• 제목/요약/키워드: Electrophoretic deposition (EPD)

검색결과 58건 처리시간 0.028초

첨가제 없이 제작된 나노구조 코발트 산화물 리튬이온 배터리 전극의 전기 화학적 특성 (Electrochemical Properties of Additive-Free Nanostructured Cobalt Oxide (CoO) Lithium Ion Battery Electrode)

  • 김주윤;박병남
    • 한국전기전자재료학회논문지
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    • 제31권5호
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    • pp.335-340
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    • 2018
  • Transition metal oxide materials have attracted widespread attention as Li-ion battery electrode materials owing to their high theoretical capacity and good Li storage capability, in addition to various nanostructured materials. Here, we fabricated a CoO Li-ion battery in which Co nanoparticles (NPs) are deposited into a current collector through electrophoretic deposition (EPD) without binding and conductive agents, enabling us to focus on the intrinsic electrochemical properties of CoO during the conversion reaction. Through optimized Co NP synthesis and electrophoretic deposition (EPD), CoO Li-ion battery with 630 mAh/g was fabricated with high cycle stability, which can potentially be used as a test platform for a fundamental understanding of conversion reaction.

Synthesis and Characterization of Graphene Counter Electrode By Electrophoretic Deposition for Dye-Sensitized Solar Cells

  • 최윤수;공재석;최현광;전민현
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.160-160
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    • 2013
  • Dye-sensitized solar cells (DSSCs) have attracted much attention because of their moderate light-to-electricity conversion efficiency, easy fabrication, and low cost. At present, platinum (Pt) is used as a counter electrode in DSSCs. However, it is found that Pt dissolves in iodide electrolyte solutions and creates chemical compound such as PtI4 and H2PtI6. Carbon based materials are one of candidates for a counter electrode of DSSCs. We prepare two types of graphite oxides by different chemical treatments; original graphite oxide, hydrazine treated graphite oxide. Each graphite oxide and magnesium nitrate dispersed in deionized water are prepared as solutions for electrophoretic deposition (EPD). Each graphite oxide electrode is deposited on fluorine-doped tin oxide (FTO) substrate by EPD method. Structural and electrochemical properties of each electrode are investigated by field-emission scanning electron microscopy and electrochemical impedance spectroscopy, respectively.

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알코올계 현탁액에 따른 YBCO 초전도제의 전기영동전착 효과 (Effectiveness of various alcohol-based suspension for electrophoretic deposition of YBCO superconductor powder)

  • Soh, Deawha;Li, Yingmei;Cho,Yongjoon;Jeon,Yongwoo;Korobova, N.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.115-118
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    • 2001
  • High-temperature superconductor films of YBa$_2$Cu$_3$$O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension. Maximum stability is observed for the suspension containing iso-alcohol as the dispersion medium. However, for the formation of a dense and adherent coating of YBCO on a silver substrate by EPD, the best results were obtained in mix PrOH and BuOH suspension. The superconducting critical current density (J$_{c}$) was 1200 A/cm$^2$ for a films deposited in 30% iso-PrOH and 70 % iso-BuOH suspension.ion.

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전기영동 증착법을 이용한 Black Phosphorus Nano Flake 리튬이온 배터리 (Black Phosphorus Nano Flake Lithium Ion Battery Using Electrophoretic Deposition)

  • 김주윤;박병남
    • 한국전기전자재료학회논문지
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    • 제32권3호
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    • pp.252-255
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    • 2019
  • Black phosphorus (BP) is a potential candidate for an anode in lithium ion batteries due to its high theoretical capacity and the large interlayer spacing in the monolayered phosphorene form, allowing for lithium intercalation/deintercalation. In this study, large-scale exfoliation of bulk BP was accomplished using a solution of NaOH and N-methyl-2-pyrrolidone (NMP), yielding phosphorene, which can be assembled into nanoflakes using electrophoretic deposition (EPD). Through the systematic addition of NaOH and subsequent sonication, BP nanoflakes were obtained in high yields by EPD, allowing for the integration of these nanoflakes into an anode in the film state. Anodes with a charge/discharge capacity of 172 mAh/g at a rate of 200 mA/g were obtained, which are promising for battery applications through various post-film treatments.

Curcumin-Loaded PLGA Nanoparticles Coating onto Metal Stent by Electrophoretic Deposition Techniques

  • Nam, So-Hee;Nam, Hye-Yeong;Joo, Jae-Ryang;Baek, In-Su;Park, Jong-Sang
    • Bulletin of the Korean Chemical Society
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    • 제28권3호
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    • pp.397-402
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    • 2007
  • Restenosis after percutaneous coronary intervention (PCI) continues to be a serious problem in clinical cardiology. To solve this problem, drug eluting stents (DES) with antiproliferative agents have been developed. Variable local drug delivery systems in the context of stenting require the development of stent manufacture, drug pharmacology and coating technology. We have worked on a system that integrates electrophoretic deposition (EPD) technology with the polymeric nanoparticles in DES for local drug delivery and a controlled release system. The surface morphology and drug loading amount of DES by EPD have been investigated under different operational conditions, such as operation time, voltage and the composition of media. We prepared poly-D,L-lactide-co-glycolic acid (PLGA) nanoparticles embedded with curcumin, which was done by a modified spontaneous emulsification method and used polyacrylic acid (PAA) as a surfactant because its carboxylic group contribute negative charge to the surface of CPNPs (?53.5 ± 5.8 mV). In the process of ‘trial and error' endeavors, we found that it is easy to control the drug loading amount deposited onto the stent while keeping uniform surface morphology. Accordingly, stent coating by EPD has a wide application to the modification of DES using various kinds of nanoparticles and drugs.

