• Title/Summary/Keyword: Electrical conductivity.

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Comparative Study on Conductivity and Moisture Content Using Polarization and Depolarization Current (PDC) Test for HV Insulation

  • Jamail, N.A.M.;Piah, M.A.M.;Muhamad, N.A.;Kamarudin, Q.E.
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.1
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    • pp.7-11
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    • 2014
  • The Polarization and Depolarization Current (PDC) measurement is an efficient and effective diagnostic technique based on time domain measurement, for evaluating the high voltage insulation condition. This paper presents a review and comparison results from several published papers on the application of the PDC method to finding the conductivity and moisture content of various types of insulators. For solid insulation, the study was focused on cable insulation, electric machine stator insulation, and paper insulator in transformer insulation with different conditions. For liquid insulation, the review and comparison was done on biodegradable and mineral transformer oils, with fresh oil condition, and aged condition. The results from previous researchers tests were complied, analyzed and discussed, to evaluate the application of the PDC method to monitor the conductivity and moisture of HV equipment insulation systems. From the review results, the PDC technique successfully gives an indication of the conductivity and moisture level of high voltage insulation.

Composited Conductive Materials for Enhancing the Ultrafast Performance for Anode in Lithium-Ion Battery (리튬이온전지 음극의 고속 성능 향상을 위한 도전재 복합화)

  • Ki-Wook, Sung;Hyo-Jin, Ahn
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.474-480
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    • 2022
  • Lithium-ion batteries (LIBs) are powerful energy storage devices with several advantages, including high energy density, large voltage window, high cycling stability, and eco-friendliness. However, demand for ultrafast charge/discharge performance is increasing, and many improvements are needed in the electrode which contains the carbon-based active material. Among LIB electrode components, the conductive additive plays an important role, connecting the active materials and enhancing charge transfer within the electrode. This impacts electrical and ionic conductivity, electrical resistance, and the density of the electrode. Therefore, to increase ultrafast cycling performance by enhancing the electrical conductivity and density of the electrode, we complexed Ketjen black and graphene and applied conductive agents. This electrode, with the composite conductive additives, exhibited high electrical conductivity (12.11 S/cm), excellent high-rate performance (28.6 mAh/g at current density of 3,000 mA/g), and great long-term cycling stability at high current density (88.7 % after 500 cycles at current density of 3,000 mA/g). This excellent high-rate performance with cycling stability is attributed to the increased electrical conductivity, due to the increased amount of graphene, which has high intrinsic electrical conductivity, and the high density of the electrode.

Electrical Property of $BaTiO_3$ Ceramics(II) ($BaTiO_3$ 세라믹의 전기적성질(II))

  • 윤기현;송효일;윤상옥;이형복
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.75-78
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    • 1981
  • The electrical conductivity of $(M_2O_3)_x (BaTiO_3)_{1-x}$ has been measured over the temperature range of 30 to 27$0^{\circ}C$. The substitution of rare earth oxide such as $La_2O_3$, $Nd_2O_3$, or $Dy_2O_3$ can be represented by $M_2O_3$. The additional mole fraction of the rare earth oxide is ranged over 0.0015 to 0.0030. The electrical conductivity exhibits an anomalous decrease near the tetragonal to cubic transition about 12$0^{\circ}C$. The decrease in the electrical conductivity is observed at the higher impurity concentrations owing to space charge layer. The increase in the electrical conductivity is observed as the impurity ion is varied from $La^{+3}$$Nd^{+3}$ to $Dy^{+3}$, due to overlap of 4f electrons of the inner shell.

