• Title/Summary/Keyword: Electrode Distance

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Microstructure of TiO2 sensor electrode on nano block copolymertemplates using an ALD (나노 블록공중합체 템플레이트에 ALD로 제조된 센서용 TiO2 박막의 미세구조 연구)

  • Park, Jong-Sung;Han, Jeung-Jo;Song, Oh-Sung;Jeon, Seung-Min;Kim, Hyeong-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.239-244
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    • 2009
  • We fabricated nano-templates by low temperature BCP(block copolymer) process at 180 $^{\circ}C$, then we deposited 10 nm-thick $TiO_2$ layers with ALD(atomic layer deposition) at low temperature of 150 $^{\circ}C$. Through FE-SEM analysis, we confirmed the successful formation of the groove-type(width of crest : 30 nm, width of trough : 18 nm) and the cylinder-type(diameter : 10 nm, distance between hole : 25 nm) templates. Moreover, after $TiO_2$-ALD processing, we confirmed the deposition of the uniform nano layers of $TiO_2$ on the nano-templates. Through AFM analysis, the pitches of the crest-through(in groove-type) and hole-hole(in cylinder-type) were the same before and after $TiO_2$-ALD processing. In addition, we indirectly determined the existence of the uniform $TiO_2$ layers on nano-templates as the surface roughness decreased drastically. We successfully fabricated nano-template at low temperature and confirmed that the three-dimensional nano-structure for sensor application could be achieved by $TiO_2$-ALD processing at extremely low temperature of 150 $^{\circ}C$.

Optical emission analysis of hybrid air-water discharges

  • Pavel, Kostyuk;Park, J.Y.;Han, S.B.;Koh, H.S.;Gou, B.K.;Lee, H.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.521-522
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    • 2006
  • In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen yield. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates, and point-to-plane electrode gap distance. The primary focus of this experiment was put on the optical emission of the near UV range, with the energy threshold sufficient for water dissociation and excitation. The $OH(A^{2+},'=0\;X^2,"=0$) band's optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. In the gaseous atmosphere saturated with water vapor the OH(A-X) band intensity was relatively high compared to the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. In the gaseous phase discharge phenomenon for Ar carrier gas transformed into a gliding arc via the flow rate growth. OH(A-X) band's intensity increased according to the flow rate or residence time of He feeding gas. Reciprocal tendency was acquired for $N_2$ and Ar carrier gases. The peak value of OH(A-X) intensity was observed in the proximity of the water surface, however in the cases of Ar and $N_2$ with 0.5 SLM flow rate peaks shifted to the region below the water surface. Rotational temperature ($T_{rot}$) was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which corresponds to the arc-like-streamer discharge.

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In situ Structural Investigation of Iron Phthalocyanine Monolayer Adsorbed on Electrode Surface by X-ray Absorption Fine Structure

  • Kim, Seong Hyeon;Toshiaki Ohta;Gang, Gwang Hun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.588-594
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    • 2000
  • Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

Flow-accelerated corrosion assessment for SA106 and SA335 pipes with elbows and welds

  • Kim, Dong-Jin;Kim, Sung-Woo;Lee, Jong Yeon;Kim, Kyung Mo;Oh, Se Beom;Lee, Gyeong Geun;Kim, Jongbeom;Hwang, Seong-Sik;Choi, Min Jae;Lim, Yun Soo;Cho, Sung Hwan;Kim, Hong Pyo
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.3003-3011
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    • 2021
  • A FAC (flow-accelerated corrosion) test was performed for a straight pipe composed of the SA335 Gr P22 and SA106 Gr B (SA106-SA335-SA106) types of steel with welds as a function of the flow rate in the range of 7-12 m/s at 150 ℃ and with DO < 5 ppb at pH levels ranging from 7 to 9.5 up to a cumulative test time of 7200 h using the FAC demonstration test facility. Afterward, the experimental pipe was examined destructively to investigate opposite effects as well as entrance effects. In addition, the FAC rate obtained using a pipe specimen with a 50 mm inner diameter was compared with the rate obtained from a rotating cylindrical electrode. The effects of the complicated fluid flows at the elbow and orifice of the pipeline were also evaluated using another test section designed to examine the independent effects of the orifice and the elbow depending on the distance and the combined effects on orifice and elbow. The tests were performed under the following conditions: 130-150 ℃, DO < 5 ppb, pH 7 and a flow rate of 3 m/s. The FAC rate was determined using the thickness change obtained from commercial room-temperature ultrasonic testing (UT).

