• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.165-165
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• 2006

We prepared nonlinear optical (NLO) polymers possessing thermal and temporal stability, which were based on the polyimides appended with NLO chromophores. NLO chromophores with a terminal hydroxyl group have been synthesized by coupling between aminobenzene or julolidine donor and phenylene bridge, and then subsequent coupling between the resulting product and tricyanofuran acceptor. The chromophores were chemically bonded to the polyimides backbone through Mitsunobu reaction. The NLO polymers showed $160-170^{\circ}C$ of Tgs and were thermally stable up to $200^{\circ}C$. We obtained optical quality films by spincoating and evaluated their electro-optical properties and temporal stability.

• Bulletin of the Korean Chemical Society
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• v.23 no.7
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• pp.964-970
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• 2002

We synthesized three kinds of chromophores incorporating aromatic quinoline unit as a $\pi-conjugated$ bridge in order to prepare more thermally stable nonlinear optical (NLO) chromophores than general stilbene unit. The NLO poly(methylmethacrylate) copolymer, polyimides, and polyester were successfully synthesized by these corresponding quinoline-based monomers. Their physical and optical properties were investigated by thermogravimetry, gel permeation chromatography, ultraviolet-visible spectroscopy, second harmonic generation (SHG) and electro-optic (EO) measurement. All the polymers exhibited better thermal stability,however their NLO activity was a little lower than that of general stilbene-based NLO polymers. Among three kinds of polymers, the PMMA copolymer with quinoline chromophores had the largest SHG coefficient d33 value of 27 pm/V (at 1.064 $\mu\textrm{m})$ and EO coefficient r33 value of 6.8 pm/V (at 1.3 $\mu\textrm{m}$).

• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.843-846
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• 1992

This thesis was investigated on optical-and ion-induced characteristics in positive(a-$Se_{75}Ge_{25}$) and negative (Ag/a-$Se_{75}Ge_{25}$) resists for focused-ion-beam microlithogaphy. The a-$Se_{75}Ge_{25}$ inorganic thin film shows an increase in optical absorption after exposure to$\sim$$10^{16}$ dose(ions/$cm^{2}$) of Ga ions. The observed shift in the absorption edge toward longer wavelengths is consistent with that in films exposed to band-gap photons ($\sim$$10^{20}$ photons/$cm^{2}$). But, ion induced shift is twice as much as that in film exposed to optical radiation. This result may be related with microstructural rearrangements with in the short range of SeGe network. Due to changes in the short range order, the chemical bonding may be affected, which results in increased chemical dissolution in ion-induced film. Also, this resist exhibits good thermal stability because of its high Tg(~220$^{\circ}C$). The composition of deposited film measured by AES is consistent with that of bulk.

• Journal of Sensor Science and Technology
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• v.7 no.1
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• pp.23-30
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• 1998

In this paper, we analyzed the effect of the time delay of the image sensor in the tracking loop of Electro-Optical Tracking System(EOTS). we showed that Smith predictor can greatly improve the stability and various performances of EOTS with time delay. And also, to verify the realistic validity, we executed the experiment in EOTS recently developed, and confirmed the effectiveness in EOTS.

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.225-228
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• 2005

Telescope structure based on Korsch type optical layout was suggested for a large aperture optical system. Korsch type optical layout is regarded as providing wide field of view and no color aberration for which high resolution space cameras greatly demand. For the suggested Korsch type telescope structure, two folding mirrors are adopted, firstly to provide for the refocusing device mounting plane on the second fold mirror assembly, secondly by double folding the light path to concisely confine focal plane assembly within the perimeter of the tube. Optical layput design and corresponding support structure design were attained.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.05a
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• pp.177-180
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• 2005

We have investigated electro-optical characteristics in three kinds of TN cells on the polyimide surface. Transmittance of no thermal stressed TN cells were better than that of thermal stressed TN cells. Also. the threshold voltage and the response time of thermal stressed TN cells were same that of no thermal stressed TN cells. There were little change of value in these TN cells. On the other hand. transmittances of TN cells on the polyimide surface decreased by increasing thermal stress time. Moreover. the residual DC of the thermal stressed TN cells on the polyimide surface showed the characteristics of thermal stressed TN cells were weakened as increasing thermal stress temperature and time. Therefore. thermal stability of TN cells were decreased gradually by giving high thermal stress for a long time.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.271-272
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• 2005

We studied liquid crystal (LC) alignment with ion beam (IB) on polyimide and electro-optical characteristics of twisted nematic (TN)-liquid crystal display (LCD) on the polyimide surface using obliquely ion beam exposure. A good uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the polyimide surface was observed. In addition, it can be achieved the good EO properties, and residual DC property of the ion-beam-aligned TN-LCD on polyimide surface.

• Macromolecular Research
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• v.15 no.1
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• pp.59-64
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• 2007

Star-shaped, nonlinear optical (NLO) material was synthesized and its optical, thermal, and electro-optic properties were investigated. Three NLO-active dipolar chromophores containing a phenylene ring substituted with a bulky alkyl chain as a conjugation bridge were chemically bonded to the core of 1,1,1-tris(4-hydroxyphenyl)ethane to form a dendritic architecture. The chemical structure and purity of the chromophore were verified by NMR spectroscopy. The chromophore exhibited a broad absorption band centered at around 608 nm tailing up to 760 nm in toluene solution and also showed a discernible solvatochromic shift in more polar solvent. The chloroform solution of the dendrimer produced an absorption band with a red-shifted maximum as large as 28 nm when compared to that of the toluene solution. It was thermally stable up to $275^{\circ}C$ in a nitrogen atmosphere and had a glass transition temperature of $76^{\circ}C$. In a preliminary result, the polymer film containing the dendritic compound exhibited a shift of 19 pm/V taken at $1.55{\mu}$.

• Korean Journal of Optics and Photonics
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• v.9 no.4
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• pp.215-220
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• 1998

We proposed an in situ measurement set-up and technique to measure the various electro-optic(E-O) properties of the E-O polymer. Using the proposed measurement set-up, the electro-optic effect and birefringence of unpoled side-chain E-O polymer induced by the strong dc and ac electric field were observed. The dependence of the E-O coefficients on the various poling conditions were measured with real time. To evaluate the thermal stability of the poled polymer the relaxation of the E-O effect was measured and the result was compared with well known polymer materials. The proposed measurement reduces the number of experimental steps and saves measurement time.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.1 s.94
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• pp.3-11
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• 2005

For monitoring of the civil and building structure, optical fiber sensors are very convenient. The fiber sensors are very small and do not disturb the structural properties. They also have several merits such as electro-magnetic immunity, long signal transmission, good accuracy and multiplexibility in one sensor line. Strain measurement technologies with fiber optic sensors have been investigated as a part of smart structure. In this paper, we investigated the possibilities of fiber optic sensor application to the monitoring of beam-column joints of structures. We expect that the fiber optic sensors replace electrical strain gauges. The commercial electric strain gauges show good stability and dominate the strain measurement market. However, they lack durability and long term stability for continuous monitoring of the structures. In order to apply the strain gauges, we only have to attach them to the surfaces of the structures. In this paper, we investigate the possibility of using fiber optic Bragg grating sensors to joint structure. The sensors show nice response to the structural behavior of the joint.