• Title/Summary/Keyword: Electrolysis alkaline aqueous

Search Result 9, Processing Time 0.023 seconds

Strength Property of Concrete Mixed Blast Furnace Slag Using Electrolysis Alkaline Aqueous as Mixed Water (전기분해 알칼리수를 배합수로 활용한 고로슬래그 혼입 콘크리트의 강도 특성)

  • Jeong, Su-Mi;Kim, Ju-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2023.05a
    • /
    • pp.135-136
    • /
    • 2023
  • In this study, a concrete was prepared using an alkaline aqueous solution produced by electrolyzing potassium carbonate in order to improve the low initial strength of concrete using blast furnace slag. In order to confirm the increase in initial strength, the compressive strength of specimens was measured on the age of 7, 28 days. As a result, the blast furnace slag concrete using the electrolysis alkaline aqueous solution as the mixed water show high strength more than the blast furnace slag concrete using the general mixed water.

  • PDF

Hydration Properties of High Volume Cement Matrix Using Blast Furnace Slag and Alkaline Aqueous by Electrolysis (고로슬래그 및 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 수화특성)

  • Kim, Sun-A;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.5 no.1
    • /
    • pp.8-13
    • /
    • 2017
  • This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

Evaluating the Durability of Concrete Combined with Ground Granulated Blast Furnace Slag using Electrolysis Alkaline Aqueous as Mixing Water (전기분해 알칼리수를 배합수로 사용한 고로슬래그 미분말 혼입 콘크리트의 내구성)

  • Jeong, Su-Mi;Kim, Ju-Sung;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
    • /
    • v.23 no.4
    • /
    • pp.349-358
    • /
    • 2023
  • This research aimed to enhance the initial strength of concrete that is mixed with ground granulated blast furnace slag, as well as to fortify its resistance to carbonation and chloride ion permeation. To achieve this, alkaline aqueous, produced through the electrolysis of potassium carbonate, was employed as the mixing water in the preparation of concrete. To substantiate the increment in initial strength, compressive strength measurements of the concrete were executed. Additionally, an accelerated carbonation test and a chloride ion permeation resistance test were undertaken. The results confirmed that the initial strength of the concrete, which utilized electrolysis alkaline aqueous as mixing water, exhibited an improvement in comparison to concrete mixed with conventional water. It was also verified that both carbonation resistance and chloride ion permeation resistance showed enhancements.

A Study on Hazard of Renewable Energy based Alkaline Water Exectrolysis Equipment (재생에너지 기반 알칼라인 수전해 장치(2 Nm3/hr) 위험요인 고찰)

  • KIM, HYEONKI;SEO, DOOHYOUN;KIM, TAEHUN;RHIE, KWANGWON;LEE, DONGMIN;SHIN, DANBEE
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.33 no.1
    • /
    • pp.55-60
    • /
    • 2022
  • As interest in sustainable and eco-friendly energy sources is increasing due to various problems in the carbon society, a hydrogen economy using hydrogen as a main energy source is emerging. While the natural gas reforming method generates carbon dioxide, the water electrolysis method based on renewable energy is eco-friendly. The water electrolysis device currently being developed uses a 2 Nm3/hr class alkaline aqueous solution as an electrolyte and produces hydrogen based on renewable energy. In this study, risk assessment was conducted for these water electrolysis devices

Hydration Properties of Cement Matrix using Electrolysis Alkaline Aqueous and Ground Granulated Blast Furnace Slag (전기분해 알칼리 수 및 고로슬래그 미분말 혼입 시멘트 경화체의 수화 특성)

  • Jung, Yoong-Hoon;Kim, Ho-Jin;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.9 no.2
    • /
    • pp.185-190
    • /
    • 2021
  • Cement has been used as a main material in the modern construction industry. However, it has been pointed out as a main cause of global warming due to carbon dioxide generated during manufactured. Recently, research that replacing cement substitute to industrial by-products such as Blast Furnace Slag which is by-producted in steelworks. When Blast Furnace Slag is used as a cement substitute, it shows a problem of lower initial strength, which is caused by glassy membrane on the particle surface. In this study, we used Electrolysis Alkaline Aqueous to improve the usability and problem of lower initial strength. As a result of the experiment, cement matrix using Blast Furnace Slag and Alkaline Aqueous showed initial strength and hydrate product were developed than that using general mixing water. Also, as a result of porosity analysis, It was confirmed that cement matrix using Alkaline Aqueous and Blast Furnace Slag has a tighter structure in internal porosity and porosity distribution than using general mixing water.

