• 제목/요약/키워드: Electrode volume balance

검색결과 7건 처리시간 0.02초

Optimization of Capacitance Balance for a Hybrid Supercapacitor Consisted of LiMn2O4/AC as a Positive and AC Negative Electrode

  • Cho, Min-Young;Park, Sun-Min;Lee, Jae-Won;Roh, Kwang-Chul
    • Journal of Electrochemical Science and Technology
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    • 제2권3호
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    • pp.152-156
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    • 2011
  • A hybrid supercapacitor is fabricated using a composite material from $LiMn_2O_4$ (LMO) and activated carbon (AC) as the positive electrode and AC as the negative electrode to form the (LMO + AC)/AC system. Volume ratio (positive : negative) of electrodes is controlled to investigate of the power and energy balance. The (LMO + AC)/AC system shows better performances than the LMO/AC system. Especially, electrochemical impedance spectra, rate charge.discharge and cycle performance testing show that the (LMO + AC)/AC system have an outstanding electrochemical performance at volume ratios of (LMO + AC)/AC = 1 : 1.7 and 1 : 2. Electric double layer capacitor (EDLC) capacitance between AC of the positive electrode and AC of the negative electrode improves power density without loss of capacitance. Stable capacitance is achieved by lowering the positive electrode resistance and balancing the energy and power densities between the positive and negative electrodes by the addition of AC to the positive electrode at high current density.

Signal Shapes from a Closed-ended Coaxial HPGe Detector

  • Park, H. D.
    • Nuclear Engineering and Technology
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    • 제29권6호
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    • pp.451-458
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    • 1997
  • Signal shapes from a closed-ended coaxial HPGe detector are investigated by numerical methods. The detector used in this study has a volume of 72 ㎤ with relative efficiency of 15%. The electric field and potential distributions in the detector are determined by solving the Poisson equation at the depletion and operating bias. Hence the time dependent signal shapes induced on the electrode are obtained from the energy balance consideration and tv solving the equation of motion for the charge carriers. For various initial positions of a charge carrier pair, the collection times of induced charge vary in the range of 70 - 404 nsec.

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PBLG와 PBDG의 자격 응답특성에 관한 연구 (A Study on Stimulus Response Characteristic of PBLG and PBDG)

  • 김병근;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.47-50
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    • 2002
  • The displacemant current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitons of $Poly-{\gamma}-benzyl_{L}$ -glutamate (PBLG) and $Poly-{\gamma}-benzyl_{D}$-glutamate(PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBLG and PBDG on the water surface. Also, we measured that compression velocity (30, 40, 50[mm/min]) when the sample spread volume was about 370[ul]-400[ul] and displacement current that occur when differed temperature. From the result, it is known that current is generated in the range of high surface pressures as compression velocity become faster and increase of temperature.

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Poly-$\gamma$-Benzyl D-Glutamine의 자격반응에 관한 연구 (A Study on the Stimulus Reaction of PBDG)

  • 장헌;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 C
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    • pp.1530-1532
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    • 2001
  • The displacement current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitons of Poly-$\gamma$-benzyl p-glutamate (PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. Also, we measured that compression velocity(30, 40, 50[mm/min]) when the sample spread volume was about 400[ul]. From the result, it is known that current is generated in the range of high surface pressures as compression velocity become faster.

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Study on Validity of 1-D Spherical Model on Aqua-plasma Power Estimation With Electrode Structure

