• 제목/요약/키워드: Electrode performance.

검색결과 1,673건 처리시간 0.029초

붕소가 도핑된 다이아몬드전극을 이용한 오존발생기의 전기화학적 특성 (Eletrochemical Characteristics of Ozone Generator using Boron-doped Diamond Electrode)

  • 오원균;김규식;;;박수길
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
    • /
    • pp.585-588
    • /
    • 2001
  • Thin. Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system. which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode. experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

  • PDF

Preparation and Comparative Test of Polypyrrole Electrodes for Direct Methanol Fuel Cell

  • Park, Jae-Chan;Kim, Jeong-Soo;Jung, Doo-Hwan
    • Macromolecular Research
    • /
    • 제10권4호
    • /
    • pp.181-186
    • /
    • 2002
  • The displacement of carbon black to polypyrrole as a catalyst supporter in the fuel electrode of a direct methanol fuel cell was investigated. Polypyrrole was obtained as a black powder by the chemical polymerization of pyrrole with three different oxidants. The synthesized polypyrroles were pasted on carbon paper and transformed to the fuel electrodes with electrochemically deposited platinum. The prepared fuel electrode was assembled and mounted in a unit cell using a membrane and cathodic electrode film. In comparison with the carbon black fuel electrode, the performance of the unit cell was analyzed in relation to the state of the catalyst, the type of oxidant, and the morphology of the polypyrrole powder.

붕소가 도핑된 다이아몬드전극을 이용한 오존발생기의 전기화학적 특성 (Eletrochemical Characteristics of Ozone Generator using Boron-doped Diamond Electrode)

  • 오원균;김규식;;;박수길
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
    • /
    • pp.585-588
    • /
    • 2001
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system, which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while PbO$_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

  • PDF

싸이크로스포린을 이용한 고분자막 전위차 전극 (Potentiometric performances of polymer membrane electrode based on cyclosporin)

  • 이인숙
    • 분석과학
    • /
    • 제18권6호
    • /
    • pp.491-494
    • /
    • 2005
  • The main component governing selectivity in ion-selective electrodes and optodes is the ionophore. For this reason, a member of natural products that possess selective ion-binding properties have long been sought after. By applying this principle, the performance of cyclosporin used as neutral carriers for calcium selective polymeric membrane electrode was investigated. The calcium ion-selective electrode based on cyclosporin gave a good Nernstian response of 26.6 mV per decade for calcium ion in the activity range $1{\times}10^{-6}M$ to $1{\times}10^{-2}M$. The optimized calcium ion-selective electrode displayed very comparable selectivity for $Ca^{2+}$ ion against alkali and alkaline earth metal ions, $Na^{2+}$, and $Mg^{2+}$ in particular.

보조전극의 위치에 따른 매설지선의 접지임피던스 측정정확도의 평가 (Evaluation of Measurement Accuracy of Ground Impedances in Counterpoise according to Location of Auxiliary Electrodes)

  • 이복희;최영철;최종혁;김동규;이규선;양순만;김태기
    • 한국조명전기설비학회:학술대회논문집
    • /
    • 한국조명전기설비학회 2009년도 춘계학술대회 논문집
    • /
    • pp.352-355
    • /
    • 2009
  • The ground resistance has been used as a method of estimating the capability of counterpoise. When transient currents blow through a ground electrode, it is reasonable to evaluate the performance of ground electrode system as a ground impedance instead of ground resistance. However, the measurement method of ground impedance for counterpoise is not clearly presented. This paper describes the measurement method of ground impedance considering the earth mutual resistances and AC mutual coupling. When we measure the ground impedance, the error due to earth mutual resistances depends on the distance between the auxiliary electrodes and the electrode under test. The measurement accuracy of high frequency ground impedance is mainly influenced by the location of the current electrode and the potential electrode.

  • PDF

붕소가 도핑된 다이아몬드 전극을 이용한 오존 발생의 효과 및 응용 (Ozone Generation Effect and application using Boron-doped Diamond Electrode)

  • 피영민;;박수길
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
    • /
    • pp.170-172
    • /
    • 2002
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond(BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work, we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

  • PDF

Electrode Materials for Lithium Ion Batteries

  • Chowdari, B.V.R.
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 추계학술발표대회
    • /
    • pp.5-5
    • /
    • 2011
  • Lithium ion batteries are found to have wide range of applications in variety of mobile devices ranging from simple toys to electric vehicles. The performance of these batteries depends on the choice of constituent materials. In this lecture, the materials aspects and perspectives of the electrode batteries will be discussed. Results from some of the specific studies made at speaker's laboratory will be presented.