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The Electrical and Optical Characteristics of Silica Sand by Terahertz Electromagnetic Pulses (테라헤르츠 전자기 펄스를 이용한 이산화규소의 전기적 광학적 특성)

  • 전태인
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.3
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    • pp.202-206
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    • 2001
  • Using THz time-domain spectroscopy (THz-TDS), the power absorption, the index of refraction, and the real conductivity of silica sand are measured from 0.1[Thz] to 0.5[Thz] frequency range. It is impossible to measure the characterization of the silica sand by simple electrical measurements using mechanical contacts, e.g., Hall effect or four-point probe measurements. However, the THz-TDS technique can measure not only electrical but also optical characterization of he sample. Also this technique can measure frequency dependent results. Especially, the real conductivity was increased according to THz frequency. This is unusual material compare with metal and semiconductor materials; the measured real conductivity are not followed by the simple Drude theory.

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Electrical characteristics of multi-walled carbon nanotube-polyethylene composites by catalyst and gas control

  • Park, Suyoung;Choi, Sun-Woo;Jin, Changhyun
    • Journal of Ceramic Processing Research
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    • v.20 no.5
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    • pp.464-469
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    • 2019
  • In this study, the electrical conductivity of multi-walled carbon nanotubes (MWCNTs) and polyethylene synthesized by an extrusion process was evaluated. The MWCNTs used exhibited differences in their dispersion characteristics depending on the type of catalyst or synthesis gas used. Thus, the choice of catalyst or synthesis gas significantly affect the physicochemical state of the final MWCNTs and MWCNT-based composites. In this investigation, the characteristics of MWCNTs were analyzed in four cases by introducing ethylene and propylene gas to each catalyst synthesized using deposition precipitation and spray drying methods. The MWCNT-based composites synthesized using the catalyst prepared by deposition precipitation and the ethylene synthesis gas showed the best electrical conductivity. In principle, the morphologies of the MWCNTs indicate that the smaller the aggregate size and bundle thickness, the better the electrical conductivity of the MWCNT composites. This implies that the network is well-formed.

Effects of Sr Contents on Structural Change and Electrical Conductivity in Cu-doped LSM ($La_{1-x}Sr_xMn_{0.8}Cu_{0.2}O_{3{\pm}{\delta}}$)

  • Ryu, Ji-Seung;No, Tae-Min;Kim, Jin-Seong;Jeong, Cheol-Won;Lee, Hui-Su
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.33.1-33.1
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    • 2011
  • Strontium doped lanthanum manganite (LSM) with perovskite structure for SOFC cathode material shows high electrical conductivity and good chemical stability, whereas the electrical conductivity at intermediate temperature below $800^{\circ}C$ is not sufficient due to low oxygen ion conductivity. The approach to improve electrical conductivity is to make more oxygen vacancies by substituting alkaline earths (such as Ca, Sr and Ba) for La and/or a transition metal (such as Fe, Co and Cu) for Mn. Among various cathode materials, $LaSrMnCuO_3$ has recently been suggested as the potential cathode materials for solid oxide fuel cells (SOFCs). As for the Cu doping at the B-site, it has been reported that the valence change of Mn ions is occurred by substituting Cu ions and it leads to formation of oxygen vacancies. The electrical conductivity is also affected by doping element at the A-site and the co-doping effect between A-site and B-site should be described. In this study, the $La_{1-x}Sr_xMn_{0.8}Cu_{0.2}O_{3{\pm}{\delta}}$ ($0{\leq}x{\leq}0.4$) systems were synthesized by a combined EDTA-citrate complexing process. The crystal structure, morphology, thermal expansion and electrical conductivity with different Sr contents were studied and their co-doping effects were also investigated.

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Experimental Study on the Effect of Degree of Saturation on the Electrical Conductivity of Soils (포화도에 따른 흙의 전기전도도 변화에 대한 실험적 연구)

