• 제목/요약/키워드: Electrical corrosion

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Application of Ni-P-PTFE Coatings for Preventing Fretting Corrosion (마찰부식 방지를 위한 Ni-P-PTFE 코팅의 적용)

  • Hong, Jin-Won;Lee, Keun-Woo;Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.16 no.7
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    • pp.430-434
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    • 2006
  • Au/Ni coatings are widely used in the electrical interconnect system, such as connectors, sockets and wire crimps. But due to repeated mechanical contacts, fretting corrosion occurs and causes a rapid increase in resistance. As an attempt to resolve these problem, application of Ni-P-PTFE to replace Ni undercoats was proposed, for which basic materials properties of Ni-P-PTFE coatings for preventing fretting corrosion was examined in this study. The Ni-P-PTFE coatings were formed by electroless Ni plating and PTFE coating followed by the heat-treatment. PTFE particles were found to be uniformly distributed in the Ni-P matrix. The Ni-P-PTFE coatings showed the excellent anti-adherent property with the contact angle of $104.3^{\circ}$, microhardness of 144.3 Hv comparable to that of Ni-P, and electric conductivity equivalent to that of Ni-P.

Development of Tungsten CMP (Chemical Mechanical Planarization) Slurry using New Abrasive Particle (새로운 연마입자를 이용한 텅스텐 슬러리 개발)

  • Yu, Young-Sam;Kang, Young-Jae;Kim, In-Kwon;Hong, Yi-Koan;Park, Jin-Goo;Jung, Seok-Jo;Byun, Jung-Hwan;Kim, Moon-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.571-572
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    • 2006
  • Tungsten CMP needs interconnect of semiconductor device ULSI chip and metal plug formation, CMP technology is essential indispensable method for local planarization. This Slurry development also for tungsten CMP is important, slurry of metal wiring material that is used present is depending real condition abroad. It is target that this research makes slurry of efficiency that overmatch slurry that is such than existing because focus and use colloidal silica by abrasive particle to internal production technology development. Compared selectivity of slurry that is developed with competitor slurry using 8" tungsten wafer and 8" oxide wafer in this experiment. And removal rate measures about density change of $H_2O_2$ and Fe particle. Also, corrosion potential and current density measure about Fe ion and Fe particle. As a result, selectivity find 83:1, and expressed similar removal rate and corrosion potential and current density value comparing with competitor slurry.

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The Corrosion behaviour of Pb-Ca alloy for Lead-acid battery by cyclic Voltammetry (Cyclic Voltammetry에 의한 연측전지용 Pb-Ca 합금의 부식특성 연구)

  • Kim, S.P.;Kim, G.T.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1048-1050
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    • 1995
  • Lead-acid battery is used widely as a power source at a automobile, industrial machines, folk lifts, U.P.S. etc. Lead-acid battery is cheaper than arty other secondary battery, but this battery has many disadvantages such as heavy, low energy density, environment problem etc. In this article, we introduce cyclic voltammetry methods to investigate corrosion behaviour of positive grids of Pb-Ca alleys.

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Production of Heavy Gauged HY-GALUME in Hyundai HYSCO

  • Park, S.J.;Koh, H.S.;Kim, J.G.;Moon, M.B.
    • Corrosion Science and Technology
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    • v.10 no.5
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    • pp.157-161
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    • 2011
  • HY-Galume is a brand name of 55%Al-Zn coated steel sheets produced by Hyundai HYSCO. Heavy gauged HY-Galume having thickness around 2 millimeters is used as a steel casing for the electrical distribution panel in the construction market. It requires a strict surface quality because it is used indoors. In this paper, several troubleshooting experiences in producing heavy gauged HY-Galume are proposed.

A Study on Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 이용한 레일부식 저감 방안에 관한 연구)

  • Choi, Jung-Youl;Kim, Jun-Hyung;Lee, Kyu-Yong;Kim, Young-Ki;Park, Jong-Yoon;Song, Bong-Hwan;Seol, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.54-60
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    • 2017
  • A railway rail will be corroded by the repetitive sea wind and fog in the splash and tidal zone such as Youngjong grand bridge. And these rusts of rail could be increased by increasing service period, and it frequently occurred the safety accidents or disorders in electrical problem. In this study, the sacrificial anode cathodic protection method was proposed as a measures for reducing the corrosion of the railway rails in the oceanic climate conditions. As the results of immersion test using the salt water during four months, the sacrificial anode cathodic protection method using the aluminum anode(Al-anode) was evaluated that a distinct effect on corrosion reduction in the rails. Therefore the sacrificial anode cathodic protection method was experimentally proven that a disorders in aspects electric and signal of railway operation condition such as direct fixation track system in Youngjong grand bridge could be prevented by reducing rust falling from the rail. In addition, the installation conditions of the anodes directly affect the transmission range of corrosion potential, the sectional loss of anode, and the corrosion reduction effect. Therefore, to expect the corrosion reduction effect of rails under the oceanic climate conditions for railway track, it was important to adopted the appropriate spacing of anode installation by considering the actual field conditions.

