• Journal of Welding and Joining
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• v.17 no.2
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• pp.76-83
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• 1999

Fracture toughness({TEX}$J_{IC}${/TEX}) on 304 austenitic stainless steel weldments artificially degraded for long period under SCC environments were evaluated to investigate its reliability and environmental characteristics. Electro-chemical polarization tests were previously carried out to evaluate corrosion susceptiblility of weldment, and stress corrosion cracking was tested under various conditions of 3.5wt.% NaCl solution, the temperature of $25^{\circ}$C and $95^{\circ}$C, and oxygen concentration during 3000hours. From the results obtained, it was found that 304 stainless steel weldment was so susceptible under high temperature and high oxygen concentration of 3.5wt.% NaCl solution, and fracture toughness({TEX}$J_{IC}${/TEX}) was also considerably reduced by material degradation.

• Journal of Mechanical Science and Technology
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• v.18 no.1
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• pp.114-121
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• 2004

In order to investigate the corrosion fatigue characteristics in the weld of multi-pass welded A 106 Gr B steel pipe, corrosion fatigue tests were performed under the various stress ratios and 3.5 wt% NaCl solution at room temperature. The corrosion fatigue characteristic curves were represented using crack closure concept. The obtained results are as follows : when the load frequency is 1.0 Hz, the crack opening point is transited in the region of $K_{max}$=20∼32 MPaㆍ $m^{1}$2/. In the low stress intensity factor range, the crack opening point is higher than that in air. However, in the high stress intensity factor range, it is lower than that in air. In the cases of 0.1 Hz and 0.01 Hz, the crack opening point gradually decreases to $K_{min}$ with $K_{max}$ increase.rease.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.603-612
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• 2000

Corrosion characteristics on the 12Cr alloy steel of turbine blade was electro-chemically investigated in 3.5wt% NaCI and 12.7wt% Na2S04 solution, respectively. Electro-chemical polarization test, Huey test and Oxalic acid etching test were previously conducted to estimate corrosion susceptibility of the material. And, using the horizontal corrosion fatigue tester, corrosion fatigue characteristics of 12Cr alloy steel in distilled water, 3.5wt% NaCI solution, and 12.7wt%(1M) Na2S04 solution were also fracture-mechanically estimated and compared their results. Parameter considered was room temperature, 60'C and 90'C. Corrosion fatigue crack length was measured by DC potential difference method.Obtained results are as follows,1) 12Cr alloy steel showed high corrosion rate in 3.5wt% NaCI solution and Na2S04 solution at high tempratue.2) Intergranular corrosion sensitivity of 12 Cr alloy was smaller than austenitic stainless steel.3) Corrosion fatigue crack growth rate in 3.5wt% NaCI and 12.7wt%(IM) Na2S04 solution is entirely higher than in the distilled water, and also increased with the temperature increase.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.34 no.1
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• pp.30-36
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• 1998

Recently, with rapid increase of gas demand, there occurs much interest their security of safety in the gas storage tanks and pressure vessels etc. In order to solve the problems, the occurrence of corrosion fatigue crack and the propagation behavior must be investigated. Especially the occurrence of corrosion fatigue crack and the propagation behavior in the part which has concentrated stress or defects, must be studied more carefully. In this paper, the high-tensile steel of SPV 50 which is much used for building the LPG storage tanks was tested by the use of a plane bending corrosion fatigue tester under the various marine environments and in the air. These experiments were done to investigate the corrosion fatigue crack propagation behavior, the variation of aspect ratio for part through crack and electro-chemical characteristics of the metal. The main results obtained are as follows ; 1. Comparing the same surface crack length with the crack depth, the crack depth toward the thickness of specimen in air propagated faster than that in corrosion environment. 2. The aspect variation of the half elliptical crack can be estimated as following equation; b/a=i-jb/t where a : surface crack length, b : crack depth, t : specimen thickness, i,j : experimental constants but the slope j is decreased as specific resistance decreases. 3. As the specific resistance of corrosion environment decrease or the corrosion fatigue crack propagates, the corrosion potential become less noble.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.19 no.4
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• pp.320-328
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• 2007

The durability of marine concrete structures is severely degraded by corrosion due to seawater attack and diffusion of chloride in concrete. The deduction of durability causes high repair cost for maintenance of marine concrete structure. So, the applicability of high-durable materials is investigated to improve the durability in marine concrete structures. For these, the characteristics of corrosion prevention of marine concrete structures mixed with the mineral admixtures(SF, FA and BFS), the modified steel(stainless and coating steel), and corrosion inhibitors are evaluated using electro-chemical methods. As a results of this study, it is quantified for the effect of promotion of durability by high-durability materials in marine concrete structures.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.412-412
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• 2008

ENIG(Electroless Nickel Immersion Gold)is a surface treatment method that is used most widely at fine pitch's SMT and BGA packaging process. ENIG has good diffusion barrier of Ni against solder and good wettability due to Au finish. But when the discoloration occurred on the Au finish of ENIG, some key characteristics related to the quality and reliability of PCB such as bondability, solderability and electrical flowing of packaging process could be deteriorated. In this paper, we have performed the water dip test ($88^{\circ}C$ purified water) which accelerates the galvanic corrosion of Ni diffused from the Ni-P layer. That is, the excessive oxidation of the Ni layer could result in non-wetting of the solder because the flux may not be able to remove excessive oxides. Though Au discoloration have been reported to be caused by Ni oxides in many literature, it is still open to verify and discuss The microstructures and chemical compositions have been investigated using FE-SEM, TEM, FIB, EDS and XPS. As a result, authors have found that the Au discoloration in ENIG type is severely caused by the oxidation of the Ni and the mechanism of Au discoloration can be confirmed through the experiment result of water dip test.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.25 no.2
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• pp.87-104
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• 1989

