• Title/Summary/Keyword: Electrokinetic

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Electrokinetic Remediation of Cobalt Contaminated Soil Using Ethanoic Buffer

  • Kim, Gye-Nam;Won, Hui-Jun;Oh, Won-Zin;Shim, Jun-Bo
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.1-8
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    • 2002
  • After kaolin clay was artificially contaminated with Co$^{2+}$ ion, the remediation characteristics were analyzed by the electrokinetic method. Ethanoic buffer was injected in the soil column and $CH_3$COOH was continuously inputted to the cathode reservoir to restrain the pH increase. Since the pH of the cathode side of the soil column was 4.0 initially and increased to only 6.5 after remediation for 43.6 hours, precipitate, Co(OH)$_2$, was not formed in the column. The effluent rate increased with the passage of time and Co$^{2+}$ removal in the column at the initial time were mainly controlled by ion migration. 13.1% of the total amount of Co$^{2+}$ in the soil column was removed in 10 hours, 46.8% of the total Co$^{2+}$ in 20.8 hours, 71.7% of the total Co$^{2+}$ in 30.1 hours, and 94.6% of the total Co$^{2+}$ in 43.6 hours. Meanwhile, residual concentrations in the column calculated by the developed model were similar to those by experiment. experiment.

Cost Analysis of Electrokinetic Process for Desalination of Saline Agricultural Land (염류집적 농경지 탈염을 위한 전기역학적 처리공정의 비용산출)

  • Kim, Do-Hyung;Choi, Jeong-Hee;Jo, Sung-Ung;Baek, Ki-Tae
    • Journal of Soil and Groundwater Environment
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    • v.17 no.4
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    • pp.91-97
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    • 2012
  • In this study, cost analysis of electrokinetic (EK) restoration process for desalination of saline agricultural land was performed for field application based on a pilot scale field application. For reasonable cost analysis, EK process was classified into three major parts: system design, installation and operation. Cost of system installation consists of materials and installation for electrode/electric wire, power supply and data monitoring, drainage system, etc. Operation cost was calculated based on electrical consumption and water charges for EK process. Total cost for EK process was 2,943,013 won for $1000m^2$ in greenhouse area. Cost for system installation was 2,553,786 won, that is, 87% of total cost, while cost for system operation was 389,229 won, that is, 13% of total cost.

Improved Treatment Technique for the Reuse of Waste Solution Generated from a Electrokinetic Decontamination System (동전기제염장치에서 발생한 폐액의 재사용을 위한 개선된 처리기술)

  • Kim, Wan-Suk;Kim, Seung-Soo;Kim, Gye-Nam;Park, Uk-Ryang;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.1-6
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    • 2014
  • A large amount of acidic waste solution is generated from the practical electrokinetic decontamination equipments for the remediation of soil contaminated with uranium. After filtration of uranium hydroxides formed by adding CaO into the waste solution, the filtrate was recycled in order to reduce the volume of waste solution. However, when the filtrate was used in an electrokinetic equipment, the low permeability of the filtrate from anode cell to cathode cell due to a high concentration of calcium made several problems such as the weakening of a fabric tamis, the corrosion of electric wire and the adhension of metallic oxides to the surface of cathode electrode. To solve these problems, sulfuric acid was added into the filtrate and calcium in the solution was removed as $CaSO_4$ precipitate. A decontamination test using a small electrokinetic equipment for 20 days indicated that Ca-removed waste solution decreased uranium concentration of the waste soil to 0.35 Bq/g, which is a similar to a decontamination result obtained by distilled water.

산업단지내 독성유기화합물 및 중금속으로 오염된 토양의 정화복원기술 상용화 연구

  • 김수곤;손규동;박지연;최희철;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.31-34
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    • 2004
  • Feasibility of electrokinetic(EK)-Fenton process and Ozone chemical oxidation were investigated for tile removal of organic contaminants and heavy metals from the contaminated soil. In EK-Fenton process, accumulated electroosmotic flow(EOF) was 80 L for 26 days. Removal efficiency of TPH, As, and Ni were 61%, 36%, and 47%, respectively. The concentration of As was high near the anode due to the transport of anionic As toward the anode, while the concentration of Ni was high near the cathode by the movement of cationic Ni to the cathode. Field scale application of in-situ ozonation was carried out for removal of TPH in 3-D test cell (3 m$\times$2 m$\times$2 m). After 25 days of ozone injection, more than 80% of removal rate was observed through the test cell.

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Remediation of Diesel-Contaminated Soil by Electrokinetically Supplied Bacterial Cells

  • 이효상;이기세
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.20-23
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    • 2000
  • The use of electrokinetic injection and transport for the distribution of an NAPLs-degrading microorganism in a sandy soil bed was studied. After the injection of the cell into cathode side of bed, an electric current was applied. The transport of cell though the sandy soil was achieved by electokinetics, mainly by electrophoresis, The pH control in electrode chamber plays un important role to achieve desirable cell transport because H$^{+}$ generated at anode is toxic or inhibits the transport of cells. Electokinetic distribution rate of bacterial cells changed depending on the applied electric current and pH. The degradation of diesel by electrokinetically transport cells were monitored.d.

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동전기 기술과 계면활성제를 이용한 clay에서의 Phenanthrene 제거

  • 박지연;이현호;조현정;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.121-124
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    • 2000
  • In-situ soil remediation using electrokinetics has been investigated and the attempts for the removal of hydrocarbons have been continued. In this study, the electrokinetic remediation using three different kinds of surfactnats was conducted for the removal of phenanthrene from clay The used surfactnats were APG, Brij30 and SDS. In the solubility test for phenanthrene, the experimental result was APG

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Visualization of Electro-osmotic Flow Instability in a T-shape Microchannel (T자형 마이크로 채널 내부 전기삼투 유동의 불안정성 가시화)

  • Han, Su-Dong;Lee, Sang-Joon
    • Journal of the Korean Society of Visualization
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    • v.3 no.2
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    • pp.45-50
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    • 2005
  • Electro-osmotic flow (EOF) instability in a microchannel has been experimentally investigated using a micro-PIV system. The micro-PIV system consisting of a two-head Nd:Yag laser and cooled CCD camera was used to measure instantaneous velocity fields and vorticity contours of the EOF instability in a T-shape glass microchannel. The electrokinetic flow instability occurs in the presence of electric conductivity gradients. Charge accumulation at the interface of conductivity gradients leads to electric body forces, driving the coupled flow and electric field into an unstable dynamics. The threshold electric field above which the flow becomes unstable and rapid mixing occurs is about 1000V/cm. As the electric field increases, the flow pattern becomes unstable and vortical motion is enhanced. This kind of instability is a key factor limiting the robust performance of complex electrokinetic bio-analytical devices, but can also be used for rapid mixing and effective flow control fer micro-scale bio-chips.

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