• 제목/요약/키워드: Electrical conductivities

검색결과 294건 처리시간 0.025초

Modeling of Electrical Conductivity from $\sigma$tot vs. Po21/4 Plot in Wet Atmosphere for High-Temperature Proton-Conducting Oxides

  • Baek, Hyun-Deok
    • The Korean Journal of Ceramics
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    • 제4권2호
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    • pp.136-140
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    • 1998
  • This work demonstrates a method for modeling of electrical conductivity in high-temperature proton-conducting oxides. Total conductivity was calculated assuming that it comprises partial conductivities contributed by protons, oxygen ions and electron holes. From the polt $\sigma_{tot}$ vs. $po_2\;{1/4}$ in wet atmosphere, thermodynamic and kinetic parameters were obtained representing transport properties such as concentration and mobility of the charge-carrying defects. The formulas for the calculation of partial conduction were derived based on the defect structure of HTPCs. Illustrative calculation were made for $SrCe_{0.95}Yb_{0.05}O_{2.975}$ system.

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리튬이온 2차 전지용 전해액의 이온전도도와 전기화학적 특성 (Conductivity and Electrochemical characterization of Lithium ion secondary battery electrolytes)

  • 임동규;이제혁;변문기;조봉희;김영호;우병원;나두찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.295-298
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    • 1998
  • We have investigated ionic conductivity and electrochemical stability of the electrolytes containing organic solvent. Ion conductivities were measured between 10 and 80$^{\circ}C$, and electrochemical stabilities were determined by cyclic voltammetry on glassy carbon, platinum and aluminum electrodes. Ionic conductivity of electrolyte(EC:DEC=1:1) with IM LiPF$\_$6/ shows better than that of the other electrolytes having Li salts. The IM LiBF$_4$-PC electrolyte exhibits good electrochemical stability. IM LiPF$\_$6/ (EC:DEC=1:1) and IM LiPF$\_$6/ (EC:DMC=1:1) electrolytes are used for the high capacity of battery system.

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성막조건에 따른 $\alpha$-Sexithienyl 박막의 물리적 특성 및 전기전도도에 관한 연구 (A study on the physical characteristics and conductivities of $\alpha$ -Sexithienyl thin films with various deposition conditions)

  • 박용인;권오관;오세운;최종선;김영관;신동명;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.91-94
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    • 1997
  • $\alpha$-sexithienyl($\alpha$-6T) thin films were deposited by Organic Molecular Beam Deposition(OMBD) technique, where the $\alpha$-6T was synthesized and purified by the sublimation method. The thin films of the $\alpha$-6T were deposited under various deposition conditions. The effects of deposition rate, substrate temperature. and vacuum pressure an the formation of these films have been studied. The molecular orientations of $\alpha$-6T films were investigated with the polarized electronic absorption spectroscopy. The molecules in the $\alpha$-6T film deposited at a low deposition rate under a high vacuum were aligned almost perpendicular to the substrate. The film deposited at an elevated substrate temperature (~9 $O^{\circ}C$) showed higher conductivity than the film deposited at room temperature.

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Dual Phase 전도성 CO2 분리막: 메커니즘, 미세구조 및 전기전도도 (Dual Phase Conductive CO2 Membranes: Mechanism, Microstructure, and Electrical Conductivity)

  • 이시우;유지행;우상국
    • 한국세라믹학회지
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    • 제44권8호
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    • pp.424-429
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    • 2007
  • Novel conductive $CO_2$ membranes composed of dual phases, molten carbonates and electronic conducting ceramics, were investigated. As the microstructure control of electronic conducting ceramic supports is extremely important to keep the molten carbonates stable in the membranes by a capillary force applied by the pore structure of the supports, we have scrutinized the microstructure of the electronic conducting supports utilizing microscopic images and gas permeability measurement. From the evaluation of the electrical conductivities of the molten carbonates and the electronic conducting ceramic supports, we found that the ionic conductivity of the molten carbonates could determine $CO_2$ flux through the dual phase membranes if the surface exchange rate were relatively high enough.

