• Title/Summary/Keyword: Electron number density

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Improvement in the bias stability of zinc oxide thin-film transistors using an $O_2$ plasma-treated silicon nitride insulator

  • Kim, Ung-Seon;Mun, Yeon-Geon;Gwon, Tae-Seok;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.180-180
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    • 2010
  • Thin film transistors (TFTs) based on oxide semiconductors have emerged as a promising technology, particularly for active-matrix TFT-based backplanes. Currently, an amorphous oxide semiconductor, such as InGaZnO, has been adopted as the channel layer due to its higher electron mobility. However, accurate and repeatable control of this complex material in mass production is not easy. Therefore, simpler polycrystalline materials, such as ZnO and $SnO_2$, remain possible candidates as the channel layer. Inparticular, ZnO-based TFTs have attracted considerable attention, because of their superior properties that include wide bandgap (3.37eV), transparency, and high field effect mobility when compared with conventional amorphous silicon and polycrystalline silicon TFTs. There are some technical challenges to overcome to achieve manufacturability of ZnO-based TFTs. One of the problems, the stability of ZnO-based TFTs, is as yet unsolved since ZnO-based TFTs usually contain defects in the ZnO channel layer and deep level defects in the channel/dielectric interface that cause problems in device operation. The quality of the interface between the channel and dielectric plays a crucial role in transistor performance, and several insulators have been reported that reduce the number of defects in the channel and the interfacial charge trap defects. Additionally, ZnO TFTs using a high quality interface fabricated by a two step atomic layer deposition (ALD) process showed improvement in device performance In this study, we report the fabrication of high performance ZnO TFTs with a $Si_3N_4$ gate insulator treated using plasma. The interface treatment using electron cyclotron resonance (ECR) $O_2$ plasma improves the interface quality by lowering the interface trap density. This process can be easily adapted for industrial applications because the device structure and fabrication process in this paper are compatible with those of a-Si TFTs.

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Evaluation of Mechanical Properties and Microstructure Depending on Sintering Heating Rate of IN 939 W Alloy (IN 939 W 합금의 소결 승온 속도에 따른 물리적 특성과 미세조직 분석)

  • Jeon, Junhyub;Lee, Junho;Seo, Namhyuk;Son, Seung Bae;Jung, Jae-Gil;Lee, Seok-Jae
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.399-410
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    • 2022
  • Changes in the mechanical properties and microstructure of an IN 939 W alloy according to the sintering heating rate were evaluated. IN 939 W alloy samples were fabricated by spark plasma sintering. The phase fraction, number density, and mean radius of the IN 939 W alloy were calculated using a thermodynamic calculation. A universal testing machine and micro-Vickers hardness tester were employed to confirm the mechanical properties of the IN 939 W alloy. X-ray diffraction, optical microscopy, field-emission scanning electron microscopy, Cs-corrected-field emission transmission electron microscopy, and energy dispersive X-ray spectrometry were used to evaluate the microstructure of the alloy. The rapid sintering heating rate resulted in a slightly dispersed γ' phase and chromium oxide. It also suppressed the precipitation of the η phase. These helped to reinforce the mechanical properties.

Ecological and Morphological Characteristics of Zostera caulescens Miki (Zosteraceae) in Korea (한국산 수거머리말(Zostera caulescens Miki.)의 형태 및 생태적 특성에 대한 연구)

  • Lee, Sang-Yong;Suh, Young-Bae;Kim, Sang-Tae;Choi, Chung-Il
    • Ocean and Polar Research
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    • v.24 no.4
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    • pp.345-357
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    • 2002
  • Ecological characteristics on habitats and morphological features of the seagrass Zostera caulescens Miki in Korea were examined. The biogeographical distribution of Z. caulescens was confirmed in the south coast of the Korea. Zostera caulescens usually inhabits at the inner bay, where is sheltered from wave action and 3.0 to 6.5 m deep. The sediment in habitats is composed of very fine muddy sand or sandy mud. In morphology, Z. caulescens is easily distinguished from other species of the genus by the formation of vegetative canopy on the top of reproductive stems. The number of longitudinal ribs in testa was 24 revealed by scanning electron microscope (SEM) while the number of ribs in Z. marina has been often reported to be 16-20. Purplish anthocyanin spots were displayed on the surface when the testa was removed. We found that the size and shape of leaf epidermal cells in Z. caulescens were very different from those of Z. marina when the leaf cuticles were removed by maceration which could be useful characters for identifying Zostera species. The leaf of Z. caulescens displays two different casts of color when the fresh plant is closely observed. The margins of leaves appear brighter than the center of leaves due to the thickening by the development of paralleled venation in the middle of leaves. The comparison of two populations of Z. caulescens in Korea showed that they were considerably different in their shoot density and biomass. The shoot density and biomass at Gabae population was $367.3 m^{-2}\;and\;725.7g$ dry wt $m^P{-2}$ respectively, while those at Jukrim population were $112.5m^{-2}\;and\;392.0g\;dry\;wt\;m^{-2}$, respectively.

