• Title/Summary/Keyword: Electroactive material

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Development of Modeling and control Methods for Multi-DOF dielectric polymer actuator

  • Jung, M.Y.;Jung, K.M.;Koo, J.C.;Choi, H.R.;Nam, J.D.;Lee, Y.K.
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1225-1228
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    • 2004
  • Principles and mechanism of energy transduction of dielectric polymer materials are well known from the various smart material related publications. However their introduction to industrial actuator applications is limited mainly due to difficulties guarantee controllability and reliability. Most of the previous publications have elaborates energy transduction physics of chunk of polymer while development of construction methods for feasible actuators made of the material is rarely proposed. In the present article, a conceptual design of multi-DOF linear polymer actuator construction that is to be controllable with moderate level of control work os introduced. In addition, numerical models that are developed with a unified energy based approach are presented not only for basic working mechanism analysis of the polymetric soft actuator but for providing analytical foundation to expend the concept toward design of multi-DOF actuator controls.

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Unique Photoluminescence Property of a Novel POSS-based Material Having Carbazole

  • Imae, Ichiro;Kawakami, Yusuke;Fujikawa, Youhei;Ooyama, Yousuke;Harima, Yutaka
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.234-234
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    • 2006
  • Novel molecular glassy POSS-based material having carbazole moiety as a photo- and electroactive group was synthesized, and its thermal, morphological, electrochemical, and optical properties were investigated. POSS having carbazole (POSS-Cz) was found to form easily amorphous glassy film by cooling the melt sample or by spin coasting onto glass substrate. POSS-Cz showed monomeric emission even in solid film, which suggests that carbazole moiety can be isolated even in solid state.

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Modeling of Antagonistically Driven Polymer Actuator (대칭구동 원리에 의한 폴리머 액추에이터의 모델링)

  • 정민영;정광목;최혁렬;남재도;이영관;구자춘
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.11
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    • pp.1000-1005
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    • 2004
  • Many different polymeric materials are introduced fur the alternative solutions of electro-mechanical actuators. Although light weight and grate flexibility of the material deserves notable attention from enormous publications, few of the publication has discussed feasibility study for actual industrial applications. Most of the previous work demonstrated plain movement of the material without delineating any design concept that guarantees 'controllable action'. The present work introduces a noble design concept that provides controllable action and the concept is verified through a modeling and a simulation of the actuation method.

Detection of Bio-chemical by Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드 전극을 이용한 생체화학물질의 검출)

  • Kim, Gyu-Sik;Einaga, Y.;Fujishima, A.;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.569-572
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    • 2001
  • Selective. highly stable determination of epinephrine(adrenalin) was achieved in cyclic voltammetric measurement carried out at electrochemically treated conductive boron-doped diamond electrode. Boron-doped diamond electrodes were prepared on single crystal Si wafers by microwave plasma chemical vapor deposition and $B_{2}O_{3}$ was dissolved in acetone/methanol(9:1) mixture solution so that the B/C weight ratio ca. $10^{4}ppm$. Epinephrine is a kind of catecholamines, which secreted from adrenal marrow cells. The serious problem to detection of epinephrine is the interference phenomena of electroactive constituent. including AA. In this study. electrochemical treatment of BDD was carried out to discriminate between epinephrine and AA responses. Experimental results showed that the peak potential of AA oxidation shift to the positive direction and the oxidation peak of epinephrine was unchanged. The effect of electrochemical treatment was maintained up to 40hrs.

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Manufacturing of 2025 Coin Type PAn/Li-Al Secondary Battery (2025 Coin형 PAn/Li-Al 2차전지의 제조)

  • Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.202-206
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    • 1990
  • The existing batteries such as lead acid battery and Nicad battery have been at serious issue, because heavy metal such as Pb and Cd give rise to environmental pollution. Therefor, when these material is changed over polymeric electroactive material, we expect environmental pollution will be prevented. We decided to develop 2025 coin type PAn/Li-Al secondary battery for goal of memory back-up battery. This report is concerned with manufacturing of 2025 coin type PAn/Li -Al secondary battery.

