• Title/Summary/Keyword: Electron contamination

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Heat Treatment of Carbonized Photoresist Mask with Ammonia for Epitaxial Lateral Overgrowth of a-plane GaN on R-plane Sapphire

  • Kim, Dae-sik;Kwon, Jun-hyuck;Jhin, Junggeun;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.208-213
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    • 2018
  • Epitaxial ($11{\bar{2}}0$) a-plane GaN films were grown on a ($1{\bar{1}}02$) R-plane sapphire substrate with photoresist (PR) masks using metal organic chemical vapor deposition (MOCVD). The PR mask with striped patterns was prepared using an ex-situ lithography process, whereas carbonization and heat treatment of the PR mask were carried out using an in-situ MOCVD. The heat treatment of the PR mask was continuously conducted in ambient $H_2/NH_3$ mixture gas at $1140^{\circ}C$ after carbonization by the pyrolysis in ambient $H_2$ at $1100^{\circ}C$. As the time of the heat treatment progressed, the striped patterns of the carbonized PR mask shrank. The heat treatment of the carbonized PR mask facilitated epitaxial lateral overgrowth (ELO) of a-plane GaN films without carbon contamination on the R-plane sapphire substrate. Thhe surface morphology of a-plane GaN films was investigated by scanning electron microscopy and atomic force microscopy. The structural characteristics of a-plane GaN films on an R-plane sapphire substrate were evaluated by ${\omega}-2{\theta}$ high-resolution X-ray diffraction. The a-plane GaN films were characterized by X-ray photoelectron spectroscopy (XPS) to determine carbon contamination from carbonized PR masks in the GaN film bulk. After $Ar^+$ ion etching, XPS spectra indicated that carbon contamination exists only in the surface region. Finally, the heat treatment of carbonized PR masks was used to grow high-quality a-plane GaN films without carbon contamination. This approach showed the promising potential of the ELO process by using a PR mask.

Evaluation of Biodegradation in an Aquifer Contaminated with Petroleum Hydrocarbon

  • 이지훈;이진용;이강근
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.120-123
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    • 2001
  • To evaluate the biodegradability of contaminants in an aquifer, computer modeling with RT3D model (Clement, 1997) was used. The RT3D model simulates the biodegradation of organic contaminants using a number of aerobic and anaerobic electron acceptors. The RT3D model was applied to a well-studied petroleum hydrocarbon plume in a shallow unconfined aquifer in Uiwang, Korea. The results of this study demonstrate tile importance of biodegradation processes in the monitored natural attenuation and in reducing contaminant concentrations in a shallow aquifer. The modeling results tell that the amount of electron acceptors is the key factor affecting biodegradation of TEX, the petroleum hydrocarbon contaminant in shallow groundwater

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In-situ rf treatment of multiwall carbon nanotube with various post techniques for enhanced field emission

  • Ahn, Kyoung-Soo;Kim, Jun-Sik;Kim, Ji-Hoon;Kim, Chae-Ok;Hong, Jin-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.859-862
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    • 2003
  • Well-aligned multiwall carbon nanotubes (MWCNTs) were prepared at low temperature of 400 $^{\circ}C$ by utilizing a radio frequency plasma-enhanced chemical vapor deposition (rf-PECVD) system. The MWCNTs were treated by an external rf plasma source and an ultra-violet laser in order to modify structural defect of carbon nanotube and to ablate possible contamination on carbon nanotube surface. Structural properties of carbon nanotubes were investigated by using a scanning electron microscopy (SEM), Raman spectroscopy, Fourier transformer Infrared spectroscopy (FTIR) and transmission electron microscope (TEM). In addition, the emission properties of the MWNTs were measured for the application of field emission display (FED) in near future. Various post treatments were found to improve the field emission property of carbon nanotubes.

