• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.310-313
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• 2003

The precipitation of heavy metals within the region of pH jump is inevitable in the conventional electrokinetic remediation technology. This study prevents the interest species from precipitating through the injection of flushing solutions in which HCl, acetic acid, citric acid, EDTA and SDS dissolved. The cumulative flow resulted from electroosmosis appear in order of Citric acid

• Journal of Environmental Science International
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• v.13 no.2
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• pp.149-159
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• 2004

In the removal of heavy metals from the mine deposit using electrokinetic processes, the effects of operation under both constant current and constant potential conditions were estimated. The results of soil pH distributions for DDW-20 V and DDW-100 mA cases after the electrokinetic remediation tests were observed. In the former case, soil pH was not much changed and kept to almost constant value just little higher than initial soil pH of 3.52, except near the cathode, which was about pH 5. While in the latter case, soil pHs of anode and the cathode regions were less than pH 3 and about 6, respectively. The electroosmotic flow to the cathode increased rapidly till 10 hrs and decreased steadily and then maintained to constant rate until the end of operation at constant current condition. Electric potential gradient was continuously increased to as much as 34.375 V/cm. At the steady state, values of the apparent electric conductivity for DDW-20 V and DDW-100 mA were around 40 ${\mu}\textrm{s}$/cm and 30 ${\mu}\textrm{s}$/cm, respectively. In the DDW-100mA test, Cu, Cd, and Zn except Pb showed the tendency of moving toward the cathode. While in the DDW-20 V case, it was observed that Cu, Zn, and Pb except Cd were not moved to any directions. The results of the tests demonstrated that the electrokinetic soil remediation process could be operated better under constant current condition than constant electric potential condition.

• Journal of Soil and Groundwater Environment
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• v.13 no.6
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• pp.17-22
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• 2008

The feasibility of acid-enhanced electrokinetic remediation on zinc and nickel-contaminated soil was investigated in the laboratory. Simple extraction efficiency using 1M HCl was 24% for Zn and 9% for Ni, as a result, the acid washing is not effective to remove Zn and Ni from the soil. The effiencey of normal electrokinetic treatment during 28 days was less than simple soil washing. Catholyte circulation with a strong acid enhanced dramatically the removal of Zn and Ni and pretreatment of soil with acid increased more the removal. Based on the result, acid-enhanced electrokinetic remediation is effective to remove Zn and Ni from the contaminated soil.

• Journal of Microbiology and Biotechnology
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• v.11 no.6
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• pp.1038-1045
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• 2001

The electrokinetic technology was applied in bioremediation for the purpose of supplying a Pseudomonas strain capable of degrading diesel to contaminated soil bed, and their biodegradation of diesel was carried out after a desired cell distribution was obtained. Electrokinetic injection of the strain was made possible because the cells acted as negatively charged particles at neutral pH, and thus the cells were transported with a precise directionality through the soil mostly by the mechanism of electrophoresis and in part by electroosmosis. A severe pH change in the soil bed was formed due to the penetration of electrolysis products, which was harmful to the cell viability and cell transport. To achieve a desirable cell transport and distribution, the control of pH in soil bed by a recirculating buffer solution in electrode chambers was essential during the appliation of an electric field. The judicious selections of electrolyte concentration and conductivity were also important for achieving an efficient electrokinetic cell transport since a higher electrolyte concentration favored the maintenance of pH stability in soil bed, but lowered electrophoretic mobility on the other hand. With electrolyte solution of pH 7 phosphate buffer, a 0.05 M concentration showed a better cell transport buffer, a 0.05 M concentration showed a better cell transport than 0.02 M and 0.08 M. The cell under pH 8 were obtained, compared to the cells under pH 7 or pH 9 in a given time period Up to $60\%$ of diesel was degraded in 8 days by the Pseudomonas cell, which were distributed electrokinetically under the conditions of pH 8 ($1,800{\mu}S/cm$, a mixture of phosphate and ammonia buffers) and 40 mA in a soil bed of 15 cm length.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2227-2238
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• 2000