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The First Discharge Characteristics of PAn/Li-Al Secondary Battery (PAn/Li-Al 2차전지의 초기방전특성)

  • Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.207-210
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    • 1990
  • The purpose of this study is to research and develop polymer secondary battery. This paper describes the first discharge characteristics of PAn/Li-Al secondary battery. PAn was prepared in $HBF_4$ aqueous solution by galvanostatic electropolymerization and then used as cathode active material. PAn/Li-Al secondary battery was prepared in 2025 coin type. Characteristics of this battery are summarized as follows. ${\bullet}$ Open curcuit voltage and discharge end voltage was 3.5V and 2.9V, respectively. ${\bullet}$ The ratio of electricities in discharge to theoretical electricities in all undoping of PAn cathode was 56% at constant current discharge of 1mA. ${\bullet}$ The capacity density, energy density and maximum power density per weight of PAn electroactive material were 56.1Ah/kg, 168.4Wh/kg and 16.9kW/kg, respectively.

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Detection of Bio-chemical by Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드 전극을 이용한 생계화학물질의 검출)

  • ;榮長 泰明;藤嶋 昭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.569-572
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    • 2001
  • Selective, highly stable determination of epinephrine(adrenalin) was achieved in cyclic voltammetric measurement carried out at electrochemically treated conductive boron-doped diamond electrode. Boron-doped diamond electrodes were prepared on single crystal Si wafers by microwave plasma chemical vapor deposition and B$_2$O$_3$ was dissolved in acetone/methanol(1:1) mixture solution so that the B/C weight ratio ca. 10$^3$ppm.. Epinephrine is a kind of catecholamines, which secreted from adrenal marrow cells. The serious problem to detection of epinephrine is the interference phenomena of electroactive constituent, including AA. In this study, electrochemical treatment of BDD was carried out to discriminate between epinephrine and AA responses. Experimental results showed that the peak potential of AA oxidation shift to the positive direction and the oxidation peak of epinephrine was unchanged. The effect of electrochemical treatment was maintained up to 40hrs.

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A study on the Spinel phase cathode materials with high capacity for lithium secondary batteries (리튬 2차 전지용 고용량 스피넬계 양극물질 연구)

  • Hong, Ki-Joo;Sun, Yang-Kook
    • Proceedings of the KIEE Conference
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    • 2001.11b
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    • pp.106-108
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    • 2001
  • As 3V cathode material, a new doping spinel material, LiMn1.6Se0.4O4 powder with a phase-pure polycrystalline was synthesized by a sol-gel method. In spite of Jahn-teller distortion in 3V region($2.4{\sim}3.5V$), the LiMn1.6Se0.4O4 electrode shows no capacity loss. The material in the 3V region initially delivers a discharge capacity of 100mAh/g which increase with cycling to reach 105mAh/g after 90cycles. And 5V cathode material LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) compounds have been synthesized by sol-gel method. a series of electroactive spinel compounds, LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) has been studied by crystallographic and electrochemical methods. The material presents only one plateau at around 4.5 V vs. Li/Li+ with a large discharge capacity of 152mAh/g and fairly good cyclability.

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Improvement of Mechanical Properties of IPMC through Developing a Degree of Dispersion of SWCNT/Nafion Composite (SWCNT/Nafion 복합체의 분산능 향상을 통한 IPMC의 기계적 특성 향상)

  • Kwon, Hui-June;Kim, Ha-Na;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.131-136
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    • 2011
  • Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

SDRE controller considering Multi Observer applied to nonlinear IPMC model

  • Bernat, Jakub;Kolota, Jakub;Stepien, Slawomir
    • Smart Structures and Systems
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    • v.20 no.1
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    • pp.1-10
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    • 2017
  • Ionic Polymer Metal Composite (IPMC) is an electroactive polymer (EAP) and a promising candidate actuator for various potential applications mainly due to its flexible, low voltage/power requirements, small and compact design, and lack of moving parts. Although widely used in industry, this material requires accurate numerical models and knowledge of optimal control methods. This paper presents State-Dependent Riccati Equation (SDRE) approach as one of rapidly emerging methodologies for designing nonlinear controllers. Additionally, the present paper describes a novel method of Multi HGO Observer design. In the proposed design, the calculated position of the IPMC strip accurately tracks the target position, which is illustrated by the experiments. Numerical results and comparison with experimental data are presented and the effectiveness of the proposed control strategy is verified in experiments.