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A Batch Study on BTEX and MTBE Biodegradation by Denitrifiers under Aerobic and Anaerobic Conditions

  • 오인석;이시진;장순웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.467-470
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    • 2003
  • Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Nitrate can also serve as an electron acceptor and results in anaerobic biodegradation of organic compounds via the processes of nitrate reduction and denitrification. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. And denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. These studies have shown that BTEX and MTBE can be degraded by the nitrate-amended microcosms under aerobic and anaerobic conditons. Biodegradation of the toluene and ethylbenzne compounds occurred very quickly under denitrifying conditions. MTBE, benzene and p-xylene were recalcitrant under denitrifying conditions in this study, But finally Biodegradaton was observed for all of the test compounds.

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탈질조건을 이용한 유류물질 생분해 기초연구

  • 오인석;장순웅;이시진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.368-371
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    • 2003
  • Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Bioremediation of aromatic hydrocarbons in groundwater and sediments is often limited by dissolved oxygen. Aerobic bioremediation has been highly effective in the remediation of many fuel releases, but Many aromatic hydrocarbons degrade very slowly under anaerobic conditions. Nitrate is a good alternative electron acceptor to oxygen and denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. This study show that biodegradation of BTEX and MTBE is enhanced by the nitrate-amended microcosms under aerobic/anaerobic conditons. Although aromatic hydrocarbons degrade very slowly under anaerobic conditions. Biodegradaton was observed for all of the test compounds.

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Optimization of MgO secondary electron emission in plasma displays, by the adoption of a suitable getter configuration;Part I: MgO degradation studies

  • Riva, Mauro;Bonucci, Antonio;Carretti, Corrado;Han, Yong-Gyu;Choi, Eun-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.220-223
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    • 2007
  • The key role of MgO is well recognized in PDP's technology. During manufacturing, significant contamination of the oxide occurs. Getters can compete against the impurities sorption speed of the oxide layer. The analysis of the impact of a suitable getter configuration on the operational parameters of PDP's is the final goal of this study.

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Applications of the Scanning Electron Microscope (주사형(走査型) 전자현미경(電子顯微鏡)의 응용분야(應用分野))

  • Kim, Yong-Nak
    • Applied Microscopy
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    • v.2 no.1
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    • pp.39-46
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    • 1972
  • There are many kinds of microscopes suitable for general studies; optical microscopes(OM), conventional transmission electron microscopes (TEM), and scanning electron microscopes(SEM). The optical microscopes and the conventional transmission electron microscopes are very familiar. The images of these microscopes are directly formed on an image plane with one or more image forming lenses. On the other hand, the image of the scanning electron microscope is formed on a fluorescent screen of a cathode ray tube using a scanning system similar to television technique. In this paper, the features and some applications of the scanning electron microscope will be discussed briefly. The recently available scanning electron microscope, combining a resolution of about $200{\AA}$ with great depth of field, is favorable when compared to the replica technique. It avoids the problem of specimen damage and the introduction of artifacts. In addition, it permits the examination of many samples that can not be replicated, and provides a broader range of information. The scanning electron microscope has found application in diverse fields of study including biology, chemistry, materials science, semiconductor technology, and many others. In scanning electron microscopy, the secondary electron method. the backscattererd electron method, and the electromotive force method are most widely used, and the transmitted electron method will become more useful. Change-over of magnification can be easily done by controlling the scanning width of the electron probe. It is possible. to continuously vary the magnification over the range from 100 times to 1.00,000 times without readjustment of focusing. Conclusion: With the development of a scanning. electron microscope, it is now possible to observe almost all-information produced through interactions between substances and electrons in the form of image. When the probe is properly focused on the specimen, changing magnification of specimen orientation does not require any change in focus. This is quite different from the conventional transmission electron microscope. It is worthwhile to note that the typical probe currents of $10^{-10}$ to $10^{-12}\;{\AA}$ are for below the $10^{-5}$ to $10^{-7}\;{\AA}$ of a conventional. transmission microscope. This reduces specimen contamination and specimen damage due to heatings. Outstanding features of the scanning electron microscope include the 'stereoscopic observation of a bulky or fiber specimen in high resolution' and 'observation of potential distribution and electromotive force in semiconductor devices'.