AN EXPERIMENTAL STUDY OF THE IRRADIATION EFFECTS ON THE MICROVASCULATURE OF THE RAT SUBMANDIBULAR GLAND (방사선 조사가 백서 악하선 미세혈관계에 미치는 영향에 관한 실험적 연구)

  • Choi Karp Shik;Choi Soon Chul;Park Tae won
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.22 no.1
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    • pp.43-53
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    • 1992
  • The purpose of this study was to investigate the effects of irradiation on the microvascular structure of the submandibular gland in rats. For this study, 110 male rats were singly irradiated with the dose of 10Gy or 20Gy to their neck region by 6MV X-irradiation and sacrificed on the 1st, 3rd, 7th, 14th and 28th day after irradiation. The author observed distribution and structural changes of the microvasculature in rat submandibular glands using a scanning electron microscope by forming vascular resin casting. The author observed ultrastructural changes of the endothelial cells using a transmission electron microscope, and also histologic changes using a light microscope at Hematoxylin and Eosin staining and PAS staining process. The results of the irradiation effects on the microvasculature in rat submandibular gland were as follows: By light microscopic examination, the dilation of small vessels were observed until the 7th day after irradiation. After then, the vascular constriction and decrease in number of small vessels were noticed. Changes were greater on 20Gy irradiated group than on lOGy irradiated group. The reaction to PAS staining at acinar cells was decreased just after irradiation, but gradually recovered with days. There was no specific difference between two irradiated groups. By scanning electron microscopic examination, general findings on the two irradiated groups were similar. The dilation of conduits and meandering were observed on the 3rd day after irradiation. Decrease of capillary density and blunt ended small vessels were appeared on the 7th day after irradiation. After that, findings of the tortuous and twisted vascular running and coarseness of capillary lumen were increased. Changes were greater on 20Gy irradiated group than on l0Gy irradiated group. By transmission electron microscopic examination, increase of the formation of cytoplasmic process was observed on the 3rd day after irradiation. After that, swelling of endothelial cell and bridge formation of cytoplasmic processes were also observed, but destruction of endothelial cell and loss of basement membrane were observed only on 20Gy irradiated group on the 28th day after irradiation.

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Flexible, Tunable, and High Capacity Ultracapacitor using Nitron-Doped Graphene (질소가 도핑된 그라핀을 이용한 고용량의 조절이 가능한 플렉서블 울트라커페시터)

  • Jeong, Hyung Mo;Shin, Weon Ho;Choi, Yoon Jeong;Kang, Jeung Ku;Choi, Jang Wook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.163.2-163.2
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    • 2010
  • We developed a simple method to synthesis a nitrogen doped graphene, nitrogen plasma treated graphene (NPG) sheets thought nitrogen plasma etching of graphene oxide (GO). X-ray photo electron spectroscopy (XPS) study of NPG sheets treated at various plasma conditions reveal that N-doping is classified to 3 kinds of binding configurations. The nitrogen doping concentration is at least 1.5 at % and up to 3 at% with changing of ratio of nitrogen configuration in NPG. Our group demonstrate ultracapacitor with high capacity and extremely durable using a NPG sheets that are comparable to pristine graphene supercapacitor, and pseudocapacitor using polymer and metal oxide with redox reaction, capacitance that are three-times higher, and a cycle life that are extremely stable. We also realized flexible capacitor by using the paper electrode that are coated by NPG sheets. NPG paper capacitor presented almost same performance compare with NPG on a metal substrate, and durability is much more enhanced than that. To additionally explain that how different kind of atoms in graphene layers can act as the ion absorption sites, we simulated the binding energy between nitrogen in graphene layer and ions in electrolyte. Increasing the energy density and long cycle life of ultracapacitor will enable them to compete with batteries and conventional capacitors in number of applications.

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Flux pinning properties of Y-Ba-Cu-O thin films grown on STO substrates with assembled Au nanoparticles (금 나노입자가 배열된 STO기판에서 성장된 Y-Ba-Cu-O박막의 Flux pinning 특성)

  • Oh, Se-Kweon;Jang, Gun-Eik;Lee, Cho-Yeon;Hyun, Ok-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.375-375
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    • 2009
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. We report measurements of critical current in $YBa_2Cu_3O_{7-\delta}$ films deposited by PLD on $SrTiO_3$ substrates decorated with Au nanoparticles. Au nanoparticles were synthesized on STO substrates with self assembled monolayer. Microstructural analysis of the obtained YBCO films was performed by using cross-section transmission electron microscopy(TEM). Phase and textural analysis was done using X-ray diffraction. The surface morphology and surface roughness(Ra) of the layers was measured by atomic force microscopy(AFM).