Recently, with the tendency of more lightening, high-strength and high-speed in the marine industries such as marine structures, ships and chemical plants, the use of the aluminium Alloy is rapidly enlarge and there occurs much interest in the study of corrosion fatigue crack characteristics. In this paper, the initiation of surface crack and the propagation characteristics on the base metal and weld zone of 5086-H116 Aluminium Alloy Plate which is one of the Al-Mg serious alloy(A5000serious) used most when building the special vessels, were investigated by the plane bending corrosion fatigue under the environments of marine, air and applying cathodic protection. The effects of various specific resistances on the initiation, propagation behavior of corrosion fatigue crack and corrosion fatigue life in the base metal and heat affected zone were examined and its corrosion sensitivity was quantitatively obtained. The effects of corrosion on the crack depth in relation to the uniform surface crack length were also investigated. Also, the structural, mechanical and electro-chemical characteristics of the metal at the weld zone were inspected to verify the reasons of crack propagation behavior in the corrosion fatigue fracture. In addition, the effect of cathodic protection in the fracture surface of weld zone was examined fractographically by Scanning Electron Microscope(S.E.M.). The main results obtained are as follows; (1) The initial corrosion fatigue crack sensitibity under specific resistance of 25Ω.cm% show 2.22 in the base metal and 19.6 in the HEZ, and the sensitivity decreases as specific resistance increases (2) By removing reinforcement of weldment, the initiation and propagation of corrosion crack in the HAZ are delayed, and corrosion fatigue life increases. (3) As specific resistance decreases, the sensitivity difference of corrosion fatigue life in the base metal and HAZ is more susceptible than that of intial corrosion fatigue crack. (4) Experimental constant, m(Paris' rule) in the marine environment is in the range of about 3.69 to 4.26, and as specific resistance increases, thje magnitude of experimental constant, also increases and the effect by corrosion decreases. (5) Comparing surface crack length with crack depth, the crack depth toward the thickness of specimen in air is more deeply propagated than that in corrosion environment. (6) The propagation particulars of corrosion fatigue crack for HAZ under initial stress intensity factor range of $\Delta$k sub(li) =27.2kgf.mm super(-3/2) and stress ratio of R=0 shows the retardative phenomenon of crack propagation by the plastic deformation at crack tip. (7) Number of stress cycles to corrosion fatigue crack initiation of the base metal and the welding heat affected zone are delayed by the cathodic protection under the natural sea water. The cathodic protection effect for corrosion fatigue crack initiation is eminent when the protection potential is -1100 mV(SCE). (8) When the protection potential E=-1100 mV(SCE), the corrosion fatigue crack propagation of welding heat affected zone is more rapid than that of the case without protection, because of the microfissure caused by welding heat cycle.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.6
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• pp.996-1003
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• 2001

In order to investigate the fatigue fracture characteristics by corrosion degradation of 12Cr alloy steel, both the fatigue characteristics in air of them artificially degraded during long period and the corrosion fatigue characteristics were experimentally evaluated in various environments which were determined from electro-chemical polarization tests. And also, their fracture mechanisms were analyzed and compared, fractographyically. From their results, the fracture mechanical characteristics of it artificially degraded during long period in the distilled water, 3.5 wt.% NaCl solution and 12.7wt.%(1M) Na$_2$SO$_4$solution of 25, 60 and 90$\^{C}$ did not show distinguishable difference comparing with non-corroded one in regardless of temperature and degradation period. It means that degradation of the material by just surface corrosion does not remarkably affect to fatigue crack growth. On the other hand, the crack growth rates by corrosion fatigue increased due to activity increase of corrosive factors such as OH(sub)-,Cl(sup)- and SO$_4$(sup)- at the crack tip with temperature increase. Therefore, the crack growth rates by corrosion fatigue were more faster than that in air of the artificially degraded specimen due to the such difference of crack growth mechanism.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.2
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• pp.75-81
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• 2010

In this study, when concrete properties are changed by concrete mix proportions or blending of admixtures, the characteristics of electro-chemical method for corrosion assessment of the embedded steel are compared and its causes are analyzed. According to the results, when the ratio of corroding area was less than 10%, the half-cell method was affected by concrete properties. In the case of specimen blended admixtures, it is possible to assess the high-corroded steel qualitatively using the half-cell method. For the polarization resistance method, though the corroding area was less than 10%, it has not affected by concrete properties. However, in case of specimen blended admixtures, the corrosion level of steel was underestimated than OPC specimens having a similar corroding area.

• Journal of the Korea Concrete Institute
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• v.21 no.5
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• pp.565-572
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• 2009

In this study, corrosion resistance of palm oil fuel ash (POFA) concrete as a blended concrete is evaluated by using electrochemical technique. The POFA is an industrial byproduct obtained from fuel ash after extracting palm oil from palm-tree. In order to obtain basic material characteristics of the POFA concrete, tests on compressive strength, slump, weight loss, bleeding and expansion ratio were carried out the early-aged POFA concrete. On the other hand, durability characteristics, both chloride penetration and carbonation depth test, were also conducted. Finally, corrosion resistance were evaluated by applying electro-chemical artificial crack healing technique, and the tests on the impressed voltage characteristic, galvanic current and linear polarization resistance. From the experimental results, it was found that long-term strength, bleeding, lower slump ratio, expansion ratio, chloride penetration, carbonation and corrosion resistance were improved by using the POFA due to activated pozzolanic reaction. It can be also mentioned that POFA concrete has a potential to be used as a cementitious binder for green-recycling resources.