  • Ko, Hyojung;Choo, Hyunwook
    • Journal of the Korean Geotechnical Society
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    • v.39 no.8
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    • pp.29-39
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    • 2023
  • The degree of saturation determines the connectivity of void space and the particle surface. Thus, it greatly affects the electrical conductivity of soils. This study aimed to analyze the electrical conductivities of coarse grains with a high relevance of pore water conduction and fine grains with a high relevance of surface conduction based on the degree of saturation. It also aimed to express the electrical conductivity of unsaturated soils as a combination of surface and pore water conductions using the modified Archie's equation. Samples were prepared in a plastic cell equipped with four electrodes, and the electrical conductivity was measured based on the porosity at various degrees of saturation (40%~100%). The results demonstrate that Archie's equation can be used to express the electrical conductivity of coarse grains, with a saturation exponent of ~1.93 regardless of the pore water conductivity. However, the saturation exponent of fine grains varied considerably with pore water concentration. This variation can be attributed to the relative magnitude of surface conduction with respect to the electrical conductivity of soils at different pore water concentrations. Thus, the degree of saturation has varying effects on pore water conduction and surface conduction. Therefore, different saturation exponents must be used for pore water conduction and surface conduction to predict the electrical conductivity of unsaturated soils using the modified Archie's equation.

Organic Compounds Vapor Detection Properties of MWCNT/PMMA Composite Film Detector (CNT/PMMA 복합막 검출기의 유기화합물 증기의 검출 특성)

  • Lim, Young Taek;Shin, Paik-Kyun;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.727-730
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    • 2015
  • In this paper, we fabricated organic compounds detector using the MWCNT/PMMA (multi-walled carbon nanotube / polymethylmethacrylate) composite film. We used polymer film as a matrix material for the device framework, and introduced CNTs for reacting with the organic compounds resulting in changing electrical conductivity. Spray coating method was used to form the MWCNT/PMMA composite film detector, and pattern formation of the detector was done by shadow mask during the spray coating process. We investigated changes of electrical conductivity of the detector before and after the organic compounds exposure. Electrical conductivity of the detector tended to decrease after the exposure with various organic compounds such as acetone, tetrahydrofuran (THF), toluene, and dimethylformamide (DMF). Finally we conclude that organic compounds detection by the MWCNT/PMMA composite film detector was possible, and expect the feasibility of commercial MWCNT/PMMA composite film detector for various organic compounds.

Defect Chemistry of BaTiO_3$ Codoped with Mn and Nb

  • Han, Young-Ho;Shin, Dong-Jin
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.68-71
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    • 1998
  • The effect of Mn and Nb additions on the electrical properties of BaTiO$_3$ has been studied by means of equilibrium electrical conductivity as a function of temperature, oxygen partial pressure(Po$_2$) and composition. If the manganese ion is added to the normal Ti site, i.e. BaTi$_{1-x}Mn_xO_{\delta-6}$, the equilibrium conductivity shows strong evidence of acceptor-doped behavior. The conductivity minimum, corresponding to the transition from oxygen excess, p-type behavior to oxygen deficient, n-type behavior with decreasing Po$_2$, is displaced to lower Po$_2$ and is broadened and flattened. The partial replacement of Mn ion with Nb decreases the acceptor-doped effect and the total replacement exhibits a typical donor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped samples, for the p-type region, the electrical conductivity follows the 1/6th power dependence of oxygen partial pressure.

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Electrical and optical characteristics AZO transparent conductivity thin films by solid state diffusion method (고상확산법에 의해 제조된 AZO 투명전도막의 전기-광학특성)

  • Lim, Kwang-Soo;Pyo, Jin-Gu;So, Soon-Jin;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.785-787
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    • 2002
  • Conductivity and transmittancy of ZnO is very excellent and the price is low. So the study of transparent electrode materials and electromagnetic wave shielding wall is actively in progress. We add $Al_2O_3$(0.0, 2.0, 3.0, 5.0wt%) to ZnO and observe microscopic structure and conductivity. For XRD observation, Al peak of AZO is increased by increasing the amount of $Al_2O_3$. We observe that the size of grain is reduced by increasing the liquid phase of grain boundary to SEM observation. Conductivity of AZO is increased by increasing the amount of $Al_2O_3$. We confirm the application possibility of the materials for electromagnetic wave reflection materials.

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