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Comparison of Morphology of Deposits on SiC Filaments with LIF Image in Propane/Air Laminar Diffusion Flames in an Oxidizer Deficient Environment (산화제 결핍 상태의 프로판 층류 확산화염에서 LIF 이미지와 SiC 필라멘트 부착물의 형태 비교)

  • Shim, Sung-Hoon;Yoo, Chang-Jong;Shin, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.1-9
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    • 2002
  • The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM and compared with UV-excited laser induced broadband fluorescences in co-flowing, propane laminar diffusion flames in a reduced oxidizer environment. The homogeneous morphology of droplet-like deposits inner flame zone and the agglomeration of condensed-phase deposits and the transition to soots from grown up droplet-like precursors with approaching the flame surface can be observed in a barely sooting flame. The average size of the mature soots deposited in the luminous flame edge is scarcely dependent on their axial position in a confined flame under reduced oxidizer condition. A double structure of PAH fluorescence is observed in near-extinction flames with further decreasing of oxidizer. A comparison of the PAH fluorescence with the morphologies of deposits indicates that appearance of the "dark" hollow zone is caused by a decreased number density of developed liquid-phase large molecules and the outer weak fluorescence zone is caused by the diffusion of gas-phase small molecules.

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Enhanced Electrocatalytic Activity of Low Ni Content Nano Structured NiPd Electrocatalysts Prepared by Electrodeposition Method for Borohydride Oxidation

  • Zolfaghari, Mahdieh;Arab, Ali;Asghari, Alireza
    • Journal of Electrochemical Science and Technology
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    • v.11 no.3
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    • pp.238-247
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    • 2020
  • Some nano structured bimetallic NiPd electrocatalysts were electrodeposited on glassy carbon electrodes using a double potential step chronoamperometry. The morphology of the electrodeposited samples was investigated by field emission-scanning electron microscopy, while their compositions were evaluated using energy dispersive X-ray spectroscopy. It was observed that the electrodeposited samples contained a low Ni content, in the range of 0.80 - 7.10%. The electrodeposited samples were employed as the anode electro-catalysts for the oxidation of sodium borohydride in NaOH solution (1.0 M) using cyclic voltammetry, chronoamperometry, rotating disk electrode, and impedance spectroscopy. The number of exchanged electrons, charge transfer resistances, apparent rate constants, and double layer capacitances were calculated for the oxidation of borohydride on the prepared catalysts. According to the results obtained, the NiPd-2 sample with the lowest Ni content (0.80%), presented the highest catalytic activity for borohydride oxidation compared with the other NiPd samples as well as the pure Pd sample. The anodic peak current density was obtained to be about 1.3 times higher on the NiPd-2 sample compared with that for the Pd sample.

THE DISTRIBUTION MODELS OF THERMAL AND NON-THERMAL RADIO CONTINUUM EMISSION IN THE GALACTIC DISK

  • SANGUANSAK N.;OSBORNE J. L.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.169-170
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    • 1996
  • In the past, it. was very difficult to distinguish thermal and non-thermal emission. Broadbent et a1. (1989) has developed a new technique with the help of the IRAS 60 micron emission. The distribution of non-thermal or synchrotron emission in the Galactic disk has been modeled from the 408 MHz all sky survey of Haslam et a1. (1982) after removal of the thermal component.. At. 408 MHz, t.here is very little absorption in the interstellar medium and the distribution along the line-of-sight. is inferred mainly from its presumed relationship to other tracers of spiral structure via a. number of fitted parameters. But. at lower frequencies, free-free absorption becomes important and can give some direct. information on the line of sight. distribution. We have modeled the thermal electron density according to the spiral arm models and the distribution of ionized hydrogen in the Galactic plane by Lockman (1976) and Cersosimo et. al. (1989) and have made predictions to compare with the surveys of Dwarakanath et al. (1990) at. 34.5 MHz and .Jones and Finlay (1974) at 29.9 MHz. The result confirms that the absorption model of the synchrotron emissivity in the Galactic plane is broadly corrected and illustrates the potential of the absorption technique.

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Biocompatibility of oxidized alginate/gelatin/BCP -based hydrogel composites

  • Phuong, Nguyen Thi;Min, Young-Ki;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byong-Teak
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.40.2-40.2
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    • 2010
  • In this study, oxidized alginate/gelatin/biphase calcium phosphate (BCP)- based hydrogel composites were fabricated. Alginate sodium was oxidized by periodate. The oxidized product was confirmed by using $^1H$ and $^{13}C$ NMR spectra. The number average molecular weight ($M_n$), the average molecular weight ($M_w$) of the oxidized alginate were determined by Gel Permeation Chromatography (GPC). The hydrogel was formed from the oxidized alginate and gelatin solution via Schift-base reaction. The hydrogel showed a highly porosity by a Scanning Electron Microscope (SEM) and Mercury Intrusion Porosimetry (MIP). Crosslinked density of the gel matrix were assessd by trinitrobenzene sulfonic acid (TNBS) assay that shows a high effect on swelling ratio. Increment of the crosslinked desity resulted in enhancing compressive strength of the hydrogel composite. The cytotoxity of hydrogel was assessed with osteoblast MG-63. The hydrogel composites show a high compatibility. The obtained results showed a potential application for bone regeneration in future.

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