depending on the particle sizes and the raio of different size particles. The simulation results show the nonlinear ER behavior (∆_𝛕 ∝ Eⁿ, n ≈ 1.55) of the conducting particle ER suspensions.

• Korea-Australia Rheology Journal
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• v.11 no.3
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• pp.169-195
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• 1999

An electrorheological fluid (ERF) is typically a suspension of semi-conducting solid particles dispersed in an insulating carrier fluid, and shows a dramatic change in rheological properties when an external electric field is applied. This rapid and reversible change in flow properties has potential application in many electronically controlled mechanical devices, but the development of efficient devices and optimal materials for ERF is still hindered by incomplete understanding of the fundamental physical mechanisms involved. In recent years there have been considerable advances In relating microstructural models to the rheological behaviour, and these will form the basis of this review. Results of the theoretical calculations and simulations will be compared to the key experimental evidence available. An overview of the fundamental physical concepts behind electrorheological fluid behaviour will also be presented.

• Tribology and Lubricants
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• v.19 no.2
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• pp.72-77
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• 2003

Chitosan derivatives, Fluorinated chitosan, and N,N,N-Trimethyl chitosan iodide were synthesized as the disperse phases for the electrorheological fluid. The synthesis of these materials were confirmed by Fourier transform infrared spectroscopy (FT-lR). Chitosan derivative suspensions showed ER effect under the electric field. Especially, N,N,N-Trimethyl chitosan iodide suspension showed better electrorheological and electric properties than Fluorinated chitosan. It is due to difference in electron strength of polar groups composed derivatives. N,N,N-Trimethyl chitosan iodide suspension exhibited a linear dependence on an electric field power of 2.07.

• The Korean Journal of Rheology
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• v.6 no.2
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• pp.83-95
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• 1994

• Proceedings of the Korean Society of Rheology Conference
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• 2001.09a
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• pp.160.3-160
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• 2001