진동정렬 EPD YBCO 후막테이프의 초전도 특성 개선 (Superconducting Properties of Shaky-aligned EPD Thick Film of YBCO Tape)

  • 소대화;조용준;박성범;전용우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.111-114
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    • 2003
  • In order to improve the surface uniformity and the conduction properties of the fabricated YBCO thick films, a system that applies alternating field vertically to the EPD field has been developed for the first time and applied to the electrophoretic deposition process. The applied alternating electric field caused a force to be exerted on each YBCO particle and resulted in a shaking of the particle in the direction of applied electric field, accomplishing a uniform particle orientation. The usual commercial electrical power was used for the vertically applied alternating voltage and the induced electric field was 25-120 V/cm at 60Hz. The thick film fabricated by the method developed in this paper showed better surface uniformity without crack and porosity and improved film characteristics such as critical temperature ($T_{c,zero}$ : 90 K) and critical current density ($2354\;A/cm^2$). Therefore, it is expected that the shaky-aligned electrophoretic deposition method can be used to fabricate superconductor films through a simpler process and at less expense.

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측면진동보조전계 전기영동 전착방식을 적용한 YBCO 초전도 후막의 제작 (Fabrication of YBCO Superconducting Thick Film by Use of Lateral Shaky Field Assisted EPD Method)

  • 소대화;전용우
    • 한국전기전자재료학회논문지
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    • 제16권11호
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    • pp.1041-1046
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    • 2003
  • In order to improve the surface uniformity and the conduction properties of the fabricated YBCO thick films, a system that applies alternating field vertically to the EPD field has been developed for the first time and applied to the electrophoretic deposition process. The applied alternating electric field, so called Shaky Alternating Assisted Field, caused a force to be exerted on each YBCO particle and resulted in a shaking of the particle in the direction of applied electric field, accomplishing a uniform particle orientation. The usual commercial electrical power was used for the vertically applied alternating voltage and the induced electric field was 25-120 V/cm at 60Hz. The thick film fabricated by the method developed in this paper showed better surface uniformity without crack and porosity and improved film characteristics such as critical temperature (Tc,zero = 90 K) and critical current density (2354 A/$\textrm{cm}^2$), Therefore, it is expected that the shaky-aligned electrophoretic deposition method can be used to fabricate superconductor films through a simpler process and at less expense.

미세 팁 기판 위에 전기영동법으로 성장시킨 탄소 나노튜브의 전계방출 특성 (Field emission properties of carbon nanotubes grown on micro-tip substrates using an electrophoretic deposition method)

  • 장한빛;노영록;김종필;박진석
    • 반도체디스플레이기술학회지
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    • 제9권4호
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    • pp.7-12
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    • 2010
  • Field-emission characteristics of carbon nanotubes(CNTs), which were grown on conical-type tungsten micro-tips by using an electrophoretic deposition(EPD) method, were examined. The EPD method proved to be convenient to manipulate and arrange CNTs from well dispersed suspensions onto such tip-type substrates. The growth rate of CNTs was proportional to the applied d.c. bias voltage and the process time. It was observed from the Raman study that the EPDproduced CNTs showed better crystal qualities with the Raman intensity ratio( $I_D$/$I_G$) of 0.41-0.42 than the CVD-produced CNTs and their crystal qualities could be further improved by thermal annealing. The electron emitters based on the EPDCNTs showed excellent field emission properties, such as the threshold voltage for electron emission of about 620 V and the maximum emission current of about 345 ${\mu}A$. In addition, the EPD-CNTs exhibited the stable long-term(up to 40 h) emission capability and the emission stability was enhanced by thermal annealing.

전착법과 담금법에 의한 음극지지형 SOFC 지르코니아 전해질막 제조 (Preparation of Electrolyte Thin Film for Anode Support Type Solid Oxide Fuel Cells by Electrophoretic Deposition and Dip-Coating)

  • 김상우;이병호;손용배;송휴섭
    • 한국세라믹학회지
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    • 제36권8호
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    • pp.791-798
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    • 1999
  • 다공성 NiO-YSZ 기판위에 전착법(EPD; Electrophoretic Deposition)법과 담금(Dip-coating)법에 의해 음극지지형 고체연료전지용 이트리아 안정화 지르코니아 박막 제조법을 연구하였다. 이를 위해 슬러리 농도 및 시간에 따른 박막의 무게, 박막의 결함 및 미세구조변화에 영향을 주는 제조조건들을 살펴 봄으로써 전착법과 담금법의 차이를 보았다. 담금법에서는 막생성 초기인 30초까지 막의 무게가 증가하지만 그 후에는 탈락이 일어나 시간을 증가하여도 막의 무게가 오히려 감소하였다. 전착법에서는 임계 인가전류 이상에서 시간에 따라 막의 무게가 증가하고 균일하고 치밀한 막이 형성하였다 전장이 매우 낮은 0.035 mA/$cm^2$ 의 정전류를 120초 이상 장시간 인가하면 막의 흘러내림(sagging)으로 인한 결함이 발생하였다. 전착법에 의해 균일하고도 치밀하게 가스 누출성이 없는 음극지지형 고체산화물 연료전지에 적합한 전해질 박막을 제조할 수 있었다.

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세라믹 분말재료의 EPD 후막형성 기술 (EPD Thick Film Formation of Ceramic Powder Materials)

  • 소대화;전용우
    • 동굴
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    • 제75호
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    • pp.49-54
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    • 2006
  • Electrophoretic Deposition (EPD) is the most convenient technology to deposit natural or oxide powders of nonconductive materials in alcoholic suspension solution with adding electrolyte of iodine to form ceramic thick film on metal substrate under applied electric field with double electric layer between electrode and metal substrate. In this research work, the important parameters and technical ways were studied to form EPD thick films of typical oxide ceramics of Al2O3, YBCO and tourmaline powders.