A Study on Effect of the Shape of Electrodes in Alkaline Water Electrolysis (알카리 수전해에서 전극 형상의 영향에 관한 연구)

  • CHOI, SOOKWANG;KIM, JONGSOO;HAN, JIN MOOK;YUN, SEONG-HO;KIM, SEWOONG;JUNG, YOUNGUAN
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.28 no.2
    • /
    • pp.121-128
    • /
    • 2017
  • For an investigation on the effect of the shape of electrodes in alkaline water electrolysis, two kinds of stack with circular and square electrode array are used to visualize both for behaviors of hydrogen bubble around the electrodes and for measurements of hydrogen production from these two stacks. The electrolytes for the hydrogen production experiment were applied for 20 wt%, 25 wt%, 30 wt% and 35 wt% of KOH alkaline aqueous solutions. As a result, the adhesion length of bubbles attached around the square electrode in the visualization experiment was found to be 1.7 times longer compared with the attached around the circular electrode. In the hydrogen production experiments, the volume of hydrogen production of the stack by using circular electrode array was approximately 3% more than that of the stack with square electrode array. These observations may be caused by the effect of the bubbles attached to the around the electrodes obstructing mass transfer such as hydrogen exhaust and electrolyte supply.

A Study on Active Ion Transport Technology to Improve Water Electrolysis System Performance (수전해 시스템 성능 향상을 위한 능동 이온수송 기술 연구)

  • HYEON-JUNG KIM;HAO GUO;SANG-YOUNG KIM
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.34 no.2
    • /
    • pp.132-140
    • /
    • 2023
  • In this study, rotary magnet holder (RMH) was manufactured to analyze the ion transport effect according to the rotating magnetic field for the hydrogen production efficiency by alkaline water electrolyte. In the experiment, the voltage signal according to the magnet arrangement inside the RMH, the rotation speed, and the rotation time was measured using the voltage measurement module. As a result of the voltage signal measurement experiment, the average potential difference increased as the rotation speed of the RMH increased. Through the results of the voltage signal measurement experiment, the most efficient magnet arrangement (case 2) was applied to the RMH to conduct a water electrolysis experiment. A 20% NaOH aqueous solution was filled in the electrolytic cell, and a direct current 2 V constant voltage was applied to measure the current value according to the RMH rotation to compare the hydrogen generation amount. When rotating at 100 RPM, the hydrogen production efficiency increased by 8.06% compared to when not rotating. Considering the area exceeding +25 mA, which was not measured at the beginning of the experiment, an increase in hydrogen production of about 10% or more can be expected.

Carbonation Resistance Property of Mortar using Electrolysis Aqueous (전기분해수를 배합수로 활용한 모르타르의 탄산화 저항 특성)

  • Jeong, Su-Mi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.10 no.3
    • /
    • pp.204-210
    • /
    • 2022
  • Cement is pointed out as the main cause of carbon dioxide emission in the construction industry. Many researchs are underway to use blast furnace slag, an industrial by-product, as a substitute for cement to reduce carbon dioxide emitted during the manufacturing the cement. When blast furnace slag is used as a substitute for cement, it has advantages such as long-term strength and chemical resistance improvement. However, blast furnace slag has a problem that makes initial strength low. This is due to the impermeable film on the surface created during the production of blast furnace slag. The created film is known to be destroyed in an alkaline environment, and based on this, previous studies have suggested a solution using various alkali activators. But, alkali activator is dangerous product since it is a strong alkaline material. And it has the disadvantage in price competitiveness. In this study, an experiment was conducted to improve the initial hydration reactivity of the blast furnace slag to secure the initial strength of the mortar substituted with the blast furnace slag and to check whether the carbonation resistance was increased. As a result of the experiment, it was confirmed that the mortar using alkaline water showed higher strength than the mortar using tap water, and there were more hydration products generated inside. In addition, it was confirmed that the mortar using alkaline water as a compounding water had high carbonation resistance.