손실 반공간에 묻힌 2차원 원통형 파이프의 검출 및 식별 (Iterative Reconstruction of Multiple Cylinders Buried in the Lossy Half Space)

  • Kim, Jeong-Seok;Ra, Jung-Woong
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 하계종합학술대회 논문집(1)
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    • pp.173-176
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    • 2001
  • Several dielectric as well as conducting cylinders buried in the lossy half space are reconstructed from the scattered fields measured along the interface between the air and the lossy ground. Iterative inversion method by using the hybrid optimization algorithm combining the genetic and the Levenberg-Marquardt algorithm enables us to find the positions, the sizes, and the medium parameters such as the permittivities and the conductivities of the buried cylinders as well as those of the background lossy half space. Illposedness of the inversion caused by the errors in the measured scattered fields are regularized by filtering the evanescent modes of the scattered fields out.

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고체산화물연료전지의 시뮬레이션을 위한 전기화학모델 (Electrochemical model for the simulation of solid oxide fuel cells)

  • 박준근;이신구;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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용융성장된 YBCO초전도체의 불순물상의 영향 (Effects of Impure phases in Textured YBCO Superconductors)

  • 소대화;단옥교;번점국
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.63-66
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    • 1996
  • The method for calculation of $Y_2$BaCuO$_{5}$ contents was set up. It was estimated that the optimum value of 211 contents in the textured YBCO superconductor as flux pinning center was about 20wt.%. Ag contents have no influence on the critical temperature, but have large influence on the critical current density of the textured YBCO. When Ag contents over 15wt.%, which was the solubility of condensed YBCO, the critical current densities tend to a stable value.e.

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Preparation of Polymer Composites Containing Gold Nanonetworks Using an Amphiphilic Poly(oxyethylene) Brush

  • Cha, Sang-Ho;Kim, Jong-Uk;Lee, Jong-Chan
    • Macromolecular Research
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    • 제16권8호
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    • pp.711-716
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    • 2008
  • We synthesized gold nanonetwork using the amphiphilic polymer brush, poly(oxyethylene) containing decyltri(oxyethylene)thiomethyl ($C_{10}H_{21}(OCH_2CH_2)_3SCH_2-$) side groups, as a stabilizer and/or a template. When tetrabutylammonium borohydride solution in THF was added to a mixture solution of the polymer and $LiAuCl_4$ in THF, 0-D gold nanomaterials were obtained. However, when an aqueous solution of sodium borohydride was added, gold nanonetworks were synthesized. The composites composed of polymer/0-D gold nanomaterials and polymer/gold nanonetworks showed electrical conductivities of ${\sim}10^{-9}$ and ${\sim}10^{-3}S/cm$, respectively, which indicated that the gold nanonetworks increased the electrical conductivity.

60Hz ELF 자계에 의한 인체내부 유도 전류밀도 해석 (Analysis on Induced Current Density Inside Human Body by 60 Hz ELF Magnetic Fields)

  • 민석원;송기현
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권2호
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    • pp.76-81
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    • 2006
  • This paper analysed the characteristics of current density induced inside human body by 60 Hz extremely low frequency magnetic fields according to varying conductivities of human model. Human model was composed of several organs and other parts, whose shapes were expressed by spheroids or cylinders. Organs such as the brain, heart, lungs, liver and intestines were taken into account. Applying the boundary element method to the human model, we estimated effects on the induced current distribution due to differences of the organ conductivity and shape. We find organ conductivity influences most and a cross section area and a position of organ also gives effects.

리튬 2차전지용 전해액의 초성 및 비교 분석 (Mixture of the Lithium Secondary Batteries and Analyses)

  • 임동규;김영호;조봉희;우병원;나두찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.395-397
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    • 1999
  • There are many efforts to improve electrolytes to satisfy the requirements of a lithium rechargeable battery. We have investigated a binary solvent mixture containing the electrolyte lithium salt($LiBF_4$, $LiPF_6$), that is conductive and electrochemically stable. Ionic conductivities were measured between -5 and $80^{\circ}C$, and cyclic voltammetry between 2.5 and 4.3 V were measured by SUS or platinum electrode.

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