The Effect of Annealing Heat Treatment by Anodic Polarization Impedance Experiments for Cu-10%Ni Alloy

  • Lee, Sung-Yul;Moon, Kyung-Man;Jeong, Jae-Hyun;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.5
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    • pp.536-541
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    • 2015
  • Copper has been used extensively as an electric wire or as a base material in various types of machineries owing to its good electrical and thermal conductivity and good fabricating property, as well as its good corrosion resistance compared to iron. Furthermore, the copper-nickel alloy has significant corrosion resistance in severely corrosive environments. Although, cupro-nickel alloy shows better corrosion resistance than the brass and bronze series, this alloy also corroded in severely corrosive environments, including aggressive chloride ions, dissolved oxygen, and condition of fast flowing seawater. In this study, and annealing treatment at various annealing temperatures was carried out on the cupro-nickel (Cu-10%Ni) alloy, and the effects of annealing were investigated using electrochemical methods, such as measuring the polarization and impedance behaviors under flowing seawater conditions. The corrosion resistance increased by annealing compared to non heat treatment in the absence of flowing seawater. In particular, the sample annealed at $200^{\circ}C$ exhibited the best corrosion resistance. The impedance in the presence of flowing seawater showed higher values than in the absence of flowing seawater. Furthermore, the highest impedances was observed in the sample annealed at $800^{\circ}C$, irrespective of the present of flowing seawater. Consequently, the corrosion resistance of cupro-nickel (Cu-10%Ni) alloy in a severely corrosive environment can be improved somewhat by annealing.

Corrosion of the non-beryllium dental casting Ni-Cr alloys for the denture base framework metal and the porcelain-fused-to-metal crown (베릴륨 불포함 치과 주조용 니켈-크롬 합금 중 금속의치상용 합금과 금속소부도재관용 합금의 부식에 관한연구)

  • Kim, Hong-Sik;Song, Jae-Sang;Park, Soo-Chul
    • Journal of Technologic Dentistry
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    • v.34 no.4
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    • pp.337-344
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    • 2012
  • Purpose: This study examined the corrosion level by alloy type and pH, and used the corrosion levels as the dental health data. The study utilized one Ni-Cr alloy for the full and removable partial denture metal frameworks and two Ni-Cr alloys for porcelain-fused-to-metal crown, among the non-beryllium dental casting non-precious Ni-Cr alloys. Methods: The alloy specimens were manufactured in $10cm^2$ and stored in the corrosive solution(pH 2.2-4.4) in the electrical water bath($37^{\circ}C$) for seven days. Afterwards, the metal ions were quantitatively analyzed using the ICP. Results: Of the three metal alloys, Bellabond-Plus$^{(R)}$alloy and SOLIBOND N$^{(R)}$alloy, with 22% or higher chrome chemical contents, had higher corrosion resistance than Jdium-100$^{(R)}$alloy with 20% chrome chemical content. In all three alloys, the corrosion of Ni was highest, and metal ion corrosion was higher in the pH 2.2 corrosive solution. Conclusion: Although Ni-Cr alloy was not very corrosive, a Ni-allergic patient should not have Ni-Cr alloy prosthesis. The Ni-Cr alloy for porcelain-fused-to-metal crown should be designed for the dental porcelain to cover the whole crown.

Effect of Zn/Al Cation Ratio on Corrosion Inhibition Capabilities of Hydrotalcites Containing Benzoate Against Carbon Steel

  • Thu Thuy, Pham;Anh Son, Nguyen;Thu Thuy, Thai;Gia Vu, Pham;Ngoc Bach, Ta;Thuy Duong, Nguyen;To Thi Xuan, Hang
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.434-444
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    • 2022
  • Corrosion inhibitors based on Zn-Al hydrotalcites containing benzoate (ZnAlHB) with different molar ratios of Zn/Al were prepared with a co-precipitation process. Compositions and structures of the resulting hydrotalcites were studied with suitable spectroscopic methods such as inductively coupled plasma mass spectrometry (ICP-MS), ultraviolet-visible spectrophotometry (UV-Vis), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and surface zeta potential measurements, respectively. Results of physico-chemical studies showed that crystallite sizes, compositions of products, and surface electrical properties were significantly changed when the molar ratio of Zn/Al was increased. The release of benzoate from hydrotalcites also differed slightly among samples. Anticorrosion abilities of hydrotalcites intercalated with benzoate at a concentration of 3 g/L on carbon steel were analyzed using electrochemical impedance spectroscopy (EIS), polarization curve, energy-dispersive X-ray spectroscopy (EDX), and SEM. Corrosion inhibition abilities of benzoate modified hydrotalcites in 0.1 M NaCl showed an upward trend with increasing Zn/Al ratio. The reason for the dependence of corrosion resistance on the Zn/Al ratio was discussed, including changes in the microstructure of hydrotalcites such as crystal size, density, uniformity, and formation of ZnO.

Characteristics of Unit Cell for SOFC (SOFC의 단위전지 특성평가)

  • 김귀열;엄승욱;문성인
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.80-83
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    • 1996
  • Among the fuel cell system, solid oxide fuel eels is constructed of ceramics, so stack construction is simple , power density is very high, and there is no corrosion problems. The purpose of this research is investigate the characteristics of unit cell for SOFC .

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