The interfacial features of suspension system made of $CaCO_3$ particles have been investigated for the purpose of designing its effective treatment process. For the examination of variation of electrokinetic potential as a function of pH. the value of potential was observed to shift in the negative direction, which was thought to be due to the adsorption of hydroxide ion on the particle surface. Adsorption of surfactant on suspended particles resulted in the change of surface charge and shift in electrokinetic potential, which was dependent upon the sign of head charge and concentration of surfactant. Addition of inorganic salts affected stability of suspension greatly and sedimentation rate of suspension was influenced by the electric valence and amount of ions produced by dissolution of inorganic coagulants. DLVO theory made it possible to construct a energy profile diagram and a close correlation was found between experimental result and theoretically derived consequences. Non-specific adsorption of indifferent electrolyte resulted in the compression of electrical double layer and specific adsorption induced the shift of IEP and PZC in the opposite direction.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.626-631
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• 2021

One of the nonlinear electrokinetic phenomena around ion exchange membrane is electroconvective instability which can be found in various electrokinetic applications such as electrodialysis, electrochemical battery, microfluidic analysis platform, etc. Such instability acts as a positive transport mechanism for the electrodialysis via amplifying mass transport rate. On the other hands, in the electrochemical battery and the microfluidic applications, the instability provokes unwanted mass transport. In this research, to control the electroconvective instability, the onset of the instability was analyzed as a function of confinement effect as well as applied voltage. As a result, we figured out that the dynamic behavior of electroconvective instability transited as a sequence of stable regime - static regime - chaotic regime depending on the applied voltage and confinement effect. Furthermore, stability curves about the dynamic transition were numerically determined as well. Conclusively, the confinement effect on electroconvective instability can be applied for effective means to control the electrokinetic chaos.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.155-161
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• 2023

Ion concentration polarization (ICP) is one of the essential important mechanisms for biomolecule preconcentration devices as well as a fundamental transport phenomenon found in electrodialysis, electrochemical cell, etc. The ICP triggered by externally applied voltage enables the biomolecular analyte to be preconcentrated at an arbitrary position by a locally amplified electric field inside the microchannel. Conventional preconcentration methodologies using the ICP have two limitations: uncertain equilibrium position and hydrodynamic instability of preconcentration plug. In this work, a new preconcentration method in the dead-end microchannel around cation exchange membrane was numerically studied to resolve the limitations. As a result, the numerical model showed that the analyte was concentrated at a shock front developed in a geometrically confined dead-end channel. Furthermore, the electrokinetic behaviors for preconcentration dynamics were analyzed by changing microchannel's applied voltage and volumetric charge concentration of microchannel as key parameters to describe the dynamics. This work would provide an effective means for a point-of-care platform that requires ultra-fast preconcentration method.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.1C
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• pp.1-5
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• 2010

The river maintenance processing has revealed that the river beds in Korea have been significantly polluted in various ways for the last two decades. Thus, the dredging, transportation and landfilling of these contaminated materials are attracting public attention these days. In this study, electrokinetic method was applied in order to accelerate the settling processes of clay particles in suspension and evaluate the factors affecting the settling behaviour. It has been found from the testing results that the settling velocity under the influence of electrokinetics was much faster than the gravitational one, and the water content of slurry soil reduced significantly after the electrokinetic processing. The initial water content of slurry soil should be one of the important factors affecting the settling behaviour as well as variation of water content, and hence the electrokinetic processing would be the cost-effective method for the field application.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1C
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• pp.9-17
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• 2006

The numerical analysis to predicting the electrokinetic remediation behavior on unsaturated soil is carried out by aiding HERO, Hanyang Unversity Electrokinetic Remediation program, developed from the finite difference method and in the VISUAL FORTRAN environment. The analysis for the pure kaolinite under saturated conditions is performed on the results of the previous study of Acar (1997). Also the predictions to the characteristics of electrokinetic remediation on unsaturated conditions are performed and the conclusions summarized as follows. First, pH of the electrolyte in the reservoirs is not different with the degree of saturation resulted from the changes in electrical efficiency. But the advance of acid front is increased dependent on the degree of saturation in contrary to the transportation of base front. Second, below the degree of saturation of 83%, which is equivalent to the optimum water content, the removal effect increased with the decreasing of degree of saturation. But it have no effect on the efficiency of removal over the degree of saturation of 83%.

• Journal of the Korean Geosynthetics Society
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• v.6 no.3
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• pp.25-30
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• 2007

The major reason to employ electrokinetic geosynthetics is to take advantage of its ability to densify very low permeability materials in shorter time periods than ordinary seepage consolidation. A number of laboratory scale experiments was carried out with acrylic column using natural clayey soil. The testing results indicate that (1) the electrically induced settlement was faster than the gravitational one, (2) the higher the voltage, the faster the dewatering but the less final settlement, and (3) the pH extended as low as 3 in the anode section and as high as 11 near the cathode.