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Effect of Disk Rotational Speed on Contamination Nano Particles Generated in a Hard Disk Drive (하드 디스크 드라이브 회전수 변화가 드라이브 내 나노 오염 입자 발생에 미치는 영향)

  • Lee, Dae-Young;Hwang, Jung-Ho;Bae, Gwi-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.8 s.227
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    • pp.976-983
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    • 2004
  • In high-density hard disk drives, the slider should be made to fly close to the magnetic recording disk to generate better signal resolution and at an increasingly high velocity to achieve better data rate. The slider disk interaction in CSS (contact-start-stop) mode is an important source of particle generation. Contamination particles in the hard disk drive can cause serious problems including slider crash and thermal asperities. We investigated the number and the sizes of particles generated in the hard disk drive, operating at increasing disk rotational speeds, in the CSS mode. CNC (condensation nucleus counter) and PSS (particle size selector) were used for this investigation. In addition, we examined the particle components by using SEM (scanning electron microscopes), AES (auger electron spectroscopy), and TOF-SIMS (time of flight-secondary ions mass spectrometry). The increasing disk rotational speed directly affected the particle generation by slider disk interaction. The number of particles that were generated increased with the disk rotational speed. The particle generation rate increased rapidly at motor speeds above 8000 rpm. This increase may be due to the increased slider disk interaction. Particle sizes ranged from 14 to 200 nm. The particles generated by slider disk interaction came from the lubricant on the disk, coating layer of the disk, and also slider surface.

Comparison of Quality of Bologna Sausage Manufactured by Electron Beam or X-Ray Irradiated Ground Pork

  • Shin, Mee-Hye;Lee, Ju-Woon;Yoon, Young-Min;Kim, Jong Heon;Moon, Byeong-Geum;Kim, Jae-Hun;Song, Beom-Suk
    • Food Science of Animal Resources
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    • v.34 no.4
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    • pp.464-471
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    • 2014
  • Ground lean pork was irradiated by an electron beam or X-rays to compare the effects of two types of radiation generated by a linear accelerator on the quality of Bologna sausage as a model meat product. Raw ground lean pork was vacuum packaged at a thickness of 1.5 cm and irradiated at doses of 2, 4, 6, 8, or 10 kGy by an electron beam (2.5 MeV) or X-rays (5 MeV). Solubility of myofibrillar proteins, bacterial counts, and thiobarbituric acid reactive substance (TBARS) values were determined for raw meat samples. Bologna sausage was manufactured using the irradiated lean pork, and total bacterial counts, TBARS values, and quality properties (color differences, cooking yield, texture, and palatability) were determined. Irradiation increased the solubility of myofibrillar proteins in a dose-dependent manner (p<0.05). Bacterial contamination of the raw meat was reduced as the absorbed dose increased, and the reduction was the same for both radiation types. Differences were observed only between irradiated and non-irradiated samples (p<0.05). X-ray irradiation may serve as an alternative to gamma irradiation and electron beam irradiation.

Effect of Electron Beam Irradiation on Microbial Qualities of Whole Black Pepper Powder and Commercial Sunsik (전자선 조사가 통후추 분말과 시판 선식의 미생물학적 안전성 및 품질에 미치는 영향)

  • Ko, Jong-Kwan;Ma, Yu-Hyun;Song, Kyung-Bin
    • Korean Journal of Food Science and Technology
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    • v.37 no.2
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    • pp.308-311
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    • 2005
  • Electron beam irradiation was applied to examine microbial safety and qualities of black pepper powder and commercial Sunsik. Whole black pepper powder and commercial Sunsik were irradiated at 2, 4, 8, 12, and 16 kGy. Microorganism contamination in black pepper powder and commercial Sunsik were significantly decreased by irradiation. Decimal reduction doses ($D_{10}\;value$) of total bacteria count in black pepper powder and commercial Sunsik were 5.32 and 1.56 kGy, respectively. $D_{10}\;value$ of yeast and mold were 2.54 and 2.14 kGy for black pepper powder and commercial Sunsik, respectively. Electron beam irradiation caused negligible changes in Hunter color L, a, and b values. Sensory evaluations of black pepper powder and commercial Sunsik showed no significant changes among samples. These results indicate electron beam irradiation improves microbial safety and qualities of black pepper powder and commercial Sunsik.