• 한국전기화학회:학술대회논문집
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• 2003.11a
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• pp.195-206
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• 2003

• Korean Journal of Materials Research
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• v.32 no.7
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• pp.313-319
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• 2022

Double-layer capacitors (DLCs) are developed with high surface electrodes to achieve a high capacitance value. In the present work, the initial bulk concentration of 1 mol/m³ and 3 mol /m³ are selected to show the consequential effects on the performance of a double-layer capacitor. A 1D model of COMSOL Multiphysics has been developed to analyze the electric field and potential in cell voltage, the electric displacement field and polarization induced by the field, and energy density in a double-layer structure. The electrostatics and the electric circuit modes in COMSOL are used to simulate the electrochemical processes in the double-layer structure. The analytical analysis of a double-layer capacitor with different initial bulk concentrations is investigated by using Poisson-Nernst-Plank equations. From the simulation results, the differential capacitance changes as a function of compact layer thickness and initial bulk concentration. The energy density varies with the differential capacitance and voltage window. The values of energy density are dominated by the interaction of ions in the solution and electrode surface.

• Interaction and multiscale mechanics
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• v.3 no.2
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• pp.157-171
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• 2010

In this paper, a theoretical method has been developed for the electric double layer interaction under condition of the variable dielectric permittivity of water. Using Poisson-Boltzmann equation (PBE), for one plate and two plates having similar or dissimilar constant charge or constant potential, we have investigated the electric double layer potential, its gradient and the disjoining pressure as well as the effect of variation of dielectric permittivity on these parameters. It has been assumed that plates are separated by a specific distance and contain a liquid solution in between. It is shown that reduction of the dielectric permittivity near the interfaces results in compression of electric double layers and affects the potential and its gradient which leads to a decreased electrostatic repulsion. In addition, it is shown that variation of dielectric permittivity in the case of higher electrolyte concentration, leads to a greater change in potential distribution between two plates.

• Carbon letters
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• v.1 no.3_4
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• pp.133-137
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• 2001

Mesoporous activated carbon fiber (ACF) was prepared from phenolic resin containing a small amount (0.1 wt %) of organic nickel complex through carbonization and steam activation. Microporous ACF as reference sample was also prepared from phenolic resin without agent. In both cases of the mesoporous ACFs and the microporous ACFs, the electric double layer capacitance of the nonaqueous electrolyte (0.5 M $TEABF_4$/PC or 1.0 M $LiClO_4$/PC) was not proportional to the BET specific surface area. This is owing to the low permeability of nonaqueous electrolyte or the low mobility of ion in narrow micropores. However, the mesoporous ACF showed higher double layer capacitance than the microporous (normal) ACF. This result suggests that the presence of many mesopores promotes the formation of effective double layer or the transfer of ion in the micropore.

• Journal of the Korean Electrochemical Society
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• v.6 no.3
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• pp.174-177
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• 2003

Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

• Journal of international Conference on Electrical Machines and Systems
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• v.2 no.2
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• pp.171-178
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• 2013

This paper discusses to conduct experimental verification of two types of micro electric vehicles (EV) in order to realize improvement in electric mileage and shorten a charging time of the battery. First, electric double layer capacitor (EDLC) systems to use as a secondary battery are proposed. The internal resistance of EDLC is small compared with a rechargeable battery, and it is suitable for momentary charge-discharge of EV. Next, control circuits of the capacitors to increase the regenerative electric power are utilized. Then, a novel method to charge a main battery of the EV is introduced. Finally, experimental results demonstrate the validity of the proposed method.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2160-2164
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• 2007

In this study, the mechanism of enhanced thermal conductivity is elucidated on the bases of both electric double layer (EDL) and kinetic theory. A novel expression for the thermal conductivity of nanofluids is proposed and verified by applying to $Al_2O_3$ nanofluids with regard to various temperatures, volume fractions and particle sizes. In dilute nanofluids, the effects of Brownian motion and particle interaction on enhancing the thermal conductivity of nanofluids are quite comparable while the effect of particle interaction due to EDL is more prominent in dense nanofluids. The model presented in this paper shows that particle interaction due to the electrical double layer is the most responsible for the enhancement of thermal conductivity of nanofluids.

• Proceedings of the KIEE Conference
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• 2007.11c
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• pp.108-111
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• 2007

A novel voltage sag compensator with hi-directional DC/DC converter of Electric double layer capacitor is proposed. Recently, the double-layer capacitor which is drawn attention as a new energy storage element has a lot of advantage such as no maintenance, long lifetime and quick charge/discharge characteristics with large current. This DC/DC converter is used to control the charging current to the double-layer capacitor and also used to keep the DC link voltage constant for discharge of the double-layer capacitor. Therefore, the proposed DC/DC converter has the high-efficiency controller, dynamic compensator of voltage sag is driven by this converter. Finally, experimental results show the validity of the control scheme and the ability of the dynamic voltage compensator.

• Transactions on Electrical and Electronic Materials
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• v.8 no.4
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• pp.182-187
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• 2007

The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about $205C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}=2.5V$, while the positively charged density became the maximum, about $61.1C/m^3$ at the region where it was located around the cathode layer. The performance of the best sample was found to be better in terms of the charge density (Cs) and specific energy ($E_s$) with a maximum value of ${\sim}8.4F/g$ and 26 Wh/kg. The $C_s$ obtained from the PEA method agreed well with that from the energy conversion method. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.115.1-115.1
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• 2011

최근 기본적인 pin 구조의 박막 cell 에서 i layer를 최적화 시키는 방안으로 double layer 구조가 많이 연구되고 있다. 본 연구에서는 ASA(Advanced Semicon ductor Analysis) simulation을 이용하여 i-double layer 최적화에 대한 연구를 진행해 보았다. 두께 150/150nm의 i double layer의 band gap 가변을 한 simulation 결과를 보았을 때, p쪽의 band gap이 상승하면서 intrinsic layer 내의 field가 증가하여 recombination center가 감소하였으나 FF의 감소가 있었다. n쪽의 band gap을 상승 시켰을때 n/i 쪽 field 증가로 Voc가 상승되어 초기 효율이 증가하였으나 intrinsic layer내의 field가 감소하여 recombination center가 오히려 증가하였다. 결과적으로 electric field와 효율을 동시에 고려했을 때 두께 300nm, 1.75의 band gap을 가지는 single layer 보다 150/150nm두께에 1.8/1.7 또는 1.8/1.75의 bandgap을 가지는 double layer를 사용하였을 때 보다 높은 효율을 얻을 수 있었다.