  • 윤성영;장윤창;김곤호
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.74-74
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    • 2010
  • The aqua-plasma is the non-thermal plasma in electrical conductive electrolyte by generates the vapor film layer on the immersed metal electrode surface. This plasma can generate the hydroxyl radical by dissociate the water molecule with the plasma electron. To develop the plasma discharge device for high efficiency in the hydroxyl radical generation, proper model for estimation of plasma power is necessary. In this work, the 1-D spherical model was developed, considering temperature dependence material constants. The relation between the plasma power and hydroxyl generation was also studied by the comparison between the optical emission intensity from the hydroxyl radical using monochromator and estimated plasma power. First, the thickness of vapor layer thickness was estimated using the Navier-Stokes fluid equation in order to calculate the discharge E-field inside vapor layer. Using the E-field magnitude and power balance on the plasma generation, it was possible to estimate the plasma power. The plasma power was assumed to uniformly fill the vapor layer and the temperature of vapor layer was fixed in the boiling temperature of electrolyte, 375K. In the experiment, the aqua-plasma was discharged in the saline by applied the voltage on the bipolar electrode. The range of applied voltage was 234 to 280V-rms in the frequency of 380 kHz. Two type electrodes were produced with two ${\Phi}0.2$ tungsten. The plasma power was estimated from the V-I signal from the two high voltage probes and current probe. The estimated plasma power agreed with the profile of emission intensity when the plasma discharged between the metal electrode and vapor layer surface. However, when the plasma discharged between the metal electrodes, the increasing rate of emission intensity was lower than the increase of plasma power. It implies that the surface reaction is more sufficient rather than the volume reaction in the radical generation, due to the high density of water molecule in the liquid.

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방전가공에서 전기적 변화가 갖는 방전 특성에 관한 연구 (A Study for its Characteristics with Electric Variation in an Electrical Discharge Machining)

  • 신근하
    • 한국생산제조학회지
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    • 제6권4호
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    • pp.72-79
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    • 1997
  • A study is a experiment which is figure out to optimum discharge cutting condition of the surface roughness, electronic discharging speed and electrode wear ration with Ton , Toff and V(voltage) as an input condition according to the current(Ip) in an electric spark machine : 1) Electrode is utilized Cu and Graphite. 2) Work piece is used the material of carbon steel. The condition of experiment is : 1) Current is varied 0.7(A) to 50(A) and the time of electric discharging to work piece in each time is 30(min) to 60(min). 2) After the upper side of work piece was measured in radius(5$\mu$m) of stylus analyzed the surface roughness to ade the table and graph of Rmax by yielding data. 3) Electro wear ratio is : \circled1Cooper was measured ex-machining and post-machining by the electronic balance. \circled2The ex-machining of graphite measured by it, the post-machining was found the data from volume $\times$specific gravity and analyzed to made its table and graph on ground the data. 4) In order to keep the accuracy of voltage affected to the work piece was equipped with the A.V. R and the memory scope was sticked to the electric spark machine. 5) In order to preserve the precision of current, to get rid of the noise occured by internal resistance of electric spark machine and to force injecting for the discharge fluid , it made the fixed table for a work piece to minimize the work error by means of one's failure during the electric discharging.

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황동과 금형강의 와이어 컷 방전가공을 통한 가공특성 평가 (Evaluation of Machining Characteristics through Wire-Cut EDM of Brass and SKD 11)

  • 김정석
    • 한국생산제조학회지
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    • 제6권4호
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    • pp.130-137
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    • 1997
  • The demand for wire-cut EDM is increasing rapidly in the die and tool making industry. In this study machining characteristics such as machining rate, surface roughness, hand drum form and hardness of machined material are investigated experimentally under the conditions varing pulse on time, pulse off time, peak voltage, wire tension after fixing other conditions in SKD 11 and brass and brass workpiece. It was found that various operating conditions had significant influences on machining characteristics. But the hardness of workpiece was uneffected by operating conditions. Also it was obtained experimentally that brass workpeice had better machinability than SKD 11 one.dition according to the current(Ip) in an electric spark machine : 1) Electrode is utilized Cu and Graphite. 2) Work piece is used the material of carbon steel. The condition of experiment is : 1) Current is varied 0.7(A) to 50(A) and the time of electric discharging to work piece in each time is 30(min) to 60(min). 2) After the upper side of work piece was measured in radius(5$\mu$m) of stylus analyzed the surface roughness to ade the table and graph of Rmax by yielding data. 3) Electro wear ratio is : \circled1Cooper was measured ex-machining and post-machining by the electronic balance. \circled2The ex-machining of graphite measured by it, the post-machining was found the data from volume $\times$specific gravity and analyzed to made its table and graph on ground the data. 4) In order to keep the accuracy of voltage affected to the work piece was equipped with the A.V. R and the memory scope was sticked to the electric spark machine. 5) In order to preserve the precision of current, to get rid of the noise occured by internal resistance of electric spark machine and to force injecting for the discharge fluid , it made the fixed table for a work piece to minimize the work error by means of one's failure during the electric discharging.

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