Failure analysis of capacitor for sub-module in HVDC (HVDC 서브모듈용 커패시터의 고장 분석)

  • Kang, Feel-soon;Song, Sung-Geun
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.941-947
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    • 2018
  • In general, capacitors have a large influence on the life of the system due to frequent charging and discharging. In this paper, we analyze the cause of the core failure of high voltage, high current HVDC sub-module film capacitor and analyze the precautions of the capacitor design and manufacturing process. First, the cause of the fault, the failure mode, and the effect are analyzed through the FMEA of the capacitor. To quantitatively evaluate the causes and effects of faults that have the greatest effect on the failure of a capacitor, a fault tree for the capacitor is presented and the failure rate is analyzed according to the design parameters and the driving conditions. It is verified that the main cause of capacitor failure is the capacitance change, and it is necessary to minimize the temperature rise, corona occurrence, electrode expansion, and insulation distance decrease during capacitor design and manufacturing process in order to reduce the failure rate of the capacitor.

Development of an ionic wind dust collector towards coronavirus reduction in subway stations (지하철 역사 내 코로나 바이러스 저감을 위한 이온풍 집진기 개발)

  • Shin, Dongho;Kim, Younghun;Han, Bangwoo
    • Particle and aerosol research
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    • v.18 no.1
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    • pp.1-8
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    • 2022
  • Since 2019, the corona virus has been continuously affect human life. In particular, in the indoor space where people live, infection by airborne transmission of viruses is a problem. Among them, the spread in the subway, which is the main mode of transport for humans, can be serious. To solve this problem, our research team developed an ionic wind collector to collect and remove corona virus using an ionic wind collector and ozone. In order to apply the ionic wind collector to the subway, it must operate in two modes. Because large amounts of ozone are harmful to the human body. There is a mode that collects bio-aerosol from the air using ionic wind and a mode that inactivates viruses floating in the air by generating a large amount of ozone. As the applied voltage increased, the cleaning ability of the ionic wind collector increased, and the farther the distance between the discharge electrode and the ground plate, the higher the cleaning ability even at low current. In addition, clean air delivery rate (CADR) of an ionic wind collector was up to 5.5 m3/min. As a result of measuring the amount of ozone generated, it was confirmed that 50 ppb to 250 ppb was generated, and it was confirmed that ozone generation was controllable in the ionic wind dust collector.

Technical Evaluation of Engineering Model of Ultra-Small Transmitter Mounted on Sweetpotato Hornworm

  • Nakajima, Isao;Muraki, Yoshiya;Mitsuhashi, Kokuryo;Juzoji, Hiroshi;Yagi, Yukako
    • Journal of Multimedia Information System
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    • v.9 no.2
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    • pp.145-154
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    • 2022
  • The authors are making a prototype flexible board of a radio-frequency transmitter for measuring an electromyogram (EMG) of a flying moth and plan to apply for an experimental station license from the Ministry of Internal Affairs and Communications of Japan in the summer of 2022. The goal is to create a continuous low-dose exposure standard that incorporates scientific and physiological functional assessments to replace the current standard based on lethal dose 50. This paper describes the technical evaluation of the hardware. The signal of a bipolar EMG electrode is amplified by an operational amplifier. This potential is added to a voltage-controlled crystal oscillator (27 MHz, bandwidth: 4 kHz), frequency-converted, and transmitted from an antenna about 10 cm long (diameter: 0.03 mm). The power source is a 1.55-V wristwatch battery that has a total weight of about 0.3 g (one dry battery and analog circuit) and an expected operating time of 20 minutes. The output power is -7 dBm and the effective isotropic radiated power is -40 dBm. The signal is received by a dual-whip antenna (2.15 dBi) at a distance of about 100 m from the moth. The link margin of the communication circuit is above 30 dB within 100 m. The concepts of this hardware and the measurement data are presented in this paper. This will be the first biological data transmission from a moth with an official license. In future, this telemetry system will improve the detection of physiological abnormalities of moths.