  • PDF

A Facile Electrochemical Fabrication of Reduced Graphene Oxide-Modified Glassy Carbon Electrode for Simultaneous Detection of Dopamine, Ascorbic Acid, and Uric Acid

  • Yu, Joonhee;Kim, Tae Hyun
    • Journal of Electrochemical Science and Technology
    • /
    • 제8권4호
    • /
    • pp.274-281
    • /
    • 2017
  • This paper describes the simple fabrication of an electrode modified with electrochemically reduced graphene oxide (ERGO) for the simultaneous electrocatalytic detection of dopamine (DA), ascorbic acid (AA), and uric acid (UA). ERGO was formed on a glassy carbon (GC) electrode by the reduction of graphene oxide (GO) using linear sweep voltammetry. The ERGO/GC electrode was formed by subjecting a GO solution ($1mg\;mL^{-1}$ in 0.25 M NaCl) to a linear scan from 0 V to -1.4 V at a scan rate of $20mVs^{-1}$. The ERGO/GC electrode was characterized by Raman spectroscopy, Fourier transform infrared spectroscopy, contact angle measurements, electrochemical impedance spectroscopy, and cyclic voltammetry. The electrochemical performance of the ERGO/GC electrode with respect to the detection of DA, AA, and UA in 0.1 M PBS (pH 7.4) was investigated by differential pulse voltammetry (DPV) and amperometry. The ERGO/GC electrode exhibited three well-separated voltammetric peaks and increased oxidation currents during the DPV measurements, thus allowing for the simultaneous and individual detection of DA, AA, and UA. The detection limits for DA, AA, and UA were found to be 0.46, 77, and $0.31{\mu}M$ respectively, using the amperometric i-t curve technique, with the S/N ratio being 3.

아크방전으로 제조된 나노입자를 이용한 리튬이온전지 음극재료의 연구 (The Research on the Nanoparticles Prepared by Arc-Discharge Method as Anode Materials for Lithium Ion Batteries)

  • 김형조;;김형진;박원조
    • 동력기계공학회지
    • /
    • 제17권1호
    • /
    • pp.104-109
    • /
    • 2013
  • Tin and Tinoxide nanoparticles were prepared by arc-discharge nanopowder process. The negative electrode were fabricated using Tin and Tinoxide nanopower. The microstructure and electrochemistry properties were investigated and compared between Tin and Tinoxide. The oxidation film has microstructure of core/shell type and the shell which was attached around Tin nanoparticle consisted of amorphous $SnO_2$. The shape of Tinoxide nanoparticles was formed with irregular shape in comparison with Tin particle. Initial discharge capcity of Tinoxide electrode possesed about 1000mAh/g, which is about 320mAh/g higher than Tin electrode. Irreversible capacity of Tin electrode is much higher than Tinoxide. The cycle performance of Tinoxide electrode was indicated that is batter than Tin. The Tin negative electrode lost most of capacity after 4 cycle but Tinoxide electrode still retained the capacity. The Tinoxide does show some promise as Li-ion battery anode due to their large reversible capacity at low potentials.

하수슬러지를 기질로 하는 미생물전기분해전지에서 전극간 거리가 메탄 생산에 미치는 영향 (Influence of Electrode Spacing on Methane Production in Microbial Electrolysis Cell Fed with Sewage Sludge)

  • 임성원;안용태;정재우
    • 대한환경공학회지
    • /
    • 제37권12호
    • /
    • pp.682-688
    • /
    • 2015
  • 하수슬러지를 처리하는 미생물전기분해전지(Microbial electrolysis cell, MEC)의 성능에 미치는 전극간 거리의 영향에 관한 실험실 규모 실험을 수행하였다. 각각 다른 전극간 거리(16, 32 mm)를 가진 두 쌍의 전극이 설치된 MEC 반응기가 안정적으로 이루어질 때 전류발생량, 메탄발생량, 메탄수율 등 MEC 성능에 미치는 전극간 거리의 영향을 분석하였다. 전극간 거리가 16 mm일 때, 전류밀도와 메탄발생량은 각각 $3.74A/m^3$$0.616{\sim}0.804Nm^3/m^3$으로 전극간 거리가 32 mm인 조건에서의 $1.50{\sim}1.82A/m^3$$0.529{\sim}0.664Nm^3/m^3$보다 높게 나타났다. COD 및 VSS의 제거효율은 각각 34~40%와 32~38%의 범위를 가지는 것으로 나타났다. 전류밀도가 증가함에 따라 MEC의 생물전기화학적 성능이 향상되어 VSS 감소와 메탄생성이 증가하는 것으로 나타났으며 전류밀도는 VSS 제거효율보다 메탄수율에 상대적으로 큰 영향을 미치는 것으로 나타났다.