Development of class I surge protection device for the protection of offshore wind turbines from direct lightning (해상풍력발전기 직격뢰 보호용 1등급 바리스터 개발)

  • Geon Hui Lee;Jae Hyun Park;Kyung Jin Jung;Sung-Man Kang;Seung-Kyu Choi;Jeong Min Woo
    • Journal of Wind Energy
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    • v.14 no.4
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    • pp.50-56
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    • 2023
  • With the abnormal weather phenomena caused by global warming, the frequency and intensity of lightning strikes are increasing, and lightning accidents are becoming one of the biggest causes of failures and accidents in offshore wind turbines. In order to secure generator operation reliability, effective and practical measures are needed to reduce lightning damage. Because offshore wind turbines are tall structures installed at sea, the possibility of direct lightning strikes is very high compared to other structures, and the role of surge protection devices to minimize damage to the electrical and electronic circuits inside the wind turbine is very important. In this study, a varistor, which is a key element for a class 1 surge protection device for direct lightning protection, was developed. The current density was improved by changing the varistor composition, and the distance between the electrode located on the varistor surface and the edge of the varistor was optimized through a simulation program to improve the fabrication process. Considering the combined effects of heat distribution, electric field distribution, and current density on the optimized varistor surface, silver electrodes were formed with a gap of 0.5 mm. The varistor developed in this study was confirmed to have an energy tolerance of 10/350 ㎲, 50kA, which is a representative direct lightning current waveform, and good protection characteristics with a limiting voltage of 2 kV or less.

Studies on the Transport of Acetic Acid by Electrodialysis (전기투석에 의한 초산의 이동특성 연구)

  • 최동민;구윤모
    • KSBB Journal
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    • v.11 no.3
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    • pp.360-366
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    • 1996
  • Electrodialysis of acetic acid was studied to find out the trend of the transport of organic acids through ultrafiltration and ion exchange membranes. The net transport rate of acetic acid was determined from the electro-migration velocity relative to the electro-osmotic flow rate through the membrane. Electro-osmosis flows through ultrafiltration membranes were from the anodic side to the cathodic side in the presence of electric field. The surface of ultrafiltration membrane was measured by the electro-osmotic flow to be charged negatively. Different transport behaviors of acetic acid were found with the ultrafiltration membranes of different materials. In general, regenerated cellulose membranes (YM series) were more effective than polysulfone membranes (PM series) for the transport of acetic acid. The transport of acetic acid was affected by electric strength, distance between the electrodes, surface area of electrode, temperature, and pore size of membrane. The transport rate through the ion exchange membrane was 1.5 to 3 times of those through the ultrafiltration membranes at the constant current of 150 mA in the experimental ranges. The transport rate of acetic acid through the ion exchange membrane increased by 10% with a pulse electric field of 10 sec/hr.

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Operational Characteristics of a Dry Electrostatic Precipitator for Removal of Particles from Oxy Fuel Combustion (순산소 연소 배출 입자 제거용 건식 전기집진장치 운전 특성)

  • Kim, Hak-Joon;Han, Bang-Woo;Oh, Won-Seok;Hwang, Gyu-Dong;Kim, Yong-Jin;Hong, Jeong-Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.1
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    • pp.27-34
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    • 2010
  • In a test duct with closed configuration, particle removal performance of an edge-plate type electrostatic precipitator (ESP) was evaluated at a high flow rate in $CO_2$ rich environments by changing gap distances between collection plates, concentrations of $CO_2$, particle sizes, types of electrodes, and types of power supplies. At the same experimental conditions, collection efficiency of particles with the mean particle size, 300 nm, decreased as the gap distance and $CO_2$ concentration increased because of low electrostatic force and low discharged current. In addition, as the particle size increased, the efficiency increased because of high charging rate of the large particles. With the electrode type which has higher surface area of a discharging plate and with the power supply which applied 25 kHz-pulsed DC voltages, the removal efficiency was high even in rich $CO_2$ condition due to high electrostatic force at the same power consumption.